Candle wax comprising a polymer and method for making candle wax
This invention pertains to candle wax and a method for making candle wax. The candle wax comprises a candle wax base mixture and a polymer wherein the polymer comprises units of the formula (I) wherein X is an alkyl, alkenyl, alkyl maleic anhydride or alkylene-imine; Y is selected from the group consisting of —O—, —S—, —NH—, —NCH 2 —, —NCH 2 CH 2 —, —COO— of which either the carbon or the oxygen group is bound to X, —C(═O)NH, trialkoxysilane, preferably trimethoxysilane or triethoxysilane, benzyl, amide group; Z is H or a C 1 -C 40 alkyl group or a C 1 -C 40 alkenyl group; n is a positive integer, preferably is n>3; if Y is —COO—, then the polymer is a copolymer comprising at least two different units, and if Z is H or a methyl or ethyl, than the polymer is a copolymer comprising at least one unit comprising a C 3 -C 40 alkyl group or C 3 -C 40 alkenyl group.
1. A candle wax, the candle wax comprising:
a mixture of a candle wax base and a polymer, wherein the polymer comprises units having formula (I):
wherein:
X is an alkyl or alkylene-imine;
Y is —C(═O)NH—, or —O— for the case that the X is alkyl, or —(C═O)— for the case that the X is alkyl imine;
Z is an unbranched C 10 to C 40 alkyl group; and
n is a positive integer;
wherein the polymer is a random copolymer with first units and second units, wherein the first units comprise a group Z different from the second unit.
2. The candle wax as claimed in claim 1 , wherein Z in the first unit comprises a palmityl group (C16) and Z in the second unit comprises a stearyl group (C18).
3. The candle wax as claimed in claim 1 , wherein the first unit is present in an amount of 50-95% by weight and the second unit is present in an amount of 5-50% by weight.
4. The candle wax according to claim 1 , wherein X is produced from a monomer chosen from the group consisting of ethylene, 1-propylene, 2-propylene, 1-methyl-2-propylene, 2-methyl-2-propylene, 1-methyl-2-propylene, 1-butylene, 2-butylene, 3-butylene.
5. The candle wax according to claim 1 , wherein Y is O.
6. The candle wax according to claim 5 , wherein Y—Z comprises a C 14 -C 22 alkyl ether.
7. The candle wax according to claim 6 , wherein the polymer comprises a structure according to the formula (IV):
wherein Z1 is a C16 unbranched n-hexadecyl group and Z2 is a C18 unbranched n-octadecyl group, and wherein in and o are positive integers and the sum of in and o is greater than 3.
8. The candle wax according to claim 1 , wherein Y is —C(═O)NH—.
9. The candle wax according to claim 1 , wherein the polymer further comprises vinyl trialkoxysilane groups.
10. The candle wax according to claim 1 , wherein the polymer is a random copolymer with a structure according to formula (IIa), having a first unit (A) and a second unit (B)
wherein:
Z and Z 3 are chosen from the group of unbranched C 14 , C 16 , C 18 , C 20 and C 22 alkyl groups; and
n and p are positive integers and the sum of n and p is greater than 3.
11. A candle comprising a candle wax according to claim 1 .
12. The candle wax according to claim 1 , wherein the candle wax base comprises fatty acids in an amount of more than 90%.
13. The candle wax according to claim 1 , wherein n is greater than 3.
14. The candle wax according to claim 1 , wherein the polymer comprises monomeric units described by the formula:
15. The candle wax according to claim 1 , wherein the polymer comprises monomeric units described by the formula: