Method for manufacturing a metal-borocarbide layer on a substrate
The invention relates to a PVD process for coating a substrate with a layer containing at least one microcrystalline metallic borocarbide phase. During the PVD process, the source output is pulsed such that the at least one peak of which the half intensity width allows conclusions to be drawn about the presence of a microcrystalline phase of the metallic borocarbide layer can be identified in the x-ray spectrum of a layer produced in this way at a substrate temperature below 600° C.
1. A PVD method for coating a substrate with a coating which at least contains a microcrystalline metal-borocarbide phase, characterized by the facts, that in the frame of the PVD method, the source power is pulsed so that in the x-ray spectrum of thereby deposited layer at a substrate temperature below 600° C. at least one peak may be identified, the half value width thereof allowing the conclusion that a microcrystalline phase of the metal-borocarbide is present, wherein the PVD method comprises a HIPIMS method.
2. The method of claim 1 , characterized by the fact that the sputtering method is operated at least to a part with a current density larger than 100 W/cm 2 as the HIPIMS method.
3. The method according to claim 1 , characterized by the fact that the PVD method is operated with a target, in which a metal is present as a ceramic compound.
4. The method according to claim 3 , characterized by the fact that the ceramic compound is a metal-borocarbide.
5. The method according to claim 1 , characterized by the fact that at least during a part of the PVD method, a negative bias is applied to the substrate to be coated.
6. The method according to claim 1 , characterized by the fact that the metal-borocarbide is a material according to the formula Me 2 BC whereby Me is an element out of the group formed by Cr, Zr and Mo.
7. The method according to claim 1 , characterized by the fact that the method is operated so that the at least one peak has an amplitude which is at least twice the largest amplitude of a measuring value, which indicates presence of a nano-crystalline and/or amorphous-phase in a 2Theta x-ray spectrum from 20° to 70°.
8. A workpiece with a metal-borocarbide coating and coated by a method according to claim 1 , characterized by the fact that in the x-ray spectrum of the coating at least one peak may be identified the half-value width thereof being indicative for the presence of a micro-crystalline phase of the metal-borocarbide.
9. A workpiece according to claim 8 , characterized by the fact the metal-borocarbide is a material according to the formula Me 2 BC, whereby Me is an element out of the group formed by Cr, Zr and Mo.