Modified nano-silica and method for preparing the same, pigment dispersion and photosensitive resin composition
The invention relates to the field of materials technology and provides a modified nano-silica and a method for preparing the same, a pigment dispersion and a photosensitive resin composition, so as to solve the problem that conventional nano-silica cannot crosslink with other polymeric materials, and pigment dispersions are apt to aggregate and have a poor film-forming property. The modified nano-silica according to the invention has unsaturated double bonds on the surface thereof and can crosslink with other polymeric materials, such that the pigment dispersion comprising the modified nano-silica can effectively prevent agglomeration and has a good film-forming property, and the photosensitive resin composition comprising the pigment dispersion can reduce the thermal expansion of a film made thereby, as well as the occurrence of shrinkage and collapse phenomena in the surface of the film, and enhance the heat-resistance, chemical-resistance, mechanical properties and abrasion-resistance of the film.
1. A pigment dispersion, characterized in that the pigment dispersion is prepared by dispersing a solute in a solvent and inducing a crosslinking reaction therein, and the average particle size of the solid particles in the pigment dispersion ranges from 40 nm to 100 nm; and
the solute comprises: based on 100% by mass of the pigment dispersion, 1% to 5% of modified nano-silica particles which have unsaturated double bonds grafted on the surface thereof and have an average particle size in the range of 5 nm to 50 nm, 3% to 6% of a dispersant, 2% to 6% of a binder resin, 10% to 20% of pigment, and 0.1% to 0.5% of a photoinitiator.
2. The pigment dispersion according to claim 1 , characterized in that the solute further comprises 0.2% to 1% of quantum dots, based on 100% by mass of the pigment dispersion.
3. The pigment dispersion according to claim 2 , characterized in that the particle size of the quantum dots is in the range of 1 nm to 10 nm.
4. The pigment dispersion according to claim 1 , characterized in that the dispersant is a block copolymer composed of segment(s) having affinity to the solvent and segment(s) comprising a nitrogen atom-containing functional group.
5. The pigment dispersion according to claim 4 , characterized in that the block copolymer is one or more of acrylic block copolymers composed of segment(s) having affinity to the solvent and segment(s) comprising a nitrogen atom-containing functional group, polyurethane block copolymers composed of segment(s) having affinity to the solvent and segment(s) comprising a nitrogen atom-containing functional group, polyaminoamide block copolymers composed of segment(s) having affinity to the solvent and segment(s) comprising a nitrogen atom-containing functional group, polyether ester block copolymers composed of segment(s) having affinity to the solvent and segment(s) comprising a nitrogen atom-containing functional group, and aliphatic polycarboxylic acid block copolymers composed of segment(s) having affinity to the solvent and segment(s) comprising a nitrogen atom-containing functional group.
6. The pigment dispersion according to claim 1 , characterized in that the pigment is one or more of azo, phthalocyanine, quinacridone, benzimidazolone, indanthrene, and dioxazine pigments.
7. The pigment dispersion according to claim 1 , characterized in that the binder resin has unsaturated double bonds.
8. The pigment dispersion according to claim 7 , characterized in that the binder resin is one or more of polyvinyl alcohols, hydroxypropyl celluloses, carboxymethyl celluloses, hydroxyethyl celluloses, methyl celluloses, styrene-acrylic acid resins, styrene-acrylic acid-acrylate resins, styrene-maleic half ester resins, methacrylic acid-methacrylate resins, isobutylene-maleic acid resins, rosin-modified maleic acid resins, polyvinyl pyrrolidone, polyallylamine, polyvinyl chloride, chlorinated polypropylene, and polyethylene imine, each having unsaturated double bonds.
9. The pigment dispersion according to claim 1 , characterized in that the photoinitiator is one or more of benzoin and its derivatives, benzil, alkylphenone, acyl phosphorus oxides, benzophenones, thioxanthones, diaryl iodonium salts, triaryl iodonium salts, alkyl iodonium salts, and cumene ferrocene hexafluorophosphate.
10. A photosensitive resin composition, characterized by comprising: based on 100% by mass of the photosensitive resin composition, 30% to 40% of a pigment dispersion, 1.5% to 6% of an alkali-soluble resin, 2% to 5% of a polymerizable monomer, and 0.2% to 0.8% of a photoinitiator,
wherein the pigment dispersion is prepared by dispersing a solute in a solvent and inducing a crosslinking reaction therein, and the average particle size of the solid particles in the pigment dispersion ranges from 40 nm to 100 nm; and
wherein the solute comprises: based on 100% by mass of the pigment dispersion, 1% to 5% of a modified nano-silica particles which have unsaturated double bonds grafted on the surface thereof and have an average particle size in the range of 5 nm to 50 nm, 3% to 6% of a dispersant, 2% to 6% of a binder resin, 10% to 20% of pigment, and 0.1% to 0.5% of a photoinitiator.
11. The photosensitive resin composition according to claim 10 , characterized in that the alkali-soluble resin is an acrylic copolymer, and the acid value of the acrylic copolymer is in the range of 50 to 150.
12. The photosensitive resin composition according to claim 11 , characterized in that the acrylic copolymer is selected from (meth)acrylic acid/methyl (meth)acrylate copolymer, (meth)acrylic acid/benzyl (meth)acrylate copolymer, (meth)acrylic acid/2-hydroxyethyl (meth)acrylate/benzyl (meth)acrylate copolymer, (meth)acrylic acid/methyl (meth)acrylate/styrene copolymer, (meth)acrylic acid/2-hydroxyethyl (meth)acrylate/benzyl (meth)acrylate/methyl (meth)acrylate copolymer, and (meth)acrylic acid/benzyl (meth)acrylate/N-phenyl maleimide copolymer, and the acrylic copolymer has an acid value in the range of 60-120.
13. The photosensitive resin composition according to claim 10 , characterized in that the polymerizable monomer is one or more of hexylphenyl carbitol acrylate, N-vinyl pyrrolidone, 2-ethylhexyl carbitol acrylate, ethyl (meth)acrylate, bisphenol A bis(acryloxyethyl) ether, pentaerythritol tetra(meth)acrylate, acrylonitrile, styrene, and vinyl acetate.