METHOD FOR PREPARING ACETYLATED CELLULOSE ETHERS HAVING IMPROVED ANTI-FOULING PROPERTIES, AND ACETYLATED CELLULOSE ETHERS PREPARED BY SAME
The present invention relates to a method for preparing acetylated cellulose ethers having improved anti-fouling properties and to acetylated cellulose ethers prepared by same. The method for preparing acetylated cellulose ethers having improved anti-fouling properties comprises the steps of: cross-linking cellulose ethers; and acetylating the cross-linked cellulose ethers. The acetylated cellulose ethers prepared by the method may activate the hydroxyl group which is made into blocks by the agglomeration between polymers performed by the materials for cross-linking the cellulose ethers, and may introduce thereto an additional hydrophilic group so as to increase hydrophilic properties, and thus may improve anti-fouling properties when applied to water-treatment membranes.
1 . A method for preparing an acetylated cellulose ester having improved anti-fouling properties, comprising the steps of:
cross-linking a cellulose ester; and
acetylating the cross-linked cellulose ester.
2 . The method of claim 1 , wherein the cellulose ester has at least one substituent selected from the group consisting of methyl, ethyl, propyl, hydroxymethyl, hydroxyethyl, and hydroxypropyl groups.
3 . The method of claim 1 , wherein the cellulose ester is at least one selected from the group consisting of methylcellulose, hydroxypropyl methylcellulose, and hydroxyethyl methylcellulose.
4 . The method of claim 1 , wherein a material for cross-linking the cellulose ester is at least one selected from the group consisting of glyoxal and glutaraldehyde.
5 . The method of claim 4 , wherein the material for cross-linking the cellulose ester is used at a content of 0.5 to 2.5% by weight, based on the total weight of the cellulose ester.
6 . The method of claim 1 , wherein the acetylated cellulose ester has a degree of substitution with alkyl groups (DS) of 1 to 2, a degree of substitution with hydroxyalkyl groups (MS) of 0 to 1, and a degree of substitution with acetyl groups (DS) of 1 to 2.
7 . An acetylated cellulose ester having improved anti-fouling properties in which hydrogen atoms in hydroxyl groups included in a monomer of the cross-linked cellulose ester prepared as defined in claim 1 are substituted with acetyl groups.