Method for continuously preparing biodegradable aliphatic/aromatic polyester copolymer
Provided is a method of continuous production of a biodegradable aliphatic polyester including continuously performing an esterification reaction of a mixture including an aliphatic dihydroxy compound and aliphatic dicarboxylic acid at a temperature of 185° C. or less to obtain an ester; continuously performing a first polycondensation reaction of the ester to obtain a preliminary polymer; and continuously performing a polycondensation reaction of the preliminary polymer. According to the method of production, an amount of the aliphatic dihydroxy compound used decreases, which is a starting material, thereby decreasing the manufacturing cost of the biodegradable aliphatic polyester.
1. A method of continuous production of a biodegradable aliphatic polyester, the method comprising:
continuously performing an esterification reaction of a mixture comprising an aliphatic dihydroxy compound and aliphatic dicarboxylic acid under the conditions of a temperature of about 160° C. to about 185° C. and residence time of reactants of about 3 hours to about 8 hours;
continuously performing a first polycondensation reaction of the ester to obtain a preliminary polymer; and
continuously performing a polycondensation reaction of the preliminary polymer.
2. The method of claim 1 , wherein an amount of the aliphatic dihydroxy compound used is about 1.1 moles to about 1.5 moles based on 1 mole of the aliphatic dicarboxylic acid.
3. The method of claim 1 , wherein the continuously performing the polycondensation reaction of the preliminary polymer comprises:
continuously performing a second polycondensation reaction of the preliminary polymer; and
continuously performing a third polycondensation reaction of a product obtained from the second polycondensation reaction.
4. The method of claim 3 , wherein the second polycondensation reaction is performed under the conditions of a temperature of about 220° C. to about 250° C., a degree of vacuum of about 2 torr to about 7 torr, and residence time of a reaction mixture of about 1 hour to 4 hours.
5. The method of claim 3 , wherein the third polycondensation reaction is performed under the conditions of a temperature of about 220° C. to about 250° C., a degree of vacuum of about 0.5 torr to about 2 torr, and residence time of the reaction mixture of about 1 hour to 3 hours.
6. The method of claim 1 , wherein the first polycondensation reaction is performed under the conditions of a temperature of about 220° C. to about 250° C., a degree of vacuum of about 10 torr to about 50 torr, and residence time of a reaction mixture of about 1 hour to 3 hours.
7. The method of claim 1 , wherein the mixture comprising the aliphatic dihydroxy compound and the aliphatic dicarboxylic acid further comprises at least one of a group consisting of a catalyst, a heat stabilizer, a branching agent, a color stabilizing agent, and a color control agent.
8. The method of claim 1 , wherein the aliphatic dihydroxy compound is an ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,4-dimethyl-2-ethyl-1,3-hexanediol, 2,2-dimethyl-1,3-propanediol, 2-ethyl-2-butyl-1,3-propanediol, 2-ethyl-2-isobutyl-1,3-propanediol, 2,2,4-trimethyl-1,6-hexanediol, or a mixture thereof, and
the aliphatic dicarboxylic acid is malonic acid, succinic acid, glutaric acid, 2-methyl glutaric acid, 3-methyl glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecandioic acid, dodecandioic acid, brassylic acid, tetradecandioic acid, fumaric acid, 2,2-dimethylglutaric acid, maleic acid, itaconic acid, 2-5-norbornane dicarboxylic acid, or a mixture thereof.