Heat-insulating structure of member facing engine combustion chamber, and process for producing same
A heat-insulating layer exhibiting high resistance to cracks, peeling, deformation, and gasoline and high heat insulation is obtained on the wall surface of an engine member ( 19 ). First, a heat insulator layer including a silicone-based resin and hollow particles containing a Si-based oxide is formed on a wall surface of the engine member ( 19 ). Then, Si-based oxide is produced through oxidation of a silicone-based resin in at least part of the surface of the heat insulator layer by heating the surface of the heat insulator layer. Thereafter, a catalytic metal is added to the silicone-based resin in the surface of the heat insulator layer and/or Si-based oxide derived from the hollow particles. Using the catalytic metal as nuclei, electroless plating is performed. In this manner, a heat-insulating layer ( 21 ) in which the surface of the heat-insulating film ( 27 ) is covered with a plating film ( 29 ) is obtained.
1. A heat-insulating structure of a member facing an engine combustion chamber, the heat-insulating structure comprising:
a heat-insulating layer including a silicone-based resin and hollow particles and located on a combustion chamber wall surface of the member facing the engine combustion chamber, wherein
the hollow particles contain a Si-based oxide,
the heat-insulating layer includes a base layer in which the hollow particles are dispersed in a base material of the silicone-based resin and also includes a surface layer containing SiO 2 or a plating film on the base layer, and
the silicone-based resin has a three-dimensional structure, wherein
the silicone-based resin is a silicone-based resin composition including a cage silsesquioxane structure.
2. The heat-insulating structure of claim 1 , wherein
surfaces of the hollow particles are treated with a silane compound.
3. The heat-insulating structure of claim 2 , wherein
at least one of a chemical conversion treatment layer or an anodized layer is located between a surface of the member facing the engine combustion chamber and the heat-insulating layer.
4. The heat-insulating structure of claim 1 , wherein
the heat-insulating layer includes 10 wt % or more of the cage silsesquioxane structure.
5. The heat-insulating structure of claim 1 , wherein
the cage silsesquioxane structure is treated with ultraviolet ray curing.
6. The heat-insulating structure of claim 4 , wherein
the cage silsesquioxane structure is treated with ultraviolet ray curing.
7. The heat-insulating structure of claim 1 , wherein
the heat-insulating layer includes chain siloxane having a fluoroalkyl group.
8. A method for producing a heat-insulating structure of a member facing an engine combustion chamber, the heat-insulating structure including a heat-insulating layer that includes a silicone-based resin and hollow particles and is located on a combustion chamber wall surface of the member, the method comprising:
obtaining a heat insulator by mixing a polysiloxane compound with a cage silicate compound including a cage silsesquioxane structure and hollow particles; and
obtaining a heat-insulating layer including a silicone resin composition including the cage silsesquioxane structure and the hollow particles by applying the heat insulator on the combustion chamber wall surface of the member.
9. The method of claim 8 , wherein
before the mixing the polysiloxane compound with the hollow particles, surfaces of the hollow particles are treated with a silane compound.
10. The method of claim 8 , wherein
the cage silicate compound is added to the polysiloxane compound such that the heat-insulating layer includes 10 wt % or more of the cage silsesquioxane structure.
11. The method of claim 8 , wherein
the hollow particles have a volume that is less than half of a total volume of the heat insulating layer.