Carbon nanofiber aggregate, thermoplastic resin composition, and method for producing thermoplastic resin composition
There is provided a carbon nanofiber aggregate capable of suppressing scatter and having excellent dispersibility and filling property in a thermoplastic resin. A carbon nanofiber aggregate has a maximum void volume P1 (cm 3 /g) at a pore diameter of 2,500 nm or more and 100,000 nm or less and a maximum void volume P2 (cm 3 /g) at a pore diameter of 6 nm or more and less than 2,500 nm in pore distribution data measured by mercury porosimetry. The maximum void volume P1 and the maximum void volume P2 satisfy a specific relationship.
1. A carbon nanofiber aggregate having
a maximum void volume P1 (cm 3 /g) at a pore diameter of 2,500 nm or more and 100,000 nm or less and
a maximum void volume P2 (cm 3 /g) at a pore diameter of 6 nm or more and less than 2,500 nm in pore distribution data measured by mercury porosimetry,
wherein the maximum void volume P1 and the maximum void volume P2 satisfy relationships of the following formulae (1) and (2):
0.01≦ P 1≦1 (1)
0< P 1/ P 2≦3.3 (2)
and wherein the carbon nanofiber aggregate comprises
(A) carbon nanofibers and
(B) a modified rosin;
wherein the carbon nanofiber aggregate comprises 100 parts by mass of component (A), 0.1 to 50 parts by mass of component (B), and 0.01 to 30 parts by mass of (C) a surfactant.
2. The carbon nanofiber aggregate according to claim 1 , wherein the carbon nanofiber aggregate has a three-dimensionally assembled structure as a structure where carbon nanofibers contained in the carbon nanofiber aggregate are entangled with each other.
3. The carbon nanofiber aggregate according to claim 1 or 2 , wherein the carbon nanofiber aggregate has
an integrating void volume Q1 (cm 3 /g) at a pore diameter of 2,500 nm or more and 100,000 nm or less and
an integrating void volume Q2 (cm 3 /g) at a pore diameter of 6 nm or more and less than 2,500 nm in the pore distribution data measured by the mercury porosimetry; and
wherein the integrating void volume Q1 and the integrating void volume Q2 satisfy a relationship of the following formula (3):
0.75≦ Q 2/( Q 1+ Q 2)<1 (3).
4. The carbon nanofiber aggregate according to claim 1 or 2 ,
wherein a content of the carbon nanofiber aggregate having a particle size passing through a sieve having a nominal opening of more than 0.3 mm and 4.75 mm or less specified according to JIS Z8801-1 is 90% by mass or more.
5. The carbon nanofiber aggregate according to claim 4 , wherein a content of the component (B) based on 100 parts by mass of the component (A) is from 0.1 to 40 parts by mass.
6. A thermoplastic resin composition comprising
a thermoplastic resin and
the carbon nanofiber aggregate according to claim 1 or 2 .
7. The thermoplastic resin composition according to claim 6 , wherein an L/D ratio of the carbon nanofiber in the thermoplastic resin composition is 50 or more.
8. The thermoplastic resin composition according to claim 7 , wherein when a slice is cut out from each ten pellets formed from the thermoplastic resin composition by a microtome and slices are observed in a viewing angle of 200 μm×200 μm with an optical microscope (400 times), all long axes of the carbon nanofiber aggregates observed in an observed area of the optical microscope are less than 10 μm.
9. A method for producing a thermoplastic resin composition,
the method comprising the step of melting and kneading a thermoplastic resin and the carbon nanofiber aggregate according to claim 1 or 2 to provide the thermoplastic resin composition.