IP Library Granted Patent US 10,175,577
Granted Patent B2
US 10,175,577 · App. 14/377,323 · Granted Jan 8, 2019

Photosensitive resin composition, method for manufacturing patterned cured film, and electronic component

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Quick Facts
Patent No.
US 10,175,577
App. No.
14/377,323
Granted
Jan 8, 2019
Kind
B2
Abstract

The invention provides a photosensitive resin composition comprising (A) an alkali-soluble resin having a phenolic hydroxyl group, (B) a compound that generates an acid by light, and (C) an acrylic resin having a group that crosslinks with the component (A), as well as a method for manufacturing a patterned cured film, and an electronic component prepared therewith.

Claims (21)

1. A photosensitive resin composition comprising:

(A) an alkali-soluble resin having a phenolic hydroxyl group;

(B) a compound that generates an acid by light; and

(C) an acrylic resin having a group that crosslinks with the component (A),

wherein the component (C) is an acrylic resin comprising a structural unit represented by the following formula (1):

wherein R 1 represents a hydrogen atom or a methyl group, and R 2 represents an organic group having a group that crosslinks with the component (A),

wherein the group that cross links with the component (A) is epoxy group, and

wherein the photosensitive resin composition comprises 1-50 parts by mass of the component (C) with respect to 100 parts by mass of the component (A),

wherein the component (C) further comprises a structural unit represented by the following formula (2)

wherein R 3 represents a hydrogen atom or a methyl group, and R 4 represents a C4-20 alkyl group,

wherein the component (C) further comprises a structural unit represented by the following formula (3) or (4), and

wherein the component (A) comprises at least one selected from the group consisting of a poly(hydroxvstvrene)-based resin, a phenol resin, a polybenzooxazole precursor, a poly(hvdroxyphenylene)ether, a polynaphthol and a mixture thereof.

2. The photosensitive resin composition according to claim 1 , wherein the component (A) is a phenol resin.

3. The photosensitive resin composition according to claim 1 , wherein the component (B) is an o-quinone diazide compound.

4. The photosensitive resin composition according to claim 1 , further comprising (E) an acrylic resin that does not contain a group that crosslinks with the component (A).

5. The photosensitive resin composition according to claim 1 , further comprising (F) a heat acid generator.

6. The photosensitive resin composition according to claim 1 , wherein the compositional ratio of the structural unit represented by formula (1) in the acrylic resin of component (C) is 1 to 25 mol % with respect to the total amount of component (C).

7. A method for manufacturing a patterned cured film, the method comprising coating the photosensitive resin composition according to claim 1 onto a substrate and drying the coated photosensitive resin composition to form a resin film, exposing the resin film to light, developing the exposed resin film with an aqueous alkali solution to form a patterned resin film, and heating the patterned resin film.

8. The method for manufacturing a patterned cured film according to claim 7 , wherein a heating temperature in the heating of the patterned resin film is no higher than 250° C.

9. An electronic component having a patterned cured film produced by the method for manufacturing a patterned cured film according to claim 7 as an interlayer insulating layer or a surface protective layer.

10. The electronic component having a patterned cured film produced by the method for manufacturing a patterned cured film according to claim 7 as a cover coat layer, core, collar or underfill.

Assignments (4)
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CHANGE OF NAME Recorded Mar 3, 2023
From: SHOWA DENKO MATERIALS CO., LTD.
To: RESONAC CORPORATION
Reel/Frame 062946/0125 →
CHANGE OF NAME Recorded Mar 2, 2023
From: HITACHI CHEMICAL COMPANY, LTD.
To: SHOWA DENKO MATERIALS CO., LTD.
Reel/Frame 062917/0865 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 16, 2014
From: TAHARA, SHINGO; KATOGI, SHIGEKI; MATSUTANI, HIROSHI; ABE, KOUICHI; TANIMOTO, AKITOSHI; AOKI, YU
To: HITACHI CHEMICAL COMPANY, LTD.
Reel/Frame 034522/0213 →