Fluoropolymer molded article
Provided is a large-size injection molded article which is obtained by injection molding a composition containing a heat-meltable fluoropolymer. Specifically, provided is a large-size injection molded article, which can be molded at a lower injection pressure as compared with a conventional PFA and obtained by molding a composition superior in mold release characteristics from a metal mold. This large-size injection molded article is superior in, particularly, heat resistance and chemical resistance, as well as dimensional accuracy, for a substrate processing apparatus. Provided is an injection molded article, having a projection area in an injection direction of 1100 cm 2 or more, obtained by injection molding a composition containing a heat-meltable fluoropolymer. It is a preferable aspect that the composition including a heat-meltable fluoropolymer is a composition containing a melt moldable tetrafluoroethylene/fluoroalkoxytrifluoroethylene copolymer having an MFR over 60 g/10 minutes.
1. An injection molded article having a trace of a gate at the time of molding and having a projection area of 1100 cm 2 or more and being obtained by injection molding a composition containing a heat-meltable fluoropolymer,
wherein the composition contains a tetrafluoroethylene/fluoroalkoxytrifluoroethylene copolymer as the heat-meltable fluoropolymer, and further a polytetrafluoroethylene in an amount of 0.05 to 10% by weight, relative to the composition,
wherein the projection area of the article is obtained by orthogonal projection of the injection molded article in an injection direction which is a direction perpendicular to the trace of the gate,
wherein the injection area diffusion ratio in a direction orthogonal to an injection direction is 3000 or larger, and
wherein no crack both of fracture and cleavage of the injection molded article is detected when a surface having a size of 1 cm×1 cm and a cross-section of the injection molded article at three positions within 5 cm from a gate center are observed using a polarizing microscope, in a magnification of 100 times and 500 times, respectively.
2. The injection molded article according to claim 1 , wherein the injection area diffusion ratio in the direction orthogonal to the injection direction is 10,000 or larger.
3. The injection molded article according to claim 1 , wherein the injection molded article is an article having a cylinder-shape, a bowl-shape, a box-shape or a basket-shape.
4. The injection molded article according to claim 1 , which comprises being used as a member or a housing thereof, for a semiconductor manufacturing apparatus or a substrate cleaning processing apparatus.
5. The injection molded article according to claim 1 , wherein melt flow rate of the composition containing the heat-meltable fluoropolymer is over 60 g/10 minutes and not more than 68 g/10 minutes.
6. The injection molded article according to claim 1 , wherein the tetrafluoroethylene/fluoroalkoxytrifluoroethylene copolymer has a melt flow rate over 60 g/10 minutes, and the polytetrafluoroethylene has a crystallization temperature of 305° C. or higher and a heat of crystallization of 50 J/g or higher.
7. The injection molded article according to claim 1 , wherein the tetrafluoroethylene/fluoroalkoxytrifluoroethylene copolymer is a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer having a melt flow rate over 60 g/10 minutes.
8. The injection molded article according to claim 6 , wherein the tetrafluoroethylene/fluoroalkoxytrifluoroethylene copolymer is a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer.
9. The injection molded article according to claim 1 , wherein the injection molded article comprises a flat-plate top having a flat top surface and a side wall, and wherein the injection molded article has a difference between a height max and a height min of 1 mm or smaller, the height max and a height min being obtained among heights measured at 8 points on the top surface of the article, using a 3-dimensional measurement device.