Latent-reactive hot-melt adhesive composition
A latent-reactive hot-melt adhesive composition comprising a) at least one first thermoplastic polymer, which is monofunctionally reactive to NCO groups and has a high tensile strength, b) at least one second NCO-reactive polymer and/or oligomer, polymer miscible with the first polymer a), which is at least di-functionally, preferably tri- or multifunctionally, reactive to NCO groups and has a melting temperature (T m ), which is lower than the melting temperature (Tm) of polymer a), and is in liquid form, c) at least one solid, surface deactivated di- and/or polyisocyanate, d) optionally one or more further thermoplastic polymer(s) which does not or do not react to NCO groups. Such compositions have significantly improved mechanical characteristics.
1. A latent-reactive hot-melt adhesive composition comprising:
a) at least one first thermoplastic polymer which is monofunctionally reactive toward NCO groups and has a tensile strength of σ M ≧4 MPa up to 30 MPa as measured according to EN ISO 527-1:1996 and an elongation at break of ε B ≧5% up to 1000% as measured according to EN ISO 527-1:1996,
b) at least one second NCO-reactive polymer and/or oligomer which is at least di-functionally reactive toward NCO groups and possesses a melting temperature T m which is lower than the melting temperature T m of the at least one first thermoplastic polymer and which is in liquid form at 40° C.,
c) at least one solid, surface-deactivated di- and/or polyisocyanate,
d) optionally one or more further thermoplastic polymers which do not react with NCO groups.
2. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein
a) the at least one first thermoplastic polymer is present at not less than 20 wt %;
b) the at least one second NCO-reactive polymer and/or oligomer is present at from 5 to 40 wt %;
c) the at least one solid, surface deactivated di- and/or polyisocyanate is present at 5 to 25 wt %; and
optionally d) the one or more further thermoplastic polymer(s) is/are present at 0 to 10 wt %.
3. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein the thermoplastic polymer a) has a melting temperature of T m <100° C.
4. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein the di- or polyisocyanate c) has a melting temperature of T m >70° C.
5. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein the at least one solid, surface-deactivated di- and/or polyisocyanate is obtainable by the addition to the di- or polyisocyanate of one or more deactivating agents which react with NCO groups.
6. The latent-reactive hot-melt adhesive composition according to claim 1 , in which the latent-reactive hot-melt adhesive composition is curable in the temperature range from >70 up to 160° C.
7. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein the at least one first thermoplastic polymer a) has an average molecular weight M w ≧25 000 g/mol up to 100 000 g/mol.
8. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein the at least one second NCO-reactive polymer or oligomer b) is a polycaprolactone, polyester, copolyester, polyether, copolyether and/or a polycarbonate having an average molecular weight M w ≧4000 g/mol.
9. The latent-reactive hot-melt adhesive composition according to claim 1 , wherein the di- and/or polyisocyanate is selected from the group consisting of dimeric 2,4-toluene diisocyanate, 1,5-diisocyanatonaphthalene, diisocyanatotolueneureas, 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane isocyanurate, 3,3′-dimethylbiphenyl 4,4′-diisocyanate, 3,3′-diisocyanato-4,4′-dimethyl-N,N-diphenylurea, diphenylmethane 2,2′-diisocyanate dimer, diphenylmethane 2,4′-diisocyanate dimer, diphenylmethane 4,4′-diisocyanate dimer and mixtures, and uretdione dimers.
10. The latent-reactive hot melt adhesive composition according to claim 1 , wherein the adhesive includes the one or more further thermoplastic polymers which do not react with NCO groups.
11. An adhesive composition obtained by heating the latent-reactive hot-melt adhesive composition, according to claim 1 , to a temperature of >70° C. up to 160° C.
12. A coated substrate or adherend comprising a latent-reactive hot-melt adhesive composition comprising:
a) at least one first thermoplastic polymer which is monofunctionally reactive toward NCO groups and has a tensile strength of σ M ≧4 MPa up to 30 MPa as measured according to EN ISO 527-1:1996 and an elongation at break of ε B ≧5% up to 1000% as measured according to EN ISO 527-1:1996,
b) at least one second NCO-reactive polymer and/or oligomer which is at least di-functionally reactive toward NCO groups and possesses a melting temperature T m which is lower than the melting temperature T m of the at least one first thermoplastic polymer and which is in liquid form at 40° C.,
c) at least one solid, surface-deactivated di- and/or polyisocyanate,
d) optionally one or more further thermoplastic polymer(s) which does or do not react with NCO groups.