Medical ceramic material and manufacturing method thereof
The present invention provides a medical ceramic material with a color other than black or white, especially blue, with which it is possible to secure sufficient durability and to maintain a good appearance by sufficiently suppressing a color difference between before and after the irradiation of gamma-rays for sterilization. The medical ceramic material is formed using a composite material containing alumina and zirconia. The composite material contains cobalt oxide. The content of cobalt oxide is set to be 0.2 wt % to 1.0 wt % with respect to 100 wt % of the composite material excluding cobalt oxide.
1. A medical ceramic material formed using a composite material containing alumina and zirconia, wherein
the composite material contains cobalt oxide, and the cobalt oxide is greater than 0.2 wt % to 1.0 wt % with respect to 100 wt % of the composite material excluding the cobalt oxide,
the composite material further contains titanium dioxide and at least one of strontium oxide, silicon dioxide, and magnesium oxide;
the composite materials are composed of particles with an average particle diameter of the particles of 1.0 micron or less; and
a color difference (ΔE) measured in the medical ceramic is less than 3.5 after the medical ceramic undergoes gamma irradiation sterilization.
2. The medical ceramic material according to claim 1 ,
wherein the cobalt oxide is greater than 0.2 wt % and less than 0.5 wt %.
3. A method for manufacturing a medical ceramic material comprising:
a mixing step of mixing powders of at least alumina, zirconia, cobalt oxide, and titanium dioxide and at least one of strontium oxide, silicon dioxide, and magnesium oxide to form a mixed powder;
a pressing step of pressing the mixed powder to form a powder compact; and
a firing step of firing the powder compact to form a sintered body,
wherein the cobalt oxide contained in the mixed powder is greater than 0.2 wt % and less than 1.0 wt % with respect to 100 wt % of the mixed powder formed in the mixing step excluding the cobalt oxide,
wherein a color difference (ΔE) measured in the medical ceramic is less than 3.5 after the medical ceramic undergoes gamma irradiation sterilization
wherein an average particle diameter of the particles contained in the sintered body is 1.0 micron or less.
4. The method for manufacturing a medical ceramic material according to claim 3 ,
wherein the cobalt oxide in the mixing step includes tricobalt tetroxide.
5. The medical ceramic material of claim 1 , wherein the cobalt oxide includes tricobalt tetroxide.