Hydrophobically sized fibrous web and a method for the preparation of a sized web layer
A hydrophobically sized fibrous web layer, preparation of a fibrous web or a fiber-based coating, a multilayer board product having at least a middle layer formed of said fibrous web, as well as use of a heat-sensitive surfactant for said methods and products, whereby microfibrillated cellulose (MFC) and hydrophobic size are brought to a foam with water and the heat-sensitive surfactant, the foam is supplied to a forming fabric of a paper or board machine, dewatered by suction of air through the forming fabric, and dried to a web product. Alternatively the foam may be supplied onto a premade fibrous web and dried to form a coating layer. The hydrophilic functionality of the surfactant contained in the web may be destroyed by heating. Pulp of a greater fiber length, such as CTMP, may be included, to provide improved wet and dry tensile strength for the paper and board products.
1. A method for the preparation of a hydrophobically sized layer of a fibrous web, the method comprising the steps of:
forming a foam comprising water, microfibrillated cellulose (MFC), hydrophobic size, and a heat-sensitive surfactant incorporated in the foam;
supplying the foam onto a forming fabric;
dewatering the foam on the forming fabric by suction to form a web;
subjecting the web to drying; and
heating the web to suppress the hydrophilic functionality of the surfactant.
2. The method of claim 1 , wherein the hydrophobic size is alkyl ketene dimer (AKD) or a derivate thereof.
3. The method of claim 1 , wherein the surfactant is decomposed by heat, removing the hydrophilic moiety from a hydrophobic residue.
4. The method of claim 3 , wherein the surfactant is formed from an AKD precursor by activation with a base, an alcohol or water.
5. The method of claim 1 , wherein the surfactant is turned insoluble by heat.
6. The method of claim 5 , wherein the surfactant is linear ethoxylated C 11 -alcohol.
7. The method of claim 1 , wherein protein is incorporated in the foam for stabilizing the same.
8. The method of claim 7 , wherein the protein is casein.
9. The method of claim 1 , wherein starch is incorporated in the foam for additional sizing of the web.
10. The method of claim 1 , further comprising a pulp of a greater fibre length incorporated in the foam, wherein the MFC has a fibre length of about 10 μm or less, and wherein the pulp of a greater fibre length has a fibre length of about 1 mm or more.
11. The method of claim 10 , wherein said pulp of a greater fibre length is mechanical pulp.
12. The method of claim 11 , wherein said pulp of a greater fibre length is chemithermomechanical pulp (CTMP).
13. The method of claim 10 , wherein the fibrous components incorporated in the foam consist of about 5 to 40 wt- % of MFC and about 60 to 95 wt- % of the pulp of a greater fibre length.
14. The method of claim 10 , wherein said pulp of a greater fibre length is chemithermomechanical pulp (CTMP).
15. The method of claim 1 , wherein a continuous fibrous web is formed on a running forming fabric of a paper or board machine, dewatered by suction through the web and the forming fabric, and finally dried in a drying section of the paper or board machine.
16. A method for providing a hydrophobically sized coating layer on a fibrous web, the method comprising the steps of:
forming a foam comprising water, microfibrillated cellulose (MFC), hydrophobic size, and a heat-sensitive surfactant incorporated in the foam;
supplying the foam as a coat onto said fibrous web;
subjecting the coat to drying; and
heating the coat to suppress the hydrophilic functionality of the surfactant.
17. Use of a heat-sensitive surfactant for forming a hydrophobically sized layer of a fibrous web, by forming a foam comprising water, cellulosic fibres, hydrophobic size and said heat-sensitive surfactant incorporated in the foam, supplying the foam as a layer onto a substrate, subjecting the layer to drying, and heating the layer to suppress the hydrophilic functionality of the surfactant.
18. The use of claim 17 , wherein the cellulosic fibres comprise microfibrillated cellulose (MFC).
19. The use of claim 18 , wherein the foam is supplied as a coating layer to a fibrous web, which forms the substrate.
20. The use of claim 18 , wherein the cellulosic fibres comprise MFC mixed with pulp of a greater fibre length, the MFC has a fibre length of about 10 μm or less, the pulp of a greater fibre length has a fibre length of about 1 mm or more, and the foam is supplied as a layer onto a forming fabric serving as the substrate, to be dewatered by suction and formed to a fibrous web.