SOLID OXIDE FUEL CELL COMPRISING REACTION PREVENTING LAYER AND METHOD FOR MANUFACTURING SAME
The present invention relates to a solid oxide fuel cell which can improve the overall performance of the cell and obtain durability and reliability, and the invention provides a solid oxide fuel cell comprising a reaction preventing layer and a method for manufacturing the same, wherein an anode, an electrolyte, and a cathode are comprised, and a material which is formed between the electrolyte and the anode comprises 35-90 mol % of gadolinia-doped ceria (GDC) and 10-65 mol % metal oxide.
1 . A solid oxide fuel cell including a reaction preventing layer, comprising:
an anode;
an electrolyte;
a cathode; and
a reaction preventing layer disposed between the electrolyte and the cathode and formed of a material including 35 mol % to 90 mol % of gadolinia doped ceria (GDC) and 10 mol % to 65 mol % of a metal oxide.
2 . The solid oxide fuel cell of claim 1 , wherein the metal oxide is selected from the group consisting of alumina (Al 2 O 3 ), ceria (CeO 2 ), gadolinia (Gd 2 O 3 ), yttria (Y 2 O 3 ), and zirconia (ZrO 2 ).
3 . The solid oxide fuel cell of claim 1 , wherein the cathode includes strontium (Sr), and
the electrolyte includes a zirconium (Zr) oxide.
4 . The solid oxide fuel cell of claim 1 , wherein the reaction preventing layer has pores with the size of 0.1 μm or below.
5 . The solid oxide fuel cell of claim 1 , wherein the reaction preventing layer is formed by an aerosol deposition method (ADM).
6 . The solid oxide fuel cell of claim 1 , wherein the reaction preventing layer has a thickness of 0.1 μm to 2 μm.
7 . A method of manufacturing a solid oxide fuel cell including a reaction preventing layer, the method comprising:
forming an anode layer;
forming a solid oxide electrolyte layer on the anode layer;
forming a reaction preventing layer on the electrolyte layer by depositing a material including 35 mol % to 90 mol % of gadolinia doped ceria (GDC) and 10 mol % to 65 mol % of a metal oxide through an aerosol deposition method (ADM) ; and
forming a cathode layer on the reaction preventing layer,
8 . The method of claim 7 , wherein the metal oxide is selected from the group consisting of alumina (Al 2 O 3 ), ceria (CeO 2 ), gadolinia (Gd 2 O 3 ) yttria (Y 2 O 3 ), and zirconia (ZrO 2 ).
9 . The method of claim 7 , further comprising heating the cathode layer at 950° C. to 1100° C.
10 . The method of claim 7 , wherein the forming of the reaction preventing layer through the ADM may be performed by allowing carrier gas to cause a mixed powder including 1 wt % to 20 wt % of the metal oxide in addition to the GDC to impact a surface of the electrolyte layer at a speed of 100 m/sec to 500 m/sec.
11 . The method of claim 7 , wherein the reaction preventing layer is formed to have a thickness of 0.1 μm to 2 μm.