Crystalline iron phosphate doped with metal, method of preparing the same, and lithium composite metal phosphate prepared therefrom
Provided are a crystalline iron phosphate doped with metals (MFePO 4 ), which is used as a precursor of olivine-structured LiMFePO 4 (LMFP) used as a cathode active material for lithium secondary batteries, and a method of preparing the crystalline iron phosphate, in which a crystalline iron phosphate doped with metals has the following Formula I obtained by crystallizing amorphous iron phosphate and doping the latter with a different type of a metal. Formula I: MFePO 4 , where M is selected from the group consisting of Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, Mg, and B. The preparation of olivine-structured LMFP, which is used as a cathode active material for lithium secondary batteries, using the crystalline iron phosphate doped with metals as a precursor can increase efficiency and reduce processing costs as compared to another method of preparing the same by mixing different types of metals in a solid state.
1. A crystalline iron phosphate doped with metals represented by the following Formula I, the crystalline iron phosphate doped with metals being doped with different types of metals while crystallizing an amorphous iron phosphate:
MFePO 4 .2H 2 O Formula I
here, M is selected from the group consisting of Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, and Mg,
wherein a crystal structure of the crystalline iron phosphate doped with metals includes Metastrengite 1.
2. The crystalline iron phosphate doped with metals according to claim 1 , wherein a mole ratio of [Fe] and [M] is 1−x:x, and here, x is 0.01 to 0.05.
3. A method of preparing a crystalline iron phosphate doped with metals represented by the following Formula I, the method comprising:
forming an amorphous iron phosphate;
mixing the amorphous iron phosphate thus obtained with a different type of metallic salt; and
crystallizing the amorphous iron phosphate mixed with the different type of metallic salt:
MFePO 4 .2H 2 O Formula I
here, M is selected from the group consisting of Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, and Mg,
wherein a crystal structure of the crystalline iron phosphate doped with metals includes Metastrengite 1.
4. The method according to claim 3 , wherein during crystallizing by mixing the amorphous iron phosphate and the different type of metallic salt, a mole ratio of [Fe] and [M] is 1−x:x, and here, x is 0.01 to 0.05.
5. The method according to claim 3 , wherein the different type of metallic salt has a structure, MX 3 here, M is selected from the group consisting of Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, and Mg, and X is an anion including halogen.
6. The method according to claim 3 , wherein the amorphous iron phosphate in a type of slurry is mixed with an aqueous solution of the different type of metallic salt in a liquid state.