Catalytic reduction of NO
A system for NO x reduction in combustion gases, especially from diesel engines, incorporates an oxidation catalyst to convert at least a portion of NO to NO 2 , particulate filter, a source of reductant such as NH 3 and an SCR catalyst and methods for operating such a system are disclosed. Considerable improvements in NO x conversion and soot reduction are observed even at relatively low operating temperatures.
1. A system comprising:
a heavy duty diesel truck engine, the heavy duty diesel truck engine configured to produce an exhaust gas comprising particulate matter, NO, and NO 2 ;
an oxidation catalyst in exhaust gas communication with the heavy duty diesel engine, the oxidation catalyst configured to convert a substantial portion of the NO in the exhaust gas to NO 2 ;
a particulate trap in exhaust gas communication downstream of the oxidation catalyst, the particulate trap configured to react a portion of the NO 2 in the exhaust gas with a substantial portion of the particulate matter in the particulate trap;
a urea reductant injector positioned downstream of the particulate trap, the urea reductant injector configured to inject a metered dose of urea reductant into the exhaust gas;
an SCR catalyst, the SCR catalyst configured to reduce the NO and NO 2 in the exhaust gas;
wherein the system is configured to operate at a sufficient temperature to react NO 2 with particulate matter in the particulate trap, and
further wherein the oxidation catalyst and the particulate trap are configured to collectively modify the exhaust gas such that it has an NO to NO 2 ratio of about 4:1 to 1:3 when the exhaust gas exits the particulate trap.
2. The system of claim 1 , wherein the exhaust gas is between 225° C. and 350° C.
3. The system of claim 1 , wherein the exhaust gas is between 250° C. and 425° C.
4. The system of claim 1 , wherein the exhaust gas is between 225° C. and 425° C.
5. The system of claim 4 , wherein the heavy duty diesel truck engine is configured for mobile use.
6. The system of claim 5 , wherein the heavy duty diesel truck engine is turbocharged.
7. The system of claim 6 , wherein the oxidation catalyst comprises a Pt catalyst deposited upon a through-flow honeycomb support.
8. The system of claim 7 , wherein the SCR catalyst comprises a transitional metal/zeolite catalyst.
9. The system of claim 8 , further comprising a clean-up catalyst configured to remove NH 3 from the exhaust gas.
10. The system of claim 9 , wherein the oxidation catalyst and particulate trap are sized and configured such that under the majority of normal on-road operational conditions of the heavy duty diesel truck engine the exhaust gas has a ratio of NO to NO 2 of about 4:1 to 1:3 when the exhaust gas exits the particulate trap.
11. The system of claim 10 , wherein the urea injector is configured to adjust the amount of urea injected into the exhaust gas stream based at least in part upon the NO:NO 2 ratio of the NO x in the exhaust gas stream.
12. The system of claim 11 , wherein the system is configured such that under the majority of normal on-road operational conditions of the heavy duty diesel truck engine the exhaust gas has at least 90% less NO x as it exits the SCR catalyst than the exhaust gas contained before it entered the oxidation catalyst.
13. The system of claim 12 , further comprising a clean-up catalyst in exhaust gas communication downstream of the second SCR catalyst, the clean-up catalyst to remove NH 3 from the exhaust gas.
14. A system comprising:
a first sub-assembly comprising a urea injector in exhaust gas communication with an SCR catalyst, and
a second sub-assembly upstream of the first sub-assembly comprising a Pt oxidation catalyst deposited upon a through-flow honeycomb support in exhaust gas communication with a wall flow particulate filter specifically configured:
(1) for use with a mobile heavy duty diesel truck engine; and
(2) for adjusting the NO to NO 2 ratio of an exhaust gas stream such that:
(i) under identical conditions and duration of operation, more particulate matter is combusted in the particulate filter than would be combusted in the absence of the oxidation catalyst; and
(ii) the NO:NO 2 ratio of the exhaust gas exiting the particulate filter during continuous particulate combustion conditions is suitable for reducing a substantial portion of the remaining NO x as the exhaust gas passes over the SCR catalyst.
15. The system of claim 14 , wherein the second sub-assembly is configured for use with an exhaust gas stream between 225° C. and 350° C.
16. The system of claim 14 , wherein the second sub-assembly is configured for use with an exhaust gas stream between 250° C. and 425° C.
17. The system of claim 14 , wherein the second sub-assembly is configured for use with an exhaust gas stream between 225° C. and 425° C.
18. The system of claim 17 , wherein the second sub-assembly is configured for use with a turbocharged heavy duty diesel truck engine.
19. The system of claim 17 , wherein the second sub-assembly is sized and configured such that under the majority of normal on-road operational conditions of the heavy duty diesel truck engine the exhaust gas stream has a ratio of NO to NO 2 of about 4:1 to 1:3 when the exhaust gas stream exits the particulate trap.
