Low temperature sulfur and sodium metal battery for grid-scale energy storage application
A re-chargeable battery comprising a non-dendrite forming sodium (Na)/potassium (K) liquid metal alloy anode, a sulfur and polyacrylonitrile (PAN) conductive polymer composite cathode, a polyethyleneoxide (PEO) solid electrolyte, a solid electrolyte interface (SEI) formed on the PEO solid electrolyte; and a cell housing, wherein the anode, cathode, and electrolyte are assembled into the cell housing with the PEO solid electrolyte disposed between the cathode and anode.
1. A re-chargeable battery comprising:
a non-dendrite forming sodium (Na)/potassium (K) liquid metal alloy anode;
a sulfur and polyacrylonitrile (PAN) conductive polymer composite cathode;
a polyethyleneoxide (PEO) solid electrolyte;
a solid electrolyte interface (SEI) directly in contact with the PEO solid electrolyte, wherein the PEO solid electrolyte completely surrounds the sulfur and PAN composite cathode; and
a cell housing, wherein the anode, cathode, and electrolyte are assembled into the cell housing.
2. The re-chargeable battery of claim 1 , wherein the PEO solid electrolyte comprises a sodium triflate salt and a potassium triflate salt.
3. The re-chargeable battery of claim 1 , wherein a potassium concentration in the sodium and potassium alloy is approximately 40% K to 90% K by weight.
4. The re-chargeable battery of claim 2 , wherein the sodium and potassium liquid metal alloy is approximately 56% K and 44% Na by weight.
5. The re-chargeable battery of claim 1 , wherein the PEO is cross-linked.
6. The re-chargeable battery of claim 5 , wherein the PEO is UV cross-linked with a benzophenone initiator.
7. The re-chargeable battery of claim 1 , wherein the PEO solid electrolyte is a Na/K ion conducting membrane.
8. The re-chargeable battery of claim 1 , wherein the PEO solid electrolyte prevents the anode from contacting the cathode.
9. The re-chargeable battery of claim 1 , wherein the PEO oxygen to Na ion ratio is at 20:1 and the PEO oxygen to K ion ratio is at 20:1.
10. The re-chargeable battery of claim 1 wherein the anode comprises a copper Cu current collector.
11. The re-chargeable battery of claim 1 , wherein the cathode comprises an aluminum Al current collector.