IP Library Granted Patent US 9,929,432
Granted Patent B2
US 9,929,432 · App. 14/385,030 · Granted Mar 27, 2018

Low temperature sulfur and sodium metal battery for grid-scale energy storage application

Inventors: Gao Liu (Piedmont, CA); Dongdong Wang (Berkeley, CA)
Assignee: The Regents of the University of California
H01M10/054H01M2/1653H01M4/40H01M4/604H01M10/056H01M10/0565H01M10/3918H01M10/3954H01M2/1673H01M4/661H01M2300/002H01M2300/0082
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Quick Facts
Patent No.
US 9,929,432
App. No.
14/385,030
Granted
Mar 27, 2018
Kind
B2
Abstract

A re-chargeable battery comprising a non-dendrite forming sodium (Na)/potassium (K) liquid metal alloy anode, a sulfur and polyacrylonitrile (PAN) conductive polymer composite cathode, a polyethyleneoxide (PEO) solid electrolyte, a solid electrolyte interface (SEI) formed on the PEO solid electrolyte; and a cell housing, wherein the anode, cathode, and electrolyte are assembled into the cell housing with the PEO solid electrolyte disposed between the cathode and anode.

Claims (16)

1. A re-chargeable battery comprising:

a non-dendrite forming sodium (Na)/potassium (K) liquid metal alloy anode;

a sulfur and polyacrylonitrile (PAN) conductive polymer composite cathode;

a polyethyleneoxide (PEO) solid electrolyte;

a solid electrolyte interface (SEI) directly in contact with the PEO solid electrolyte, wherein the PEO solid electrolyte completely surrounds the sulfur and PAN composite cathode; and

a cell housing, wherein the anode, cathode, and electrolyte are assembled into the cell housing.

2. The re-chargeable battery of claim 1 , wherein the PEO solid electrolyte comprises a sodium triflate salt and a potassium triflate salt.

3. The re-chargeable battery of claim 1 , wherein a potassium concentration in the sodium and potassium alloy is approximately 40% K to 90% K by weight.

4. The re-chargeable battery of claim 2 , wherein the sodium and potassium liquid metal alloy is approximately 56% K and 44% Na by weight.

5. The re-chargeable battery of claim 1 , wherein the PEO is cross-linked.

6. The re-chargeable battery of claim 5 , wherein the PEO is UV cross-linked with a benzophenone initiator.

7. The re-chargeable battery of claim 1 , wherein the PEO solid electrolyte is a Na/K ion conducting membrane.

8. The re-chargeable battery of claim 1 , wherein the PEO solid electrolyte prevents the anode from contacting the cathode.

9. The re-chargeable battery of claim 1 , wherein the PEO oxygen to Na ion ratio is at 20:1 and the PEO oxygen to K ion ratio is at 20:1.

10. The re-chargeable battery of claim 1 wherein the anode comprises a copper Cu current collector.

11. The re-chargeable battery of claim 1 , wherein the cathode comprises an aluminum Al current collector.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 4, 2016
From: LIU, GAO; WANG, DONGDONG
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 038187/0243 →
CONFIRMATORY LICENSE Recorded Dec 15, 2014
From: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 034756/0868 →
Continuity (2)
Provisional Application 61611140 · Mar 15, 2012
Related Publication 20150044545A1 · Feb 12, 2015