Hydrophobized gas diffusion layers and method of making the same
A gas diffusion layer having a first major surface and a second major surface which is positioned opposite to said first major surface and an interior between said first and second major surfaces is formed. The gas diffusion layer comprises a porous carbon substrate which is directly fluorinated in the interior and is substantially free of fluorination on at least one of the first major surfaces or the second major surfaces, and preferably both surfaces. The gas diffusion layer may be formed using protective sandwich process during direct fluorination or by physically or chemically removing the C—F atomic layer at the major surfaces, for example by physical plasma etching or chemical reactive ion etching.
1. A gas diffusion layer having electron conductivity and gas diffusibility, the gas diffusion layer having a first major surface and a second major surface which is positioned opposite to said first major surface and an interior between said first and second major surfaces; wherein said gas diffusion layer comprises a porous carbon substrate having interior pores with interior pore surfaces, which interior pore surfaces have been directly fluorinated and wherein said gas diffusion layer is substantially free of fluorination on at least one of said first major surface or said second major surface.
2. The gas diffusion layer of claim 1 wherein at least about 80% of the surface area of the first major surface is not fluorinated.
3. The gas diffusion layer of claim 1 wherein at least about 80% of the surface area of the first major surface is not fluorinated and at least 80% of the surface area of the second major surface is not fluorinated.
4. The gas diffusion layer of claim 1 wherein gas diffusion layer contains less than about 2 wt % fluorine.
5. The gas diffusion layer of claim 1 in which said porous carbon substrate comprises a macroporous carbon substrate adjacent a microporous carbon substrate such that the gas diffusion layer is a bilayer having said first major surface comprised of the microporous carbon substrate and said second major surface comprised of the macroporous carbon substrate.
6. The gas diffusion layer of claim 5 wherein at least about 60% of the surface area of the first major surface is not fluorinated.
7. The gas diffusion layer of claim 5 wherein at least about 60% of the surface area of the first major surface is not fluorinated and at least 60% of the surface area of the second major surface is not fluorinated.
8. A fuel cell comprising the gas diffusion layer of claim 1 .
9. The fuel cell of claim 8 , comprising two of said gas diffusion layers.
10. The fuel cell of claim 8 , further comprising:
a membrane-electrode assembly including a polymer electrolyte membrane; and
a pair of catalyst layers sandwiching said polymer electrolyte membrane.
11. The fuel cell of claim 10 , wherein the polymer electrolyte membrane is a proton exchange membrane.
12. The fuel cell of claim 8 wherein at least about 80% of the surface area of the first major surface of the gas diffusion layer is not fluorinated.
13. The fuel cell of claim 8 wherein at least about 80% of the surface area of the first major surface of the gas diffusion layer is not fluorinated and at least 80% of the surface area of the second major surface of the gas diffusion layer is not fluorinated.
14. The fuel cell of claim 8 wherein the gas diffusion layer contains less than about 2 wt % fluorine.
15. The fuel cell of claim 8 in which said porous carbon substrate of the gas diffusion layer comprises a macroporous carbon substrate adjacent a microporous carbon substrate such that the gas diffusion layer is a bilayer having said first major surface comprised of the microporous carbon substrate and said second major surface comprised of the macroporous carbon substrate.
16. The fuel cell of claim 8 wherein at least about 60% of the surface area of the first major surface of the gas diffusion layer is not fluorinated.
17. The fuel cell of claim 8 wherein at least about 60% of the surface area of the first major surface of the gas diffusion layer is not fluorinated and at least 60% of the surface area of the second major surface of the gas diffusion layer is not fluorinated.
18. The gas diffusion layer of claim 1 , wherein said direct fluorination comprises contacting said interior pore surfaces with fluorine gas.
19. The gas diffusion layer of claim 1 , wherein all of said interior pore surfaces are covered with fluorine.
20. A fuel cell comprising:
a membrane-electrode assembly including a hydrogen ion conductive polymer electrolyte membrane;
a pair of catalyst layers sandwiching said polymer electrolyte membrane;
and a pair of gas diffusion layers disposed on the outer surfaces of said catalyst layers;
the gas diffusion layers having electron conductivity and gas diffusibility, the gas diffusion layers each having a first major surface and a second major surface which is positioned opposite to said first major surface and an interior between said first and second major surfaces;
wherein said gas diffusion layers comprise a porous carbon substrate having interior pores with interior pore surfaces, which interior pore surfaces have been directly fluorinated, and wherein said gas diffusion layer is substantially free of fluorination on at least one of said first major surface or said second major surface.
21. The fuel cell of claim 20 wherein at least about 80% of the surface area of the first major surface is not fluorinated.
22. The fuel cell of claim 20 wherein at least about 80% of the surface area of the first major surface is not fluorinated and at least 80% of the surface area of the second major surface is not fluorinated.
23. The fuel cell of claim 20 wherein at least one gas diffusion layer contains less than about 2 wt % fluorine.
24. The fuel cell of claim 20 in which said porous carbon substrate comprises a macroporous carbon substrate adjacent a microporous carbon substrate such that the gas diffusion layer is a bilayer having said first major surface comprised of the microporous carbon substrate and said second major surface comprised of the macroporous carbon substrate.
25. The fuel cell of claim 20 wherein at least about 60% of the surface area of the first major surface is not fluorinated.
26. The fuel cell of claim 20 wherein at least about 60% of the surface area of the first major surface is not fluorinated and at least 60% of the surface area of the second major surface is not fluorinated.