Production method for anhydro sugar alcohol having markedly reduced ion content and improved colour characteristics
The present invention relates to a production method for an anhydro sugar alcohol having a markedly reduced ion content and improved color characteristics, and, more specifically, relates to a method for producing an anhydrous sugar alcohol having a markedly reduced ion content, markedly lowered electrical conductivity and improved color characteristics, which is obtained by subjecting hydrogenated sugar (sugar alcohol) to a dehydration reaction and thereby converting same to an anhydrous sugar alcohol and then subjecting distilled water, which has been isolated through a distillation step, to a decolorizing process using activated carbon, and subsequently bringing the resulting decolorized substance into contact with an ion exchange resin.
1. A method for producing anhydrosugar alcohol comprising the steps of:
(1) converting hydrogenated sugar to anhydrosugar alcohol by dehydration reaction,
(2) distilling the resulting liquid of the reaction of said step (1),
(3) contacting the resulting distillate of said step (2) with active carbon having an average particle size of from 0.25 mm to 0.75 mm,
(4) contacting the resulting product of said step (3) with cation ion exchange resin, and
(5) contacting the resulting product of said step (4) with anion ion exchange resin,
wherein the method does not comprise a further step of treating the resulting product of said step (5) with active carbon, and
wherein the produced anhydrosugar alcohol has an ion content of 10 ppm or less, a conductivity of 10 μs/cm or less, a color index b value of 0.2 or less, and a yellow index (YI) value of 0.1 or less.
2. The method for producing anhydrosugar alcohol according to claim 1 , wherein the hydrogenated sugar is hexitol and the anhydrosugar alcohol is dianhydrohexitol.
3. The method for producing anhydrosugar alcohol according to claim 1 , wherein an acid catalyst is used in the step of converting hydrogenated sugar to anhydrosugar alcohol by dehydration reaction.
4. The method for producing anhydrosugar alcohol according to claim 1 , wherein in said step (3), the contact of the resulting distillate of step (2) with active carbon is conducted by passing the distillate through a column packed with the active carbon.
5. The method for producing anhydrosugar alcohol according to claim 1 , wherein in said step (3), the contact of the resulting distillate of step (2) with active carbon is conducted by incorporating the distillate and the active carbon into a reactor and mixing them with agitation.
6. The method for producing anhydrosugar alcohol according to claim 1 , wherein the active carbon is one or more selected from active carbon groups obtained by activating plant source or mineral source.
7. The method for producing anhydrosugar alcohol according to claim 1 , wherein the cation ion exchange resin used in said step (4) is a strong cation ion exchange resin.
8. The method for producing anhydrosugar alcohol according to claim 7 , wherein the strong cationic ion exchange resin is one or more selected from H-form strong cation ion exchange resin and Na-form strong cation ion exchange resin.
9. The method for producing anhydrosugar alcohol according to claim 1 , wherein the anion ion exchange resin used in said step (5) is a strong anion ion exchange resin.