Methods of nanowire functionalization, dispersion and attachment
A nanowire device and a method of making a nanowire device are provided. The device includes a plurality of nanowires functionalized with different functionalizing compounds. The method includes functionalizing the nanowires with a functionalizing compound, dispersing the nanowires in a polar or semi-polar solvent, aligning the nanowires on a substrate such that longitudinal axes of the nanowires are oriented about perpendicular to a major surface of the substrate, and fixing the nanowires to the substrate.
1. A composition comprising:
a polar or semi-polar solvent; and
rod-shaped semiconductor nanowires suspended in and floating on a surface of the solvent, the rod-shaped semiconductor nanowires suspended in the solvent each comprising a first portion and a second portion, wherein the first portion of each rod-shaped semiconductor nanowire comprises a first functionalizing compound and the second portion of each rod-shaped semiconductor nanowire comprises a second functionalizing compound, wherein the second functionalizing compound is different from the first functionalizing compound;
wherein the first portion of the rod-shaped semiconductor nanowires comprises a metal nanowire growth catalyst particle, and wherein the second portion of the rod-shaped semiconductor nanowires comprises one or more of GaAs, InP, InAs, GaAs x P 1-x , In x Ga 1-x P, InGaAsP, GaN, InN, Ga x In 1-x N, GaP, InSb, GaSb, In x Al 1-x Sb, Ga x Al 1-x Sb, AlN, BN, Si, or SiC, wherein one of the first and the second functionalizing compounds comprises a charged compound and the other one of the first and the second functionalizing compounds comprises a non-charged compound,
wherein the charged compound comprises an anchor portion selected from a group consisting of thiol, carboxylic acid, phosphonic acid, disulfide, silane, sulfonate and phosphine, and a functional group selected from a group consisting of sulfonate, phosphonate, carboxylate, amine, and polyether,
wherein the non-charged compound comprises an anchor portion selected from a group consisting of thiol, carboxylic acid, phosphonic acid, disulfide, silane, sulfonate and phosphine, and a functional group selected from alkane, alkene, alkyne and a fluoro compound, and
wherein the semiconductor nanowires are aligned perpendicular to the surface of the solvent.
2. The composition of claim 1 , wherein the solvent is polar.
3. The composition of claim 1 , wherein:
the charged compound is selected from a group consisting of sodium mercaptopropane sulfonate, sodium mercaptoethane sulfonate, 2-mercaptosuccinate, 12-mercaptododecanoic acid, (11-mercaptoundecyl)-N,N,N-trimethylammonium bromide, (12-Phosphonododecyl)phosphonic acid, lipoic acid, (2-ammonioethyl)di-tert-butylphosphonium bis(tetrafluoroborate) and (3-aminopropyl)triethoxysilane, 12-mercaptododecanoic acid NHS ester; and
the non-charged compound is selected from a group consisting of pentanethiol, perfluorodecane thiol, dodecyltrichloro silane, stearic acid, decyl phosphonic acid, triphenyl phosphine and octadecanethiol.
4. The composition of claim 1 , wherein one of the first and the second functionalizing compounds comprises a fluorinated compound and the other one of one of the first and the second functionalizing compounds comprises a non fluorinated compound.
5. The composition of claim 1 , wherein the first functionalizing compound comprises 1-octadecanethiol, the second functionalizing compound comprises (12-phosphonodecyl) phosphonic acid and the polar or semi-polar solvent comprises cyclopentanone.
6. The composition of claim 1 , wherein the second portions of the rod-shaped semiconductor nanowires are not affixed to another rod-shaped semiconductor nanowire.
7. A composition comprising:
a polar or semi-polar solvent; and
rod-shaped semiconductor nanowires suspended in and floating on a surface of the solvent, the rod-shaped semiconductor nanowires suspended in the polar or semi-polar solvent consisting of a first portion and a second portion of the rod-shape, wherein the first portion of the rod-shaped semiconductor nanowire comprises a first functionalizing compound;
wherein the first portion of all of the semiconductor nanowires in the solvent comprise a metal nanowire growth catalyst particle, and wherein the second portion of all of the semiconductor nanowires in the solvent comprises one or more of GaAs, InP, InAs, GaAs x P 1-x , In x Ga 1-x P, InGaAsP, GaN, InN, Ga x In 1-x N, GaP, InSb, GaSb, In x Al 1-x Sb, Ga x Al 1-x Sb, AlN, BN, Si, or SiC, wherein the first functionalizing compound comprises sodium mercaptopropane sulfonate and the solvent comprises at least one of methyl isobutyl ketone and ethanol, and
wherein the semiconductor nanowires are aligned perpendicular to the surface of the solvent.
8. The composition of claim 7 , wherein the first portion comprises gold.
9. The composition of claim 7 , wherein the second portions of the rod-shaped semiconductor nanowires are not affixed to another rod-shaped semiconductor nanowire.