Sialon sintered body and cutting insert
A sialon sintered body includes a β-sialon (Si 6-Z Al Z O Z N 8-Z ) and at least one polytype sialon, wherein a Z value is 0.4 or greater and 1.0 or less, a proportion of a total of peak intensities of each polytype sialon to a total of peak intensities of each sialon, is 10% or greater and 50% or less, at least one rare earth element B selected from a group consisting of La and Ce and at least one rare earth element C selected from a group consisting of Y, Nd, Sm, Eu, Gd, Dy, Er, Yb, and Lu is included, a molar ratio of the rare earth element B and the rare earth element C is 1.0:0.06 to 1.0:3.5 in terms of an oxide, and a total content of the rare earth elements B and C is 0.8 mol % or greater and 4.0 mol % or less in terms of an oxide.
1. A sialon sintered body comprising:
a β-sialon; and
at least one polytype sialon selected from a group consisting of a 12H-sialon, a 15R-sialon, and a 21R-sialon,
characterized in that:
a Z value of the β-sialon expressed by Si 6-Z Al Z O Z N 8-Z is 0.4 or greater and 1.0 or less,
a proportion [(I P /I A )×100] of a total I P of peak intensities of each polytype sialon calculated from the peak intensities of the polytype sialons to a total I A of peak intensities of each sialon calculated from the peak intensities of the sialons, which is obtained by X-ray diffraction analysis, is 10% or greater and 50% or less,
the sialon sintered body includes at least one rare earth element B selected from a group consisting of La and Ce, and at least one rare earth element C selected from a group consisting of Y, Nd, Sm, Eu, Gd, Dy, Er, Yb, and Lu,
a molar ratio M B :M C of the rare earth element B and the rare earth element C is 1.0:0.06 to 1.0:3.5 in terms of an oxide, and
a total content of the rare earth element B and the rare earth element C in the sialon sintered body is 0.8 mol % or greater and 4.0 mol % or less in terms of an oxide.
2. The sialon sintered body according to claim 1 ,
characterized in that:
when the Z value calculated from a composition of the sialon sintered body is set to a theoretical Z value on the assumption that an amount of Al included in the β-sialon is the same as the amount of Al included in the sialon sintered body, a solid solution ratio of Al in the β-sialon, which is expressed by a proportion [(Z value/theoretical Z value)×100] of the Z value to the theoretical Z value, is 30% or greater and 60% or less.
3. The sialon sintered body according claim 1 ,
characterized in that:
the sialon sintered body does not include an α-sialon.
4. The sialon sintered body according to claim 1 ,
characterized in that:
a proportion [(I α /I A )×100] of a peak intensity I α of an α-sialon to the total I A of the peak intensities of each sialon, which is obtained by X-ray diffraction analysis, is less than 10%,
in the α-sialon expressed by M x (Si,Al) 12 (O,N) 16 (0<x≦2), M is a metal element including the rare earth element B and the rare earth element C, and
a proportion [(A α /A S )×100] of an atomic ratio A α of the rare earth element B to the rare earth element C in the α-sialon to an atomic ratio A S of the rare earth element B to the rare earth element C in the sialon sintered body is 70% or less.
5. A cutting insert comprising:
the sialon sintered body according to claim 1 .