Resin composition for foaming containing biodegradable resin, and foam manufactured therefrom
There are provided a resin composition for foaming including a biodegradable resin and a foamed article made thereof. The resin composition for foaming according to the present invention includes an ethylene-vinyl acetate resin, a biodegradable polyester resin containing a monomer of a double bond compound, a cross-linking agent, a co-crosslinking agent, a filler, and a foaming agent. In the resin composition, the double bond in the biodegradable polyester resin can be chemically cross-linked to the ethylene-vinyl acetate resin by a cross-linking agent, so that a compatibility with the ethylene-vinyl acetate resin can be improved, processability (mold releasability) during a mixing and melting process can be improved, and a foaming property and a mechanical property of a foamed article can be remarkably improved.
1. A resin composition for foaming, comprising:
an ethylene-vinyl acetate resin;
a biodegradable polyester resin bonding with a monomer having a double bond;
a cross-linking agent;
a co-crosslinking agent; a filler; and
a foaming agent,
wherein the double bond in the biodegradable polyester resin is chemically cross-linked to the ethylene-vinyl acetate resin.
2. The resin composition of claim 1 , wherein the biodegradable polyester resin is used in the amount ranging from 20% by weight to 50% by weight with respect to the ethylene-vinyl acetate resin.
3. The resin composition of claim 1 , wherein the monomer having a double bond is included in a mole ratio of from 0.003 to 0.2 in the biodegradable polyester resin.
4. The resin composition of claim 1 , wherein the biodegradable polyester resin is selected from polyester resins bonding with monomers having double bonds, wherein the monomers comprise unsaturated acids, unsaturated isocyanates, unsaturated alcohols, or unsaturated hydroxy carboxylic acids with two or more functional groups.
5. The resin composition of claim 4 , wherein the biodegradable polyester resin is selected from PBAF, PBAI, PBSAF, PBSAI, PBSF, or PBSI.
6. The resin composition of claim 1 , wherein the composition includes the cross-linking agent in the amount of 0.1 parts to 10 parts by weight, the co-crosslinking agent in the amount of 0.1 parts to 5 parts by weight, the filler in the amount of 0.1 parts to 5 parts by weight, and the foaming agent in the amount of 1 part to 10 parts by weight with respect to 100 parts by weight of the total weight of the ethylene-vinyl acetate resin and the biodegradable polyester resin.
7. A foamed article being foam-molded of a resin composition for foaming according to claim 1 .
8. The foamed article of claim 7 , wherein the foamed article is foam-molded by an injection foam molding method or a press foam molding method.
9. The foamed article of claim 7 , wherein the foamed article is used as a sole, a midsole, or an insole of a shoe.