Surface treatment method for aluminum heat exchangers
A surface treatment method for aluminum heat exchangers including (a) a step wherein a chemical conversion coating film is formed on the surface of an aluminum heat exchanger by subjecting the aluminum heat exchanger to chemical conversion using a chemical conversion agent; (b) a step wherein the aluminum heat exchanger, the surface of which has been provided with a chemical conversion coating film in step (a), is brought into contact with a hydrophilizing agent that contains a hydrophilic resin; and (c) a step wherein a hydrophilized coating film is formed on the surface of the aluminum heat exchanger by baking the aluminum heat exchanger, which has been subjected to a contact treatment in step (b). The chemical conversion agent used in step (a) contains zirconium and/or titanium in an amount of 5-5,000 ppm by mass in total, vanadium in an amount of 10-1,000 ppm by mass and a metal stabilizer in an amount of 5-5,000 ppm by mass. In addition, the chemical conversion agent used in step (a) has a pH of 2-6.
1. A surface treatment method for an aluminum heat exchanger, comprising:
(a) a step of forming a chemical conversion film on a surface of the aluminum heat exchanger using a chemical conversion treatment agent;
(b) a step of bringing the aluminum heat exchanger on which the chemical conversion film was formed on the surface in the step (a) into contact with a hydrophilization treatment agent containing a hydrophilic resin; and
(c) a step of forming a hydrophilized film on the surface by baking the aluminum heat exchanger that was contact treated in the step (b),
wherein the chemical conversion treatment agent used in the step (a) contains both zirconium and titanium, wherein a content thereof is 10 to 2,500 ppm by mass in total, contains vanadium, wherein a content thereof is 100 to 500 ppm by mass, contains a metal stabilizer, wherein a content thereof is 10 to 2,000 ppm by mass, and has a pH of 3 to 5.
2. The surface treatment method for aluminum heat exchanger according to claim 1 , wherein the metal stabilizer is at least one selected from the group consisting of organic compounds having reducibility and iminodiacetic acid derivatives.
3. The surface treatment method for aluminum heat exchanger according to claim 2 , wherein:
in the chemical conversion film formed in the step (a), a total of an amount of zirconium and an amount of titanium is 5 to 300 mg/m 2 , an amount of vanadium is 1 to 150 mg/m 2 , and an amount of metal stabilizer is 0.5 to 200 mg/m 2 in terms of carbon, and
a film amount of the hydrophilized film formed in the step (c) is 0.05 to 5 g/m 2 .
4. The surface treatment method for aluminum heat exchanger according to claim 2 , wherein
the hydrophilization treatment agent used in the step (b) further comprises at least one of a guanidine compound represented by general formula (1) below and a salt thereof,
wherein, in formula (1), Y represents —C(═NH)—(CH 2 ) m —, —C(═O)—NH—(CH 2 ) m —, or —C(═S)—NH—(CH 2 ) m —;
m represents an integer of 0 to 20; n represents a positive integer; k represents 0 or 1;
X represents hydrogen, an amino group, hydroxyl group, methyl group, phenyl group, chlorophenyl group or methylphenyl group;
Z represents hydrogen, an amino group, hydroxyl group, methyl group, phenyl group, chlorophenyl group, methylphenyl group, or a polymer represented by general formula (2) below having a mass average molecular weight of 200 to 1,000,000; and
wherein p in formula (2) represents a positive integer.
5. The surface treatment method for aluminum heat exchanger according to claim 4 , wherein the guanidine compound and salt thereof are a compound having a biguanide structure represented by general formula (3) below and a salt thereof
6. The surface treatment method for aluminum heat exchanger according to claim 4 , wherein
the hydrophilization treatment agent used in the step (b) further comprises at least one selected from the group consisting of phosphoric acid, condensed phosphoric acid, phosphonic acid, derivatives thereof and lithium ion.
7. The surface treatment method for aluminum heat exchanger according to claim 4 , wherein
the hydrophilic resin in the hydrophilization treatment agent used in the step (b) further comprises at least one of a polyvinyl alcohol and a modified-polyvinyl alcohol having a degree of saponification of at least 90%.
