Coated film
According to the present invention, there is provide a coated film capable of exhibiting an excellent adhesion property to a prism resin used in optical applications such as a backlight unit for liquid crystal displays, etc., in particular, a prism resin adaptable for high-brightness prisms, i.e., a high-refractive index prism resin. The coating film of the present invention comprises a polyester film and a coating layer formed on at least one surface of the polyester film which is prepared from a coating solution comprising a (meth)acrylate (A) and at least one crosslinking agent (B) selected from the group consisting of an oxazoline compound, an isocyanate-based compound and a melamine compound.
1. A coated film comprising:
a polyester film;
a coating layer having a thickness of 0.002 to 0.2 μm and formed on at least one surface of the polyester film which is prepared from a coating solution comprising a (meth)acrylate (A) and at least one crosslinking agent (B) selected from the group consisting of an oxazoline compound, an isocyanate-based compound and a melamine compound; and
a surface functional layer which is formed from a solvent-free active energy ray-curable resin on a surface of the coating layer and has a refractive index of 1.56 to 1.65.
2. The coated film according to claim 1 , wherein a content of a carbon-carbon double bond in the (meth)acrylate (A) is not less than 3% by weight.
3. The coated film according to claim 1 , wherein the (meth)acrylate (A) is a polyfunctional (meth)acrylate.
4. The coated film according to claim 1 , wherein a content of the (meth)acrylate (A) in the coating solution is 5 to 95% by weight, and a content of the crosslinking agent (B) in the coating solution is 5 to 95% by weight, both based on a total amount of whole non-volatile components in the coating solution.
5. The coated film according to claim 1 , wherein the coating solution further comprises particles having an average particle diameter of not more than 1.0 μm, and a content of the particles in the coating solution is not more than 25% by weight based on a total amount of whole non-volatile components in the coating solution.
6. The coated film according to claim 1 , wherein the isocyanate-based compound is selected from the group consisting only of tolylene diisocyanate, xylylene diisocyanate, methylene diphenyl diisocyanate, phenylene diisocyanate, naphthalene diisocyanate, α,α,α′,α′-tetramethyl xylylene diisocyanate, methylene diisocyanate, propylene diisocyanate, lysine diisocyanate, trimethyl hexamethylene diisocyanate, hexamethylene diisocyanate, cyclohexane diisocyanate, methyl cyclohexane diisocyanate, isophorone diisocyanate, methylene-bis(4-cyclohexyl isocyanate), isopropylidene dicyclohexyl diisocyanate, biuret compounds, isocyanurate compounds, uretdione compounds, carbodiimide-modified compounds of isocyanates, blocked isocyanates, and combinations thereof.
7. The coated film according to claim 6 , wherein blocking agents used in the production of the blocked isocyanates are selected from the group consisting only of bisulfites; phenol, cresol, ethyl phenol, propylene glycol monomethyl ether, ethylene glycol, benzyl alcohol, methanol, ethanol, dimethyl malonate, diethyl malonate, methyl acetoacetate, ethyl acetoacetate, acetyl acetone, butyl mercaptan, dodecyl mercaptan, ε-caprolactam and δ-valerolactam, diphenyl aniline, aniline and ethylene imine, acetanilide, acetic acid amide, formaldehyde, acetaldoxime, acetone oxime, methyl ethyl ketone oxime, cyclohexanone oxime, and combinations thereof.
8. A coated film comprising:
a polyester film, and
a coating layer having a thickness of 0.002 to 0.2 μm and formed on at least one surface of the polyester film which is prepared from a coating solution comprising a (meth)acrylate (A) and at least one crosslinking agent (B) selected from the group consisting of an oxazoline compound, an isocyanate-based compound and a melamine compound,
wherein non-volatile components in the coating solution consist only of a (meth)acrylate (A) and at least one crosslinking agent (B) selected from the group consisting of an oxazoline compound, an isocyanate-based compound and a melamine compound.