Laminate body, cross-linked product, and molded member
Provided are a laminate body, a cross-linked product, and a molded member superior in interlayer adhesiveness. An acrylic elastomer layer 11 is prepared from an acrylic elastomer composition containing an epoxy group-containing acrylic elastomer as major component, an onium salt in an amount of 1 to 5 parts by mass and a polyol compound in an amount of 1 to 8 parts by mass with respect to 100 parts by mass of the acrylic elastomer, and a fluorine-based elastomer layer 12 is prepared from a fluorine-based elastomer composition containing a polyol crosslinking agent. The acrylic elastomer layer 11 and the fluorine-based elastomer layer 12 are laminated, to give a laminate body 1 . The laminate body 1 is cross-linked, to give a cross-linked product or a molded member.
1. A laminate body, comprising:
an acrylic elastomer layer prepared from an acrylic elastomer composition containing an epoxy group-containing acrylic elastomer as major component, an onium salt in an amount of 1 to 5 parts by mass and a polyol compound in an amount of 1 to 8 parts by mass with respect to 100 parts by mass of the acrylic elastomer; and a fluorine-based elastomer layer prepared from a fluorine-based elastomer composition containing a polyol crosslinking agent
wherein the epoxy group-containing acrylic elastomer is a copolymer of an alkyl(meth)acrylate ester and an epoxy group-containing crosslinking monomer,
the epoxy group-containing crosslinking monomer is optionally copolymerized to one or more other crosslinking monomers,
the epoxy group-containing crosslinking monomer is copolymerized in an amount of 0.5 to 10 mass % with respect to the total amount of the monomers constituting the acrylic elastomer,
the onium salt and the polyol compound are blended into the acrylic elastomer before the acrylic elastomer layer and the fluorine-based elastomer layer are bonded by crosslinking,
the Mooney scorch time (t5) of the acrylic elastomer composition is 10 minutes or more according to JIS K6300 under a test condition at 125° C.,
the acrylic elastomer layer and the fluorine-based elastomer layer are crosslinked, and
the polyol compound in the acrylic elastomer composition is one or more polyhydroxyaromatic compounds.
2. The laminate body according to claim 1 , wherein the onium salt is an organic ammonium salt and/or an organic phosphonium salt.
3. A cross-linked product, prepared by crosslinking the laminate body according to claim 1 .
4. A molded member of the cross-linked product according to claim 3 .
5. The molded member according to claim 4 , for use as a hose, a seal part, or an antivibration rubber part.
6. A molded member of the laminate body according to claim 1 .
7. The molded member according to claim 6 , for use as a hose, a seal part, or an antivibration rubber part.
8. A cross-linked product, prepared by crosslinking the laminate body according to claim 2 .