20. The system of claim 19 , wherein the SCR catalyst comprises a transitional metal/zeolite catalyst.
21. The system of claim 20 , wherein the urea injector is configured to adjust the amount of urea injected into the exhaust gas stream based at least in part upon the NO:NO 2 ratio of the NO x in the exhaust gas stream.
22. The system of claim 21 , wherein the first sub-assembly and the second sub-assembly are configured such that under the majority of normal on-road operational conditions of the heavy duty diesel truck engine the exhaust gas stream has at least 90% less NOx as it exits the SCR catalyst than the exhaust gas stream contained before it entered the oxidation catalyst.
23. The system of claim 22 , further comprising a clean-up catalyst in exhaust gas communication downstream of the SCR catalyst, the clean-up catalyst configured to remove NH 3 from the exhaust gas.
24. A system comprising:
a turbocharged heavy-duty diesel truck engine, the heavy-duty diesel truck engine configured to produce an exhaust gas comprising soot-type particulate matter, NO, and NO 2 ;
a Pt oxidation catalyst deposited upon a ceramic through-flow honeycomb support in exhaust gas communication with the heavy-duty diesel engine,
a wall-flow particulate trap in exhaust gas communication downstream of the honeycomb support, the particulate trap configured to combust, at a temperature of between 250° C. and 425° C., at least a substantial portion of the soot-type particulates in the exhaust gas,
an SCR catalyst in exhaust gas communication downstream of the particulate trap, the SCR catalyst configured to reduce the NO and NO 2 in the exhaust gas;
a urea reductant injector configured to inject a metered dose of urea reductant into the exhaust gas upstream of the SCR catalyst;
wherein the system is configured such that, under the majority of normal on-road operational conditions of the heavy-duty diesel truck engine,
the exhaust gas exiting the particulate trap has an NO to NO 2 ratio of about 4:1 to 1:3, and
the exhaust gas exiting the SCR catalyst has at least 90% less NOx relative to an NOx content in the exhaust gas entering the oxidation catalyst.
25. The system of claim 24 , further comprising a clean-up catalyst in exhaust gas communication downstream of the SCR catalyst, the clean-up catalyst configured to remove NH 3 from the exhaust gas.
26. A system comprising:
a turbocharged heavy-duty diesel truck engine, the heavy-duty diesel truck engine configured to produce an exhaust gas comprising soot-type particulate matter, NO, and NO 2 ;
a first sub-assembly in exhaust gas communication with the heavy-duty diesel engine, the sub-assembly comprising:
(i) a Pt oxidation catalyst deposited upon a ceramic through-flow honeycomb support, and
(ii) a wall-flow particulate trap;
a second sub-assembly comprising:
(i) a transitional metal/zeolite SCR catalyst; and
(ii) a urea reductant injector positioned in an exhaust pipe connecting the first and second sub-assemblies, the urea reductant injector configured to inject a metered dose of urea reductant into the exhaust gas;
wherein the system is configured such that, under the majority of normal on-road operational conditions of the heavy-duty diesel truck engine,
(a) the first sub-assembly is operated at a temperature of between 250° C. and 425° C., and the exhaust gas exiting the first sub-assembly has an NO to NO2 ratio pre-determined to be sufficient for the second sub-assembly and at least a substantial percentage of soot-type particulates have been eliminated relative to an amount of soot-type particulates in the exhaust gas entering the first sub-assembly, and
(b) the second sub-assembly is operated at a temperature cooler than the temperature in the first sub-assembly and the exhaust gas exiting the second sub-assembly has at least 90% less NOx relative to an amount of NOx in the exhaust gas entering the first sub-assembly.
27. The system of claim 26 , wherein the oxidation catalyst and particulate trap are sized and configured to provide an exhaust gas stream with a ratio of NO to NO 2 of 4:1 to 1:3 at the exit of the particulate trap.
28. The system of claim 26 , further comprising a clean-up catalyst in exhaust gas communication downstream of the second sub-assembly, the clean-up catalyst configured to remove NH 3 from the exhaust gas.
29. The system of claim 26 , wherein the first sub-assembly comprises:
(i) the Pt oxidation catalyst deposited upon a ceramic through-flow honeycomb support, and
(ii) the wall-flow particulate trap.
30. The system of claim 29 , wherein the second sub-assembly comprises the transitional metal/zeolite SCR catalyst and the urea injector.
31. The system of claim 29 , further comprising a clean-up catalyst in exhaust gas communication downstream of the second sub-assembly, the clean-up catalyst configured to remove NH 3 from the exhaust gas.
32. The system of claim 26 , wherein the second sub-assembly comprises the transitional metal/zeolite SCR catalyst and the urea injector.
33. The system of claim 32 , further comprising a clean-up catalyst in exhaust gas communication downstream of the second sub-assembly, the clean-up catalyst configured to remove NH 3 from the exhaust gas.
34. The system of claim 32 , further comprising a clean-up catalyst in exhaust gas communication downstream of the second sub-assembly, the clean-up catalyst configured to remove NH 3 from the exhaust gas.