Electrode catalyst layer for fuel cell
To provide a catalyst layer for a fuel cell, which exhibits excellent power generation performance even in the case of reducing the used amount of a catalyst. It is an electrode catalyst layer for a fuel cell comprising a catalyst, a porous carrier for supporting the above-mentioned catalyst, and a polymer electrolyte, in which a mode diameter of the pore distribution of the above-mentioned porous carrier is 4 to 20 nm, and the above-mentioned catalyst is supported in a pore with a pore diameter of 4 to 20 nm of the above-mentioned porous carrier.
1. An electrode catalyst layer for a fuel cell consisting essentially of a catalyst, a porous carrier for supporting the catalyst, and a polymer electrolyte, or consisting essentially of a catalyst, a porous carrier for supporting the catalyst, a polymer electrolyte, and liquid proton-conducting material;
wherein a mode diameter of a pore distribution of the porous carrier measured without the supported catalyst is 4 to 20 nm;
the catalyst is supported in a pore with a pore diameter of 4 to 20 nm of the porous carrier;
a pore capacity with a pore diameter of 4 to 20 nm of the porous carrier measured without the supported catalyst is 0.23 to 0.78 cm 3 /g, and
the porous carrier is a graphitized carbon carrier.
2. The electrode catalyst layer according to claim 1 , wherein the catalyst comprises platinum or platinum-containing alloy.
3. The electrode catalyst layer according to claim 2 , wherein a platinum content is 0.20 mg/cm 2 or less.
4. The electrode catalyst layer according to claim 1 , wherein an average particle diameter of the porous carrier measured without the supported catalyst is 20 to 100 nm.
5. The electrode catalyst layer according to claim 1 , further comprising the liquid proton-conducting material capable of connecting the catalyst and the polymer electrolyte in a proton-conductable state between the catalyst and the polymer electrolyte; wherein an electric double layer capacity at an interface between the catalyst/the liquid proton-conducting material, measured in a state such that the liquid proton-conducting material is filled into pores of the porous carrier, is larger than an electric double layer capacity at an interface between the catalyst/the polymer electrolyte.
6. The electrode catalyst layer according to claim 2 , wherein a platinum content per unit catalyst coated area of the electrode catalyst layer is 0.20 mg/cm 2 or less.
7. The electrode catalyst layer according to claim 1 , comprising the polymer electrolyte with an EW of 1000 or less.
8. The electrode catalyst layer according to claim 1 , wherein the catalyst supported in the pore with a pore diameter of 4 to 20 nm is not coated with the polymer electrolyte.
9. The electrode catalyst layer according to claim 1 , wherein the polymer electrolyte does not intrude into the pores of the porous carrier.
10. A membrane electrode assembly for a fuel cell comprising: a solid polymer electrolyte membrane; a cathode catalyst layer disposed on one side of the solid polymer electrolyte membrane; an anode catalyst layer disposed on the other side of the solid polymer electrolyte membrane; and a pair of gas diffusion layers for sandwiching the solid polymer electrolyte membrane, the anode catalyst layer and the cathode catalyst layer; wherein at least one of the cathode catalyst layer and anode catalyst layer is the electrode catalyst layer according to claim 1 .
11. A fuel cell having the membrane electrode assembly according to claim 10 .