IP Library Granted Patent US 12,180,099
Granted Patent B2
US 12,180,099 · App. 14/505,309 · Granted Dec 31, 2024

Water treatment compositions and methods of use

Inventors: Francis Kneib (Phoenix, AZ); Everett J. Nichols (Edmonds, WA); James R. Scott (Bellevue, WA); Ryan Wietholter (Chicago, IL)
Assignee: Dober Chemical Corp.
C02F1/5245C02F1/5263C02F2101/10C02F2101/105C02F2101/32C02F2103/10C02F2103/20C02F2103/32C02F2103/343C02F2103/365C02F2303/04
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Quick Facts
Patent No.
US 12,180,099
App. No.
14/505,309
Granted
Dec 31, 2024
Kind
B2
Abstract

Methods for clarifying water, reducing turbidity of water, and removing phosphate from water include adding a water treatment composition having an aluminum-containing coagulant, and a natural non-charged polysaccharide, such as guar. The aluminum-containing compound can include polyaluminum chloride, aluminum chlorohydrate, polyaluminum chlorohydrate, aluminum sulfate, sodium aluminate, polyaluminum sulfate, polyaluminum silicate chloride, polyaluminum silicate sulfate, or a combination thereof.

Claims (27)

1. A composition consisting of the following components:

polyaluminum chloride having a basicity greater than 65% and less than 70%;

uncharged guar; and

water,

wherein a weight ratio of the polyaluminum chloride to the uncharged guar in the composition is between 10:1 and 100:1;

said composition being capable of clarifying or reducing a turbidity of a turbid water when an effective amount of said composition is mixed therewith.

2. The composition of claim 1 , wherein the weight ratio of the uncharged guar to the polyaluminum chloride is about 1:34.

3. The composition of claim 1 , wherein the composition is made by a process comprising mixing the uncharged guar in a solid guar form and the polyaluminum chloride in a solid polyaluminum chloride form, and adding the water to the solid guar form and the solid polyaluminum chloride form.

4. A method for clarifying or reducing a turbidity of drill water, the method comprising:

mixing a composition consisting of the following components:

polyaluminum chloride having a basicity greater than 65% and less than 70%; and

uncharged guar, wherein a weight ratio of the polyaluminum chloride to the uncharged guar in the composition is between 10:1 and 100:1;

with the drill water;

forming agglomerations in the drill water containing the composition that is mixed; and

removing the agglomerations from the drill water,

thereby clarifying or reducing the turbidity of the drill water.

5. The method of claim 4 , comprising:

mixing the uncharged guar in solid form and the polyaluminum chloride in solid form to form a solid mixture and adding water to said solid mixture.

6. A method for clarifying or reducing a turbidity of a process water comprising suspended materials from oil or gas drilling, hydraulic fracturing, or oil refinery operations, the method comprising:

the step of forming a mixture comprising mixing a composition consisting of the following components:

polyaluminum chloride having a basicity greater than 65% and less than 70%; and

uncharged guar; and

water,

wherein a weight ratio of the polyaluminum chloride to the uncharged guar in the composition is between 10:1 and 100:1;

with the process water from oil refinery operations containing suspended materials to form a mixed liquid;

forming agglomerations in the mixed liquid;

removing the agglomerations from the mixed liquid, thereby clarifying or reducing the turbidity of the process water.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY NAME PREVIOUSLY RECORDED ON REEL 038789 FRAME 0280. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jul 7, 2016
From: HALOSOURCE, INC.
To: DOBER CHEMICAL CORP.
Reel/Frame 039460/0294 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2016
From: KNEIB, FRANCIS; NICHOLS, EVERETT J; SCOTT, JAMES R; WIETHOLTER, RYAN
To: HALOSOURCE, INC.
Reel/Frame 039129/0578 →
NUNC PRO TUNC ASSIGNMENT Recorded Jun 2, 2016
From: HALOSOURCE, INC.
To: DOBER CHEMCIAL CORP.
Reel/Frame 038789/0280 →
Continuity (4)
Continuation 13851826 · Mar 27, 2013
Provisional Application 61798333 · Mar 15, 2013
Provisional Application 61616943 · Mar 28, 2012
Related Publication 20150090667A1 · Apr 2, 2015