SiC single crystal substrate
A single crystal SiC substrate capable of forming a good epitaxial thin film thereon to give a high-quality epitaxial substrate is provided. The single crystal SiC substrate has a CMP-treated surface and has 5 or fewer lattice defects measuring 30 nm or more in a direction parallel to the polished surface and 50 nm or more in a direction perpendicular to the polished surface as counted within a depth of 100 nm from the polished surface in a direction perpendicular to the polished surface and a length of 10 μm in a direction parallel to the polished surface when observed in cross-section using a transmission electron microscope under the 00L reflection or the h-h0 reflection, where L and h are each an integer other than 0.
1. A single crystal SiC substrate having a CMP-treated polished surface,
wherein the single crystal SiC substrate has 5 or fewer lattice defects, which have a width of 30 nm or more in a direction parallel to the polished surface and a length of 50 nm or more in a direction perpendicular to the polished surface, as counted within a depth of 100 nm from the polished surface in a direction perpendicular to the polished surface and a length of 10 μm in a direction parallel to the polished surface when observed in cross-section using a transmission electron microscope under the 00L reflection or the h-h0 reflection, where L and h are each an integer other than 0;
and wherein the CMP treatment is carried out using a polishing slurry containing manganese oxide particles and manganate ions;
the manganate ion concentration in the polishing slurry is from 0.5 to 40 mass %, and the manganese oxide particles content is from 1.0 to 35 mass %; and
the molar ratio of manganate ion to manganese oxide in the polishing slurry is ⅕ or higher.
2. The single crystal SiC substrate according to claim 1 , wherein L is 4, or h is 1.
3. The single crystal SiC substrate according to claim 1 , wherein:
the polishing slurry further comprises an alkali metal ion; and
the molar ratio of the alkali metal ion to the manganate ion is 1:1 to 6:1.
4. The single crystal SiC substrate according to claim 1 , wherein the polishing slurry has a pH of 7 or more.
5. The single crystal SiC substrate according to claim 1 , wherein the polishing slurry has a pH of from 7 to 9.6.
6. The single crystal SiC substrate according to claim 1 , wherein
the manganate ion concentration in the polishing slurry is from 0.5 to 10 mass %, and the manganese oxide particles content is from 1.0 to 10 mass %; and
the ratio of manganate ion to manganese oxide in the polishing slurry is from ⅕ to 4 by molar concentration.
7. A method for preparing a single crystal SiC substrate having a CMP-treated polished surface,
the single crystal SiC substrate having 5 or fewer lattice defects, which have a width of 30 nm or more in a direction parallel to the polished surface and a length of 50 nm or more in a direction perpendicular to the polished surface, as counted within a depth of 100 nm from the polished surface in a direction perpendicular to the polished surface and a length of 10 μm in a direction parallel to the polished surface when observed in cross-section using a transmission electron microscope under the 00L reflection or the h-h0 reflection, where L and h are each an integer other than 0;
the method comprising performing a CMP treatment using a polishing slurry containing manganese oxide particles and manganate ions,
wherein the manganate ion concentration in the polishing slurry is from 0.5 to 40 mass % and the manganese oxide particles content is from 1.0 to 35 mass %, and
the molar ratio of manganate ion to manganese oxide in the polishing slurry is ⅕ or higher.
8. The method according to claim 7 , wherein L is 4, or h is 1.
9. The method according to claim 7 , wherein the polishing slurry further comprises an alkali metal ion, and the molar ratio of the alkali metal ion to the manganate ion is 1:1 to 6:1.
10. The method according to claim 7 , wherein the polishing slurry has a pH of 7 or more.
11. The method according to claim 7 , wherein the polishing slurry has a pH of from 7 to 9.6.
12. The method according to claim 7 , wherein
the manganate ion concentration in the polishing slurry is from 0.5 to 10 mass % and the manganese oxide particles content is from 1.0 to 10 mass %, and
the ratio of manganate ion to manganese oxide in the polishing slurry is from ⅕ to 4 by molar concentration.