Processes for preparing alumina and various other products
There are provided processes for preparing alumina. These processes can comprise leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate; reacting said leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid; and heating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and optionally recovering gaseous HCl so-produced. These processes can also be used for preparing various other products such as hematite, MgO, silica and oxides of various metals, sulphates and chlorides of various metals, as well as rare earth elements, rare metals and aluminum.
1. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate;
reacting said leachate with HCl to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid;
heating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and producing gaseous HCl,
recycling said gaseous HCl so-produced by contacting same with water to obtain a composition having a concentration of about 25 to about 45 weight % and using said composition for leaching said aluminum-containing material.
2. The process of claim 1 , wherein said aluminum-containing material is leached with HCl having a concentration of about 25 to about 45 weight % at a temperature of about 125 to about 225° C.
3. The process of claim 1 , wherein said recycled gaseous HCl so-produced is contacted with water to obtain said composition having a concentration of about 26 to about 42 weight % and said composition is reacted, at a temperature of about 125 to about 225° C., with said aluminum-containing material to leach same.
4. The process of claim 3 , wherein said liquid comprises at least one iron chloride.
5. The process of claim 4 , wherein said liquid is concentrated to obtain a concentration of said at least one iron chloride of at least 30% by weight; and then hydrolyzed at a temperature of about 155 to about 350° C.
6. The process of claim 4 , wherein said liquid is concentrated to obtain a concentration of said at least one iron chloride of at least 30% by weight; and then said at least one iron chloride is hydrolyzed at a temperature of about 155 to about 350° C. while maintaining a ferric chloride concentration at a level of at least 65% by weight, to generate a composition comprising a liquid and precipitated hematite; recovering said hematite; and recovering rare earth elements and/or rare metals from said liquid.
7. The process of claim 6 , further comprising, after recovery of said rare earth elements and/or said rare metals, reacting said liquid with HCl to cause precipitation of MgCl 2 , and recovering same.
8. The process of claim 1 , wherein said process comprises reacting said leachate with HCl, optionally recovered during said process, and having a concentration of at least 30% to obtain said liquid and said precipitate comprising said aluminum ions, said precipitate being formed by crystallization of AlCl 3 .6H 2 O.
9. The process of claim 1 , wherein said process comprises heating said precipitate at a temperature of at least 350° C. for converting AlCl 3 .6H 2 O into Al 2 O 3 .
10. The process of process of claim 1 , wherein said process comprises converting AlCl 3 .6H 2 O into Al 2 O 3 by carrying out a calcination of AlCl 3 .6H 2 O, said calcination comprising steam injection.
11. The process of claim 10 , wherein steam is injected at a pressure of about 200 to about 700 psig.
12. The process of claim 1 , wherein said aluminum-containing material is leached at a pressure of about 4 to about 10 barg.
13. The process of claim 1 , further comprising, before leaching said aluminum-containing material, a pre-leaching removal of fluorine optionally contained in said aluminum-containing material.
14. The process of claim 1 , wherein said aluminum-containing material is chosen from aluminosilicate minerals.
15. The process of claim 3 , wherein said aluminum-containing material is red mud.
16. The process of claim 1 , wherein the recovered HCl is purified and/or concentrated.
17. The process of claim 1 , wherein the concentration of gaseous HCl is increased from a value below the azeotropic point before treatment to a value above the azeotropic point after treatment.
18. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate;
reacting said leachate with gaseous HCl having a concentration of at least 85% by weight to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid; and
heating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and producing HCl.
19. A process for preparing aluminum comprising:
obtaining Al 2 O 3 by the process of claim 1 ; and
converting said Al 2 O 3 into aluminum.
20. A process for preparing alumina, said process comprising:
leaching red mud with HCl to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate;
reacting said leachate with HCl to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid;
heating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and producing gaseous HCl,
recycling said gaseous HCl so-produced by contacting same with water to obtain a composition having a concentration of about 25 to about 45 weight % and using said composition for leaching said red mud.
21. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate;
reacting said leachate with HCl to obtain a liquid, the liquid comprising at least one iron chloride, and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid;
heating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and producing gaseous HCl,
recycling said gaseous HCl so-produced by contacting said gaseous HCl so-produced with water to obtain a composition having a concentration of about 25 to about 45 weight % and using said composition for leaching said aluminum-containing material;
wherein said liquid is concentrated to obtain a concentration of said at least one iron chloride of at least 30% by weight; and then said at least one iron chloride is hydrolyzed at a temperature of about 155 to about 350° C. while maintaining a ferric chloride concentration at a level of at least 65% by weight, to generate a composition comprising a liquid and precipitated hematite; recovering said hematite; and recovering rare earth elements and/or rare metals from said liquid.
22. The process of claim 20 , wherein said recycled gaseous HCl so-produced is contacted with water to obtain said composition having a concentration of about 26 to about 42 weight %.
23. The process of claim 21 , wherein said recycled gaseous HCl so-produced is contacted with water to obtain said composition having a concentration of about 26 to about 42 weight %.