Processes for preparing alumina and magnesium chloride by HCl leaching of various materials
The disclosed processes can be effective for treating various materials comprising several different metals. These materials can be leached with HCl for obtaining a leachate and a solid. Then, they can be separated from one another and a first metal can be isolated from the leachate. Then, a second metal can further be isolated from the leachate. The first and second metals can each be substantially selectively isolated from the leachate. This can be done by controlling the temperature of the leachate, adjusting pH, further reacting the leachate with HCl, etc. The metals that can be recovered in the form of metal chlorides can eventually be converted into the corresponding metal oxides, thereby allowing for recovering HCl. The various metals can be chosen from aluminum, iron, zinc, copper, gold, silver, molybdenum, cobalt, magnesium, lithium, manganese, nickel, palladium, platinum, thorium, phosphorus, uranium, titanium, rare earth element and rare metals.
1. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions, magnesium ions and a solid, and separating said solid from said leachate;
substantially selectively precipitating MgCl 2 from said leachate under conditions effective for controlling solubility of MgCl 2 based on at least one parameter chosen from temperature, acid concentration and chlorides concentration and removing said MgCl 2 from said leachate;
reacting said leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid;
optionally reacting said precipitate with a base;
treating said precipitate under conditions effective for converting said precipitate into Al 2 O 3 and optionally recovering gaseous HCl so-produced; and
treating said MgCl 2 under conditions effective for converting it into MgO and optionally recovering gaseous HCl so-produced,
wherein MgCl 2 is substantially selectively precipitated from said leachate and removed therefrom and then, said leachate is reacted with HCl so as to obtain said liquid and said precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid.
2. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions, magnesium ions and a solid, and separating said solid from said leachate;
substantially selectively precipitating MgCl 2 from said leachate under conditions effective for controlling solubility of MgCl 2 based on at least one parameter chosen from temperature, acid concentration and chlorides concentration and removing said MgCl 2 from said leachate;
reacting said leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid;
optionally reacting said precipitate with a base;
treating said precipitate under conditions effective for converting said precipitate into Al 2 O 3 and optionally recovering gaseous HCl so-produced; and
treating said MgCl 2 under conditions effective for converting it into MgO and optionally recovering gaseous HCl so-produced,
wherein said aluminum-containing material is leached at a pressure of about 4 to about 10 barg.
3. The process of claim 1 , wherein said process is carried out without reacting said precipitate with said base.
4. The process of claim 2 , wherein said process is carried out without reacting said precipitate with said base.
5. The process of claim 1 , wherein said process is carried out by reacting said precipitate with said base.
6. The process of claim 2 , wherein said process is carried out by reacting said precipitate with said base.
7. The process of claim 1 , wherein said aluminum-containing material is leached with HCl having a concentration of about 25 to about 45 weight %.
8. The process of claim 1 , wherein said aluminum-containing material is leached with HCl having a concentration of about 25 to about 45 weight % at a temperature of about 160 to about 190° C.
9. The process of claim 1 , wherein said aluminum-containing material is leached with HCl having a concentration of about 18 to about 32 weight % at a temperature of about 160 to about 175° C.
10. The process of claim 1 , comprising calcining MgCl 2 into MgO.
11. The process of claim 1 , comprising calcining MgCl 2 into MgO and recycling the gaseous HCl so-produced by contacting it with water so as to obtain a composition having a concentration of about 25 to about 45 weight % and using said composition for leaching said aluminum-containing material.
12. The process of claim 1 , wherein said process comprises reacting said leachate with dry gaseous HCl so as to obtain said liquid and said precipitate comprising said aluminum ions, said precipitate being formed by crystallization of AlCl 3 .6H 2 O.
13. The process of claim 1 , wherein said process comprises reacting said leachate with HCl recovered during said process and having a concentration of at least 30% as to obtain said liquid and said precipitate comprising said aluminum ions, said precipitate being formed by crystallization of AlCl 3 .6H 2 O.
14. The process of claim 1 , wherein said crystallization is carried out at a temperature of about 45 to about 65° C.
15. The process of claim 1 , wherein said process comprises converting AlCl 3 .6H 2 O into Al 2 O 3 by carrying out a calcination of AlCl 3 .6H 2 O, said calcination comprising steam injection.
16. The process of claim 1 , wherein said aluminum-containing material is chosen from aluminosilicate minerals.
17. The process of claim 2 , wherein MgCl 2 is substantially selectively precipitated from said leachate and removed therefrom and then, said leachate is reacted with HCl so as to obtain said liquid and said precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid.
18. The process of claim 2 , wherein said leachate is reacted with HCl so as to obtain said liquid and said precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid, and then said MgCl 2 is substantially selectively precipitated from said leachate and removed therefrom.
19. The process of claim 1 , wherein said aluminum-containing material is leached with HCl so as to obtain said leachate comprising aluminum ions, magnesium ions and said solid, and said solid is separated from said leachate at a temperature of at least 50° C.
20. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions, magnesium ions and iron ions and a solid, and separating said solid from said leachate;
reacting said leachate with HCl so as to obtain a liquid comprising said magnesium ions and said iron ions and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid;
substantially selectively removing said iron ions from said leachate by means of an hydrolysis;
substantially selectively precipitating MgCl 2 from said liquid under conditions effective for controlling solubility of MgCl 2 based on at least one parameter chosen from temperature, acid concentration and chlorides concentration and removing said MgCl 2 from said liquid;
treating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and optionally recovering gaseous HCl so-produced; and
treating said MgCl 2 under conditions effective for converting it into MgO and optionally recovering gaseous HCl so-produced.