Negative electrode active material for nonaqueous electrolyte secondary batteries
Provided is a novel negative electrode for nonaqueous electrolyte secondary batteries, which is capable of improving cycle characteristics and is also capable of suppressing aggregation of active material particles in a slurry. The negative electrode active material for nonaqueous electrolyte secondary batteries contains silicon and has a D50 of 0.1 μm to 5 μm, and an amount of water measured at 120° C. to 300° C. by the Karl-Fischer method (referred to as “amount of water”) per specific surface area (referred to as “CS”), that is, the amount of water/CS, of 0.1 to 80 ppm/(m 2 /cc).
1. A negative electrode active material for nonaqueous electrolyte secondary batteries, the active material comprising silicon,
wherein a D50 according to a laser diffraction scattering type particle size distribution analysis method is 0.1 μm to 1.5 μm, and an amount of water, measured at 120° C. to 300° by a Karl-Fischer method, per specific surface area (CS, measured by a laser diffraction particle size distribution analyzer), that is, an amount of water/CS, is 5 to 80 ppm/(m 2 /cc),
wherein the negative electrode active material for nonaqueous electrolyte secondary batteries is produced by,
(a) forming a molten liquid by,
(i) heating a silicon-containing material to obtain the molten liquid, or
(ii) mixing an additive element with the silicon-containing material and heating the mixture to obtain the molten liquid, or
(iii) heating the silicon-containing material to obtain an intermediate molten liquid, and adding the additive element to the intermediate molten liquid, thereby forming the molten liquid,
(b) micronizing the molten liquid by atomization or liquid quenching, thereby forming a micronized active material in the form of a powder, and
(c) pulverizing and classifying the micronized active material in a nitrogen atmosphere in which air is present in an amount of less than 1%, and the balance is composed of nitrogen, to thereby adjust the particle size of the micronized active material.
2. The negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 1 , wherein the active material comprises one or two or more elements selected from a group consisting of transition metal elements, semi-metal elements or metal elements of Group 3, semi-metal elements or metal elements of Group 4, and non-metal or semi-metal elements of Group 5.
3. The negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 1 , wherein one or two or more elements selected from the group consisting of transition metal elements, semi-metal elements or metal elements of Group 3, semi-metal elements or metal elements of Group 4, and non-metal or semi-metal elements of Group 5, are solid-solubilized in the active material.
4. The negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 1 , wherein the active material comprises one or two or more elements selected from a group consisting of Ni, B, Cu, Co, Ti, Fe, In, Nb and Ag.
5. The negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 1 , wherein one or two or more elements selected from the group consisting of Ni, B, Cu, Co, Ti, Fe, In, Nb and Ag are solid-solubilized in the active material.
6. The negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 4 , wherein the active material comprises boron.
7. The negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 5 , wherein boron is solid-solubilized in the active material.
8. A negative electrode for nonaqueous electrolyte secondary batteries, the negative electrode comprising the negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 1 , and a binder.
9. A negative electrode for nonaqueous electrolyte secondary batteries, the negative electrode comprising the negative electrode active material for nonaqueous electrolyte secondary batteries according to claim 1 , graphite, and a binder.
10. The negative electrode for nonaqueous electrolyte secondary batteries according to claim 8 , wherein the binder is a polyimide.
11. A nonaqueous electrolyte secondary battery comprising the negative electrode according to claim 8 .
12. The negative electrode for nonaqueous electrolyte secondary batteries according to claim 9 , wherein the binder is a polyimide.
13. A nonaqueous electrolyte secondary battery comprising the negative electrode according to claim 9 .
14. A nonaqueous electrolyte secondary battery comprising the negative electrode according to claim 10 .