Polymer matrices functionalized with carbon-containing species for enhanced thermal conductivity
View Patent ↗Disclosed are thermally conductive composites that include a polymer matrix functionalized with a carbon-containing species covalently coupled with the polymer matrix. Also disclosed are methods that generally include functionalizing a carbon-containing species and incorporating the functionalized carbon-containing species into the polymer, such that the carbon-containing species are covalently bonded to the polymer matrix via a coupling agent.
1. A material comprising a polymer matrix functionalized with a carbon-containing species covalently coupled with the polymer matrix, wherein the carbon-containing species is covalently bonded to the polymer matrix via a coupling agent that is part of the polymer matrix, and the polymer matrix comprises a two-part silicone matrix including a first part operable as the coupling agent and a second part operable as a functionalization molecule;
wherein the polymer matrix includes at least one thermally conductive filler; and/or
wherein the functionalization of the polymer matrix improves thermal conductivity of the polymer matrix by at least 11%.
2. The material of claim 1 , wherein
the carbon-containing species has at least one dimension less than 100 nanometers.
3. The material of claim 1 , wherein:
the functionalization molecule comprises polydimethylsiloxane (PDMS) or a derivative thereof; and/or
polydimethylsiloxane (PDMS) chains are covalently attached to the carbon-containing species.
4. The material of claim 1 , wherein the carbon-containing species comprises graphene nanoplatelets.
5. The material of claim 1 , wherein:
the functionalization of the polymer matrix with the functionalized carbon-containing species enhances thermal conductivity of the polymer matrix while retaining electrical insulation properties such that the functionalized polymer matrix is thermally conductive and dielectric; and/or
the functionalization of the polymer matrix with the functionalized carbon-containing species enhances thermal conductivity without having to increase a loading amount of thermally conductive filler in the polymer matrix.
6. The material of claim 1 , wherein:
the functionalization of the polymer matrix improves thermal conductivity of the polymer matrix by about 20% to about 40%; and/or
the material has a thermal conductivity of 4 Watts per meter Kelvin or more; and/or
the material further comprises at least one thermally conductive filler in the functionalized polymer matrix, to thereby enhance thermal conductivity.
7. The material of claim 1 , wherein electrical conductivity is selectively tunable based on functionalization level such that the material is electrically insulative or electrically conductive.
8. A thermally conductive material comprising the material of claim 1 and at least one thermally conductive filler in the polymer matrix, wherein the thermally conductive material comprises a thermal interface material, a thermally conductive composite, and/or a conformable thermal interface material suitable for use to fill a gap between at least two surfaces to transfer heat between the at least two surfaces.
9. A material comprising a polymer matrix functionalized with a carbon-containing species covalently coupled with the polymer matrix, wherein the carbon-containing species is covalently bonded to the polymer matrix via a coupling agent that is part of the polymer matrix, wherein the polymer matrix is prepared from 3-methacryloxypropyltrimethoxylsilane (MPTMS) and polydimethylsiloxane (PDMS).
10. The material of claim 9 , wherein:
the carbon-containing species is covalently bonded to the polymer matrix via the MPTMS; and/or
the PDMS is operable as a functionalization molecule.
11. The material of claim 9 , wherein PDMS chains are covalently attached to the carbon-containing species.
12. A material comprising a polymer matrix functionalized with a carbon-containing species covalently coupled with the polymer matrix, wherein the carbon-containing species is covalently bonded to the polymer matrix via a coupling agent that is part of the polymer matrix, wherein the polymer matrix is functionalized with 3 wt % (weight percent) of PDMS-functionalized graphene, whereby anchoring of the PDMS chains onto the surface of the graphene retains dielectric and electrical insulation properties of the functionalized polymer matrix.