8. The surface treatment method for aluminum heat exchanger according to claim 4 , wherein the aluminum heat exchanger is flux brazed.
9. The surface treatment method for aluminum heat exchanger according to claim 4 , wherein the aluminum heat exchanger is flux brazed according to the Nocolok brazing process.
10. The according to claim 1 , wherein the hydrophilization treatment agent used in the step (b) further comprises at least one of a guanidine compound represented by general formula (1) below and a salt thereof,
wherein, in formula (1), Y represents —C(═NH)—(CH 2 ) m —, —C(═O)—NH—(CH 2 ) m —, or —C(═S)—NH—(CH 2 ) m ;
m represents an integer of 0 to 20; n represents a positive integer; k represents 0 or 1;
X represents hydrogen, an amino group, hydroxyl group, methyl group, phenyl group, chlorophenyl group or methylphenyl group;
Z represents hydrogen, an amino group, hydroxyl group, methyl group, phenyl group, chlorophenyl group, methylphenyl group, or a polymer represented by general formula (2) below having a mass average molecular weight of 200 to 1,000,000; and
wherein p in formula (2) represents a positive integer.
11. An aluminum heat exchanger, comprising:
a chemical conversion film formed on a surface of the aluminum heat exchanger using a chemical conversion treatment agent;
a hydrophilized film formed by baking treatment, after bringing the aluminum heat exchanger on which the chemical conversion film was formed into contact with a hydrophilization treatment agent containing a hydrophilic resin,
wherein the chemical conversion film is formed by the chemical conversion treatment agent that contains both zirconium and titanium, wherein a content thereof is 10 to 2,500 ppm by mass in total, contains vanadium, wherein a content thereof is 100 to 500 ppm by mass, contains a metal stabilizer, wherein a content thereof is 10 to 2,000 ppm by mass, and has a pH of 3 to 5,
wherein the metal stabilizer is at least one selected from the group consisting of organic compounds having reducibility and iminodiacetic acid derivatives, and
wherein the chemical conversion film includes the metal stabilizer.
12. The aluminum heat exchanger according to claim 11 , wherein in the chemical conversion film, a total of an amount of zirconium and an amount of titanium is 5 to 300 mg/m 2 , an amount of vanadium is 1 to 150 mg/m 2 , and an amount of metal stabilizer is 0.5 to 200 mg/m 2 in terms of carbon, and a film amount of the hydrophilized film is 0.05 to 5 g/m 2 .
13. The aluminum heat exchanger according to claim 11 , wherein
the hydrophilization treatment agent further comprises at least one of a guanidine compound represented by general formula (1) below and a salt thereof, and
the chemical conversion film includes the hydrophilic resin and at least one of a guanidine compound represented by general formula (1) below and a salt thereof,
wherein, in formula (1), Y represents —C(═NH)—(CH 2 ) m —, —C(═O)—NH—(CH 2 ) m —, or —C(═S)—NH—(CH 2 ) m ;
m represents an integer of 0 to 20; n represents a positive integer; k represents 0 or 1;
X represents hydrogen, an amino group, hydroxyl group, methyl group, phenyl group, chlorophenyl group or methylphenyl group;
Z represents hydrogen, an amino group, hydroxyl group, methyl group, phenyl group, chlorophenyl group, methylphenyl group, or a polymer represented by general formula (2) below having a mass average molecular weight of 200 to 1,000,000; and
wherein p in formula (2) represents a positive integer.
14. The aluminum heat exchanger according to claim 13 , wherein the guanidine compound and salt thereof are a compound having a biguanide structure represented by general formula (3) below and a salt thereof
15. The aluminum heat exchanger according to claim 11 , wherein the hydrophilic resin further comprises at least one of a polyvinyl alcohol and modified-polyvinyl alcohol having a degree of saponification of at least 90%.
16. The aluminum heat exchanger according to claim 11 , wherein the aluminum heat exchanger is flux brazed.
17. The aluminum heat exchanger according to claim 11 , wherein the aluminum heat exchanger is flux brazed according to the Nocolok brazing process.