Viscoelastic foam
Embodiments of the invention provide for viscoelastic polyurethane foams. The foams are made from reaction system which includes (a) an isocyanate reactive component, (b) a isocyanate component, (c) one or more blowing agents, (d) a catalyst component, and (e) a silicone based surfactant. The isocyanate reactive component includes at least (i) from 25 to 80% by weight of at least one polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol having a combined number average equivalent weight from 1300 to 1700, a polyoxyethylene percentage of between 75% and 95% by weight of the combined amounts of polyoxypropylene and polyoxyethylene, and a primary OH percentage of between 80 and 95% of the total number of OH groups of the polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol, and (ii) from 5 to 30% by weight of the isocyanate reactive component of at least one low functionality polyol having a functionality of between 1.5 and 2.5, a combined number average equivalent weight from 500 to 1500 and an OH number of 40 to 70.
1. A reaction system for preparation of a viscoelastic polyurethane foam comprising:
(a) an isocyanate reactive component comprising:
(i) from 25 to 80% by weight of the isocyanate reactive component of at least one polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol having a combined number average equivalent weight from 1300 to 1700, a polyoxyethylene percentage of between 75% and 95% by weight of the combined amounts of polyoxypropylene and polyoxyethylene, and a primary OH percentage of between 80 and 95% of the total number of OH groups of the polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol;
(ii) from 5 to 30% by weight of the isocyanate reactive component of at least one low functionality polyol having a functionality of between 1.5 and 2.5, a combined number average equivalent weight from 500 to 1500 and an OH number of 40 to 70; and
(iii) from 5 to 30% by weight of the isocyanate reactive component of at least one polyoxyethylene capped polyoxypropylene polyol having an average functionality between 4 and 6, a combined number average molecular weight from 4000 to 6000, and an OH number of 25 to 45;
(b) an isocyanate component;
(c) one or more blowing agents;
(d) a catalyst component; and
(e) a silicone based surfactant.
2. The reaction system of claim 1 , wherein the isocyanate reactive component further comprises:
(iv) from 2 to 20% by weight of the isocyanate reactive component of at least one triol having a combined number average equivalent weight from 200 to 400 and an OH number of 175 to 275.
3. The reaction system of claim 1 , wherein the one or more blowing agents comprises water.
4. The reaction system of claim 1 , wherein the isocyanate component (b) comprises an isocyanate terminated prepolymer.
5. The reaction system of claim 4 , wherein the isocyanate terminated prepolymer comprises the reaction product of a polyol and a mixture of 2,4′-methylene diphenyl diisocyanate, 4,4′-methylene diphenyl diisocyanate, and polymeric methylene diphenyl diisocyanate.
6. A polyurethane foam, comprising a reaction product of the reaction system of claim 1 .
7. The polyurethane foam of claim 6 , wherein the polyurethane foam is molded and comprises a skin having a thickness of 100-300 μm thick.
8. The polyurethane foam of claim 7 , wherein the skin has a thickness of 150-250 μm.
9. The polyurethane foam of claim 8 , wherein the skin comprises polyurethane cells having diameters of 50-150 μm.