13. A material comprising a polymer matrix functionalized with a carbon-containing species covalently coupled with the polymer matrix, wherein the carbon-containing species is covalently bonded to the polymer matrix via a coupling agent that is part of the polymer matrix, wherein:
the carbon-containing species comprises exfoliated graphene nanoplatelets; and
the polymer matrix comprises a silicone matrix functionalized with the exfoliated graphene nanoplatelets and including at least one thermally conductive filler.
14. The material of claim 13 , wherein the functionalized silicone matrix includes 2 wt % (weight percent) exfoliated graphene nanoplatelets and 47 wt % (weight percent) boron nitride.
15. A method of enhancing thermal conductivity of a polymer matrix, the method comprising functionalizing a carbon-containing species and incorporating the functionalized carbon-containing species into the polymer matrix, such that the carbon-containing species are covalently bonded to the polymer matrix via a coupling agent that is part of the polymer matrix, and the polymer matrix comprises a two-part silicone matrix including a first part operable as the coupling agent and a second part operable as a functionalization molecule;
wherein the polymer matrix includes at least one thermally conductive filler; and/or
wherein the functionalization of the polymer matrix improves thermal conductivity of the polymer matrix by at least 11%.
16. The method of claim 15 , wherein the carbon-containing species comprises graphene nanoplatelets.
17. A method of enhancing thermal conductivity of a polymer matrix, the method comprising functionalizing a carbon-containing species and incorporating the functionalized carbon-containing species into the polymer matrix, such that the carbon-containing species are covalently bonded to the polymer matrix via a coupling agent, wherein:
the carbon-containing species comprises graphene nanoplatelets; and
the method includes:
functionalizing the graphene nanoplatelets by a reaction between hydroxyl groups on edges of the graphene nanoplatelets and the coupling agent via covalent bonding to incorporate double bonds on the surface of the graphene nanoplatelets; and
reacting the double bonds on the surface of the graphene nanoplatelets.
18. The method of claim 17 , wherein the method includes incorporating the functionalized graphene nanoplatelets into the polymer matrix and curing the polymer matrix and functionalized graphene nanoplatelets.
19. The method of any one of claim 18 , wherein the curing includes using ultraviolet radiation at room temperature.
20. The method of claim 17 , wherein the reacting of the double bonds on the surface of the graphene nanoplatelets occurs at a temperature ranging from room temperature to 200° C.
21. The method of claim 17 , wherein the method includes:
functionalizing the graphene nanoplatelets by means of a reaction between hydroxyl groups on edges of the graphene nanoplatelets and the coupling agent via covalent bonding of O—Si group to incorporate double bonds on the surface of the graphene nanoplatelets; and
reacting the double bonds on the surface of the graphene nanoplatelets with the Si—H groups on functionalization molecules.
22. The method of claim 17 , wherein:
the polymer matrix comprises 3-methacryloxypropyltrimethoxylsilane (MPTMS) and polydimethylsiloxane (PDMS);
the method includes:
functionalizing the graphene nanoplatelets by means of a reaction between hydroxyl groups on edges of the graphene nanoplatelets and the MPTMS via covalent bonding of O—Si group to incorporate double bonds on the surface of the graphene nanoplatelets; and
reacting the double bonds on the surface of the graphene nanoplatelets with the Si—H groups on PDMS chains via a hydrosilation reaction in the presence of a platinum based catalyst at a sufficient temperature, whereby the PDMS chains are wrapped around the graphene nanoplatelets.
23. The method of claim 22 , wherein the method includes incorporating the PDMS functionalized graphene nanoplatelets into the polymer matrix and curing the polymer matrix and PDMS functionalized graphene nanoplatelets to obtain a gel.
24. The method of claim 23 , wherein during the curing, the PDMS functionalized graphene nanoplatelets become a part of the siloxane network due to a reaction between the double bonds on the graphene surface and the Si—H groups of the polydimethylsiloxane (PDMS) of polymer matrix.
25. The method of claim 23 , wherein:
the hydrosilation reaction occurs at a temperature of 150° C.; and/or
the curing occurs at a temperature of 150° C.