Polymeric composites, resulting panels, and method for producing the same
A polymeric composite derived from a reclaimed polymeric material. The polymeric composite in particulate form can be thermally compressed into panels and other embodiments that require a component that possesses sufficient mechanical strength and moisture resistance. In certain embodiments, the panel may be utilized as one layer in a multilayered article.
1. A method comprising thermal compression bonding (i) a polymeric material from a hydropulping process, or (ii) a composite of a reclaimed polymeric material, a high aspect ratio filler, and a lightweight filler to form a substrate; and applying an adhesive composition that is formed as a layer on the substrate.
2. A method comprising thermal compression bonding (i) a polymeric material from a hydropulping process, or (ii) a composite of a reclaimed polymeric material, a high aspect ratio filler, and a lightweight filler to form a substrate; and surface treating the substrate.
3. A method according to claim 2 , wherein treating comprises plasma treatment, silane treatment, heat treatment, corona treatment, or combinations thereof.
4. A method comprising:
(a) scattering onto a first rotating belt a (i) a polymeric material from a hydropulping process, or (ii) a reclaimed polymeric material and a lightweight filler, and optionally an organic filler or inorganic filler or combinations thereof, and
(b) thermal compression bonding the composite between the first rotating belt with a second rotating belt to form a substrate.
5. A method according to claim 4 , further comprising scattering a layer of a second compound onto the composite prior to thermal compression bonding to form a multilayered article.
6. A method according to claim 4 , further comprising one or more additives selected from antioxidants, light stabilizers, fibers, blowing agents, foaming additives, antiblocking agents, heat stabilizers, impact modifiers, biocides, compatibilizers, flame retardants, plasticizers, tackifiers, colorants, processing aids, lubricants, adhesion promoting agents, pigments or combinations thereof.
7. A method according to 40, further comprising blending the one or more additives with (i) the polymeric material from a hydropulping process, or (ii) the reclaimed polymeric material and lightweight filler, and optionally the organic filler or inorganic filler or combinations thereof, prior to thermal compression bonding.
8. A method comprising thermal compression bonding (i) a polymeric material from a hydropulping process, or (ii) a composite of a reclaimed polymeric material, a high aspect ratio filler, and a lightweight filler to form a substrate; and applying an adhesive composition that is formed as a layer on the substrate, or surface treating the substrate.
9. The method according to claim 8 , wherein the composite is co-scattered with another polymeric material, and upon thermal compression bonding forms a multilayered substrate.
10. The method according to claim 8 , further comprising bonding an aesthetic layer, a reinforcing layer, a sound dampening layer, an adhesive layer, a bondable layer, a support layer, a printable layer, polymeric layer, reflective layer, or combinations thereof to the substrate.
11. The method according to 42, further comprising blending the one or more additives with (i) the polymeric material from a hydropulping process, or (ii) the reclaimed polymeric material and lightweight filler prior to thermal compression bonding.
12. The method according to 11 , wherein the one or more additives is selected from antioxidants, light stabilizers, fibers, blowing agents, foaming additives, antiblocking agents, heat stabilizers, impact modifiers, biocides, compatibilizers, flame retardants, plasticizers, tackifiers, colorants, processing aids, lubricants, adhesion promoting agents, pigments or combinations thereof.
13. The method according to claim 8 , wherein the lightweight filler is expanded volcanic ash, perlite, pumice, cenospheres, glass microspheres, ceramic microspheres, polymeric microspheres, foamed polymeric beads, cellulosic fiber, or combination thereof.
14. The method according to claim 8 , wherein the substrate further comprises one or more of an inorganic filler, organic filler, a coupling agent, a desiccant, a lubricant, or an antimicrobial.
15. The method according to claim 8 , wherein the substrate exhibits water absorption of less than 10% as indicated after submersion in water for twenty-four hours at room temperature.
16. The method according to claim 8 , wherein the substrate is a flooring substrate, a roofing panel, a marine panel, a concrete form, wall panel, door panel, automotive panel, aerospace panel, or a signage panel.
17. The method according to claim 8 , wherein a flexural modulus, a coefficient of thermal expansion, or an impact strength of the substrate in a machine direction is within at least 30% of a flexural modulus, a coefficient of thermal expansion, or an impact strength of the substrate in a transverse machine direction.
18. The method according to claim 8 , wherein the substrate exhibits a thermal expansion of less than 0.5% according to a Thermal Expansion Test Method.
19. The method according to claim 8 , wherein the reclaimed polymeric material includes reclaimed polymers from hydropulping processes, low density polyethylene, polymers from agricultural film waste streams, polymers from municipal waste streams, polymers from medical waste streams, or combinations thereof.
20. The method according to claim 8 , wherein the substrate exhibits at least two of a specific gravity of about 0.5 to 1.6 g/cm3, a coefficient of thermal expansion of less than 70 μm/m/K, a thermal expansion of less than 0.5% according to the Thermal Expansion Test Method, and a water absorption of less than 10% as indicated after submersion in water for twenty-four hours at room temperature.