Binder for battery electrode and electrode and battery using same
The purpose of the present invention is to provide: an aqueous binder having high adhesiveness, that in particular does not exhibit oxidative degradation in an electrode environment, and having little environmental load; and an electrode and a battery that use same. Disclosed is a battery electrode binder containing: (A) a constituent unit derived from a monomer having a hydroxyl group; and (B) a constituent unit derived from a polyfunctional (meth)acrylate having no more than 5 functions. An electrode is prepared using this binder and is used in a battery such as a lithium-ion secondary battery.
1. A binder for battery electrode, comprising a polymer comprising:
(A) constitutional units derived from a monomer having a hydroxyl group, represented by the following general formula (1):
wherein R 1 is hydrogen, or a linear or branched alkyl group having 1 to 4 carbon atoms,
R 2 and R 3 each is hydrogen, or a linear or branched alkyl group having 1 to 4 carbon atoms, and
n is an integer of 2 to 30, and
(B) constitutional units derived from a polyfunctional (meth)acrylate monomer represented by the following formula (2):
wherein R 11 each is, the same or different, hydrogen or a methyl group,
R 12 is a penta- or less valent organic group having 2 to 100 carbon atoms, and
m is an integer from 2 to 5, and
wherein the amount of the constitutional units (B) is from 1 to 20% by weight, based on the polymer.
2. The binder for battery electrode according to claim 1 , wherein n is an integer of 4 to 20, in the formula (1).
3. The binder for battery electrode according to claim 1 , wherein m is an integer from 3 to 5, in the formula (2).
4. The binder for battery electrode according to claim 1 , wherein the polymer further comprises one or both of constitutional units (C) derived from a (meth)acrylate ester monomer and constitutional units (D) derived from a (meth)acrylic acid monomer.
5. The binder for battery electrode according to claim 4 , wherein the (meth)acrylate ester monomer (C) is a compound represented by the following formula (3):
wherein R 21 is hydrogen or a methyl group, and
R 22 is a hydrocarbon group having 1 to 50 carbon atoms.
6. The binder for battery electrode according to claim 4 , wherein the (meth)acrylic acid monomer (D) is a compound represented by the following formula (4):
wherein R 31 is hydrogen or a methyl group.
7. The binder for battery electrode according to claim 4 , wherein the amounts of the constitutional units (A), the constitutional units (B), the constitutional units (C), and the constitutional units (D) in the polymer are 1 to 40 parts by weight of constitutional units (B), 0 to 200 parts by weight of the constitutional units (C), and 0 to 60 parts by weight of the constitutional units (D), based on 100 parts by weight of constitutional units (A).
8. The binder for battery electrode according to claim 1 , wherein the battery is a secondary battery.
9. An electrode for battery comprising the binder according to claim 1 , and an active material.
10. A battery comprising the electrode according to claim 9 .
11. The binder for battery electrode according to claim 1 , wherein the content of the polymer is from 0.2% to 80% by weight.
12. The binder for battery electrode according to claim 1 , wherein the amount of the constitutional units (B) is from 1 to 18% by weight, based on the polymer.