Rare earth element compositions obtained from particulate material comprising kaolin and methods for obtaining such compositions
A method for obtaining rare earth element compositions may include providing a dispersed aqueous suspension of a particulate material including at least one rare earth element compound and kaolinite. The method may further include adding to the suspension a selective flocculation polymer that facilitates separation of at least a portion of the at least one rare earth element compound from the kaolinite by flocculating the kaolinite and allowing particles of the rare earth element compound to be or remain deflocculated. The method may also include allowing the suspension containing the polymer to separate in a selective flocculation separator into layers including a flocculated product layer and a deflocculated layer containing the portion of the at least one rare earth element compound. The method may further include extracting each of the separated layers from the separator. The rare earth element compound may include La 2 O 3 , CeO 2 , Nd 2 O 3 , or Y 2 O 3 .
1. A method, comprising:
providing a dispersed aqueous suspension of a particulate material comprising at least one rare earth element compound and kaolinite;
adding to the suspension a selective flocculation polymer that facilitates separation of at least a portion of the at least one rare earth element compound from the kaolinite by flocculating the kaolinite and allowing particles comprising the at least one rare earth element compound to be or remain deflocculated;
allowing the suspension containing the polymer to separate in a selective flocculation separator into layers comprising a flocculated product layer and a deflocculated layer containing the portion of the at least one rare earth element compound; and
extracting the deflocculated layer from the separator.
2. The method of claim 1 , wherein the deflocculated layer is an overflow layer.
3. The method of claim 1 , wherein the particles comprising the at least one rare earth element compound have an equivalent spherical diameter of less than about 325 μm.
4. The method of claim 1 , wherein the particles comprising the at least one rare earth element compound have an equivalent spherical diameter of less than about 1 μm.
5. The method of claim 1 , wherein the particulate material comprises or is obtained from kaolin.
6. The method of claim 1 , wherein the particulate material comprises or is obtained from sedimentary kaolin.
7. The method of claim 1 , wherein providing the dispersed aqueous suspension of the particulate material comprises adding water and a dispersing agent to a substantially dry, crude kaolin.
8. The method of claim 1 , wherein the specific gravity of the deflocculated layer containing the portion of the at least one rare earth element compound is greater than about 1.0005.
9. The method of claim 1 , wherein the specific gravity of the deflocculated layer containing the portion of the at least one rare earth element compound ranges from about 1.0005 to about 1.02.
10. The method of claim 1 , wherein the specific gravity of the deflocculated layer containing the portion of the at least one rare earth element compound ranges from about 1.001 to about 1.003.
11. The method of claim 1 , wherein the selective flocculation polymer comprises a polymer having a molecular weight greater than about one million.
12. The method of claim 1 , wherein the selective flocculation polymer comprises a weakly anionic organic polymer having a molecular weight greater than about 100,000.
13. The method of claim 1 , further comprising separating at least a portion of the at least one rare earth element compound from the deflocculated layer.
14. The method of claim 13 , wherein the separating of the at least one rare earth element compound from the deflocculated layer includes concentration by solvent extraction or acid extraction.
15. The method of claim 13 , wherein the separating of the at least one rare earth element compound from the deflocculated layer includes concentration by supercritical fluid extraction.
16. The method of claim 1 , further comprising:
adding a second flocculation polymer to the deflocculated layer to form a flocculated layer and a second deflocculated layer containing the at least one rare earth element compound, wherein the second flocculation polymer is the same or different than the selective flocculation polymer; and
extracting the at least one rare earth element compound from the second deflocculated layer.
17. A method for preparing a rare earth element composition, the method comprising:
adding a flocculation polymer to an aqueous suspension comprising kaolinite and at least one rare earth element compound to form a flocculated layer comprising the kaolinite and a deflocculated layer comprising the at least one rare earth element; and
extracting the at least one rare earth element compound from the deflocculated layer;
wherein the at least one rare earth element comprises lanthanum, cerium, yttrium, neodymium, or a combination thereof.
18. The method of claim 16 , wherein the at least one rare earth element compound comprises La 2 O 3 , CeO 2 , Nd 3 O 3 , or Y 2 O 3 .