IP Library Granted Patent US 10,865,332
Granted Patent B2
US 10,865,332 · App. 14/347,901 · Granted Dec 15, 2020

Epoxy resin composition and electronic component device

Inventors: Hirokuni Ogihara (Ibaraki, JP); Fumio Furusawa (Ibaraki, JP); Shinya Nakamura (Ibaraki, JP); Takatoshi Ikeuchi (Ibaraki, JP); Takashi Yamamoto (Ibaraki, JP)
Assignee: Showa Denko Materials Co., Ltd.
C09J163/00C08G59/3218C08G59/621C08L63/00H01L23/293H01L2924/181Y10T428/31511
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Quick Facts
Patent No.
US 10,865,332
App. No.
14/347,901
Granted
Dec 15, 2020
Kind
B2
Abstract

An epoxy resin composition includes: (A) an epoxy resin containing a compound represented by the following Formula (I); (B) a phenol resin containing a compound represented by the following Formula (II); and (C) a dihydroxynaphthalene compound containing a compound represented by the following Formula (III). In Formula (I), R represents a hydrogen atom, and n represents an integer from 0 to 10. In Formula (II), R 1 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an alkoxy group having 1 or 2 carbon atoms, and each R 1 may be the same as or different from another R 1 . n represents an integer from 0 to 10. In Formula (III), R 1 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an alkoxy group having 1 or 2 carbon atoms.

Claims (38)

1. An epoxy resin composition, consisting of:

an epoxy resin component (A) consisting of:

(1) a first compound represented by the following Formula (I), or

(2) an epoxy resin component consisting of:

at least 80% by mass, based on a total amount of the epoxy resin, of the first compound represented by the following Formula (I);

and a second epoxy compound having at least two epoxy groups per molecule, the second epoxy compound including a cresol novolac epoxy resin as the epoxy resin component (A);

(B) a phenol resin including a compound represented by the following Formula (II);

(C) a dihydroxynaphthalene compound including a compound represented by the following Formula (III); and

optionally, one or more of an antioxidant, a curing accelerator, an inorganic filler, a coupling agent, an ion exchanger, a mold releasing agent, a stress relaxing agent, a flame retardant, and a colorant;

wherein, in the Formula (I), R represents a hydrogen atom, and n represents an integer from 0 to 10;

wherein, in the Formula (II), R 1 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an alkoxy group having 1 or 2 carbon atoms, and each R 1 may be the same as or different from another R 1 , and n represents an integer from 0 to 10;

wherein, in the Formula (III), R 1 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an alkoxy group having 1 or 2 carbon atoms;

wherein a content of a total amount of the compound represented by the Formula (III) with respect to a total amount of the compound represented by the Formula (II) and the compound represented by the Formula (III) is from 10% by mass to 55% by mass; and

wherein the epoxy resin composition is solid at 25° C.

2. The epoxy resin composition according to claim 1 , wherein the epoxy resin composition includes an antioxidant.

3. An electronic component device, comprising an element sealed by the epoxy resin composition according to claim 1 .

4. The epoxy resin composition according to claim 1 , wherein a ratio of a number of hydroxyl groups in the phenol resin to the number of epoxy groups in the epoxy resin component (A) is from 0.5 to 2.

5. The epoxy resin composition according to claim 1 , wherein the epoxy resin component (A) consists of only the first compound represented by the Formula (I).

6. The epoxy resin composition according to claim 1 , wherein the epoxy resin component (A) consists of at least 80% by mass, based on a total amount of the epoxy resin, of the first compound represented by the Formula (I) and the cresol novolac epoxy resin.

7. An epoxy resin composition, consisting of:

an epoxy resin component consisting of:

(1) a first compound represented by the following Formula (I), or

(2) an epoxy resin component consisting of:

at least 80% by mass, based on a total amount of the epoxy resin, of the first compound represented by the following Formula (I); and

a second epoxy compound having at least two epoxy groups per molecule, the second epoxy compound including a cresol novolac epoxy resin as the epoxy resin component,

a phenol resin including a compound represented by the following Formula (IV);

a dihydroxynaphthalene compound including a compound represented by the following Formula (III); and

optionally, one or more of an antioxidant, a curing accelerator, an inorganic filler, a coupling agent, an ion exchanger, a mold releasing agent, a stress relaxing agent, a flame retardant, and a colorant;

wherein, in the Formula (I), R represents a hydrogen atom, and n represents an integer from 0 to 10;

wherein, in the Formula (IV), R 1 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an alkoxy group having 1 or 2 carbon atoms, and each R 1 may be the same as or different from another R 1 , and n represents an integer from 0 to 10; and

wherein, in the Formula (III), R 1 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an alkoxy group having 1 or 2 carbon atoms;

wherein a content of a total amount of the compound represented by the Formula (III) with respect to a total amount of the compound represented by the Formula (IV) and the compound represented by the Formula (III) is from 10% by mass to 55% by mass; and

wherein the epoxy resin composition is solid at 25° C.

8. The epoxy resin composition according to claim 7 , wherein the epoxy resin composition includes an antioxidant.

9. An electronic component device, comprising an element sealed by the epoxy resin composition according to claim 7 .

10. The epoxy resin composition according to claim 7 , wherein a ratio of a number of hydroxyl groups in the phenol resin to a number of epoxy groups in the epoxy resin component is from 0.5 to 2.

11. The epoxy resin composition according to claim 7 , wherein the epoxy resin component consists of only the first compound represented by the Formula (I).

12. The epoxy resin composition according to claim 7 , wherein the epoxy resin component consists of at least 80% by mass, based on a total amount of the epoxy resin, of the first compound represented by the Formula (I) and the cresol novolac epoxy resin.

Assignments (4)
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CHANGE OF NAME Recorded Mar 8, 2023
From: SHOWA DENKO MATERIALS CO., LTD.
To: RESONAC CORPORATION
Reel/Frame 062992/0805 →
CHANGE OF NAME Recorded Nov 9, 2020
From: HITACHI CHEMICAL COMPANY, LTD.
To: SHOWA DENKO MATERIALS CO., LTD.
Reel/Frame 054360/0789 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 22, 2014
From: OGIHARA, HIROKUNI; FURUSAWA, FUMIO; NAKAMURA, SHINYA; IKEUCHI, TAKATOSHI; YAMAMOTO, TAKASHI
To: HITACHI CHEMICAL COMPANY, LTD.
Reel/Frame 032952/0312 →