Transparent inorganic thin-film electroluminescent display element and method for manufacturing it
An inorganic, transparent thin film electroluminescent display element with a display area having at least one emissive area and at least one non-emissive area, improved in terms of transparency and inconspicuousness is provided, as well as a method for its preparation. The structure according to the invention comprises a substrate ( 40 ), a first conducting layer ( 42 ), a first insulating layer ( 45 ), a luminescent layer ( 46 ), a second insulating layer ( 47 ), a second conductive layer ( 43 ) and a third insulating layer ( 44 ) comprising insulating, inorganic material. Emissive and non-emissive areas of the display are rendered optically similar by providing passive film elements ( 50 ) at the non-emissive areas, namely by providing conductor material also at these areas when the conductive electrodes connected to a power source for generating the required voltage are deposited at the emissive areas.
1. An inorganic, transparent thin film electroluminescent display element with a display area having at least one emissive area and at least one non-emissive area, the display element comprising a layer structure on a substrate, said layer structure comprising
a first conducting layer comprising transparent conductive material, having a thickness in the range 30-250 nm,
a first insulating layer comprising insulating, inorganic material,
a luminescent layer comprising zinc sulfide, having a thickness in the range 30-250 nm,
a second insulating layer comprising insulating, inorganic material,
a second conducting layer comprising transparent conductive material, having a thickness in the range 30-250 nm,
a third insulating layer comprising insulating, inorganic material having a lower refractive index than that of the second conducting layer,
characterized in that each of said first and second conducting layers comprises at least one conductor element at the at least one emissive area and at least one passive film element at the at least one non-emissive area.
2. A display element according to claim 1 , wherein the sum of the emissive areas covered by the conductor elements and the non-emissive areas covered by the passive film elements is >80% of the display area.
3. A display element according to claim 1 , whose photopic transmission is >78%.
4. A display element according to claim 1 , wherein the transparent conductive material comprises indium tin oxide.
5. A display element according to claim 1 , wherein the first and second insulating layers comprise at least one of aluminium oxide, titanium oxide, and combinations and mixtures of these.
6. A display element according to claim 1 , wherein the third insulating layer comprises aluminium oxide.
7. A display element according to claim 1 , wherein the luminescent layer comprises manganese-doped zinc sulfide ZnS:Mn.
8. A display element according to claim 1 , wherein the luminescent layer comprises terbium-doped zinc sulfide ZnS:Tb.
9. A display element according to claim 1 , comprising a glass panel optically bonded to the third insulating layer.
10. A display element according to claim 1 , wherein at least part of the conducting layers form a matrix of intersecting electrodes.
11. A display element according to claim 1 , wherein at least part of the conducting layers are formed so as to provide emissive segments, icons, or symbols at predetermined locations of the display area.
12. A display element according to claim 1 , wherein at least one light emitting zone is provided in the display area for illuminating the area behind the display.
13. A method of manufacturing an inorganic, transparent thin film electroluminescent display element with a display area having at least one emissive area and at least one non-emissive area, the method comprising the steps of
providing a substrate,
preparing a first conducting layer comprising transparent conductive material, having a thickness in the range 30-250 nm,
depositing by atomic layer deposition a first insulating layer comprising insulating, inorganic material,
depositing by atomic layer deposition a luminescent layer comprising zinc sulfide, having a thickness in the range 30-250 nm,
depositing by atomic layer deposition a second insulating layer comprising insulating, inorganic material,
preparing a second conducting layer comprising transparent conductive material, having a thickness in the range 30-250 nm, and
preparing a third insulating layer comprising insulating, inorganic material having a lower refractive index than that of the second conducting layer,
characterized in that each of said first and second conducting layers is prepared so as to comprise at least one conductor element at the at least one emissive area and at least one passive film element at the at least one non-emissive area.