Method for reducing color in used lubricating oil
A method for reducing color in used lubricating oil. The method comprises combining: (i) a used lubricating oil; (ii) an alkali metal borohydride; and (iii) a bisulfite or metabisulfite salt.
1. A method for reducing color in used lubricating oil comprising
(a) combining an aqueous alkali metal borohydride mixture comprising from about 1% to about 40% alkali metal borohydride and from about 10% to about 45% alkali metal hydroxide with a bisulfite or metabisulfite salt to provide an aqueous alkali metal dithionite reagent, and
(b) contacting the aqueous alkali metal dithionite reagent with a used lubricating oil to provide a used lubricating oil purification composition.
2. The method of claim 1 , wherein a molar ratio of bisulfite or metabisulfite to alkali metal borohydride is from 4:1 to 8:1.
3. The method of claim 2 , wherein the alkali metal borohydride in step (a) is used in an amount from 0.01 wt % to 0.1 wt %, based on weight of the used lubricating oil.
4. The method of claim 3 , wherein the aqueous alkali metal borohydride mixture is an aqueous sodium borohydride mixture.
5. The method of claim 4 , wherein the sodium borohydride in step (a) is used in an amount from 0.02 wt % to 0.08 wt %, based on weight of the used lubricating oil.
6. The method of claim 1 , further comprising
(c) distilling the used lubricating oil purification composition to remove water and other volatile compounds.
7. The method of claim 6 , wherein from 5% to 30% of the total mass of the used lubricating oil purification composition is removed by distilling.
8. The method of claim 1 , wherein the aqueous alkali metal borohydride mixture comprises from about 10% to about 25% alkali metal borohydride and from about 17% to about 25% alkali metal hydroxide.
9. The method of claim 3 , wherein the aqueous alkali metal borohydride mixture comprises from about 10% to about 25% alkali metal borohydride and from about 17% to about 25% alkali metal hydroxide.
10. The method of claim 4 , wherein the aqueous alkali metal borohydride mixture comprises from about 10% to about 25% alkali metal borohydride and from about 17% to about 25% alkali metal hydroxide.