Manufacturing method of cathode active material, and cathode active material for lithium secondary battery manufactured thereby
View Patent ↗Provided are a method of preparing a cathode active material including coating a surface of a lithium transition metal oxide with a lithium boron oxide by dry mixing the lithium transition metal oxide and a boron-containing compound and performing a heat treatment, and a cathode active material prepared thereby. A method of preparing a cathode active material according to an embodiment of the present invention may easily transform lithium impurities present in a lithium transition metal oxide into a structurally stable lithium boron oxide by performing a heat treatment near the melting point of a boron-containing compound. Also, a coating layer may be formed in which the lithium boron oxide is uniformly coated in an amount proportional to the used amount of the boron-containing compound even at a low heat treatment temperature.
1. A method of preparing a cathode active material, comprising: dry mixing a lithium transition metal oxide and a boron-containing compound; and heating the mixture to obtain a lithium boron oxide coating on a surface of a lithium transition metal oxide in a temperature range of 130° C. to 160° C., wherein the boron-containing compound is H 3 BO 3 .
2. The method of claim 1 , wherein the boron-containing compound is transformed into a lithium boron oxide through a reaction with at least a portion of lithium impurities in the lithium transition metal oxide by the heat treatment.
3. The method of claim 1 , wherein a portion of elemental boron (B) of the lithium boron oxide is doped into the lithium transition metal oxide by the heating of the mixture, and an amount of the B has a concentration gradient gradually decreasing from the surface of the lithium transition metal oxide to inside thereof.
4. The method of claim 2 , wherein the lithium impurities comprise LiOH, Li 2 CO 3 , or a mixture thereof.
5. The method of claim 1 , wherein the mixing is performed by a mortar grinder mixing method or a mechanical milling method.
6. The method of claim 5 , wherein the mixing by the mechanical milling method is performed by using a roll mill, ball mill, high energy ball mill, planetary mill, stirred ball mill, vibrating mill, or jet mill.
7. The method of claim 1 , wherein the boron-containing compound is used in an amount of 0.05 wt % to 1 wt % based on a total weight of the lithium transition metal oxide.
8. The method of claim 1 , wherein the lithium boron oxide is LiBO 2 , Li 2 B 4 O 7 , or a mixture thereof.
9. The method of claim 1 , wherein the lithium transition metal oxide is represented by Chemical Formula 1:
Li 1+a [Ni x Mn y Co z M v ]O 2−c A c <Chemical Formula 1>
where M is any one selected from the group consisting of aluminum (Al), zirconium (Zr), zinc (Zn), titanium (Ti), magnesium (Mg), gallium (Ga), and indium (In), or two or more elements thereof; A is at least one selected from the group consisting of phosphorus (P), fluorine (F), sulfur (S), and nitrogen (N), and 0≤x≤1.0, 0≤y<0.6, 0≤z<0.6, 0≤v≤0.1, 0≤a<0.3, 0≤c≤0.2, and a+x+y+z+v=1.