IP Library Granted Patent US 9,221,972
Granted Patent B2
US 9,221,972 · App. 14/410,895 · Granted Dec 29, 2015

Poly-3-hydroxyalkanoate resin composition and molded article

Inventors: Tetsuya Minami (Settsu, JP); Kenichiro Nishiza (Settsu, JP); Noriyuki Suzuki (Settsu, JP)
Assignee: KANEKA CORPORATION
C08L67/04C08L2201/06
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Quick Facts
Patent No.
US 9,221,972
App. No.
14/410,895
Granted
Dec 29, 2015
Kind
B2
Abstract

A poly-3-hydroxyalkanoate resin composition having excellent ductility and transparency, and a molded article thereof. The poly-3-hydroxyalkanoate resin composition includes: a poly-3-hydroxyalkanoate resin (A); and an ethylene-vinyl acetate copolymer resin (B) having a vinyl acetate content of 65 to 95 wt %, wherein the resin (A) and the resin (B) are miscible and a ratio of resin (A)/resin (B) is 90/10 to 55/45 (wt/wt). The molded article is produced using such a poly-3-hydroxyalkanoate resin composition.

Claims (33)

1. A resin composition, comprising:

a poly-3-hydroxyalkanoate resin (A); and

an ethylene-vinyl acetate copolymer resin (B) having a vinyl acetate content of 70 to 90 wt %,

wherein:

the poly-3-hydroxyalkanoate resin (A) and the ethylene-vinyl acetate copolymer resin (B) are miscible, and a weight ratio of the poly-3-hydroxyalkanoate resin (A) with respect to the ethylene-vinyl acetate copolymer resin (B) is from 85/15 to 70/30 in wt/wt; and

the ethylene-vinyl acetate copolymer resin (B) has a melt flow rate of from 5 to 8 g/10 min.

2. The resin composition according to claim 1 , wherein the poly-3-hydroxyalkanoate resin (A) has a 3-hydroxybutyrate content of 80 mol % or more.

3. A molded article, comprising:

the resin composition according to claim 1 .

4. A molded article, comprising:

the resin composition according to claim 2 .

5. The resin composition according to claim 1 , wherein the poly-3-hydroxyalkanoate resin (A) has a 3-hydroxybutyrate content of 85 mol % or more.

6. The resin composition according to claim 1 , wherein the poly-3-hydroxyalkanoate resin (A) comprises at least one selected from the group consisting of a poly(3-hydroxybutyrate) homopolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxypropionate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxyheptanoate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxyoctanoate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxynanoate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxydecanoate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxyundecanoate) copolymer resin, and a poly(3-hydroxybutyrate-co-4-hydroxybutyrate) copolymer resin.

7. A resin composition, comprising:

a poly-3-hydroxyalkanoate resin (A); and

an ethylene-vinyl acetate copolymer resin (B) having a vinyl acetate content of 65 to 95 wt %,

wherein:

the poly-3-hydroxyalkanoate resin (A) and the ethylene-vinyl acetate copolymer resin (B) are miscible, and a weight ratio of the poly-3-hydroxyalkanoate resin (A) with respect to the ethylene-vinyl acetate copolymer resin (B) is from 90/10 to 55/45 in wt/wt; and

the poly-3-hydroxyalkanoate resin (A) comprises at least one selected from the group consisting of a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolymer resin, a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) copolymer resin, and a poly(3-hydroxybutyrate-co-4-hydroxybutyrate) copolymer resin.

8. The resin composition according to claim 7 , wherein the weight ratio of the poly-3-hydroxyalkanoate resin (A) with respect to the ethylene-vinyl acetate copolymer resin (B) is from 90/10 to 70/30.

9. The resin composition according to claim 7 , wherein the weight ratio of the poly-3-hydroxyalkanoate resin (A) with respect to the ethylene-vinyl acetate copolymer resin (B) is from 85/15 to 70/30.

10. The resin composition according to claim 7 , wherein the vinyl acetate content in the ethylene-vinyl acetate copolymer resin (B) is from 70 to 90 wt %.

11. The resin composition according to claim 7 , wherein the poly-3-hydroxyalkanoate resin (A) has a 3-hydroxybutyrate content of 80 mol % or more.

12. The resin composition according to claim 7 , wherein the poly-3-hydroxyalkanoate resin (A) has a 3-hydroxybutyrate content of 85 mol % or more.

13. The resin composition according to claim 7 , wherein the vinyl acetate content in the ethylene-vinyl acetate copolymer resin (B) is from 70 to 90 wt %.

14. The resin composition according to claim 7 , wherein the ethylene-vinyl acetate copolymer resin (B) has a melt flow rate of from 0.1 to 1000 g/10 min.

15. The resin composition according to claim 14 , wherein the melt flow rate is from 0.5 to 500 g/10 min.

16. The resin composition according to claim 14 , wherein the melt flow rate is from 1 to 100 g/10 min.

17. The resin composition according to claim 14 , wherein the melt flow rate is from 5 to 60 g/10 min.

18. The resin composition according to claim 14 , wherein the melt flow rate is from 5 to 8 g/10 min.

19. The resin composition according to claim 18 , wherein the vinyl acetate content in the ethylene-vinyl acetate copolymer resin (B) is from 70 to 90 wt %.

20. A molded article, comprising:

the resin composition according to claim 7 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 23, 2014
From: MINAMI, TETSUYA; NISHIZA, KENICHIRO; SUZUKI, NORIYUKI
To: KANEKA CORPORATION
Reel/Frame 034578/0555 →
Priority Claims (1)
JP 2012-146453 · Jun 29, 2012 · national
Continuity (1)
Related Publication 20150166785A1 · Jun 18, 2015