IP Library Granted Patent US 9,394,503
Granted Patent B2
US 9,394,503 · App. 14/514,206 · Granted Jul 19, 2016

Separation process of oil and sugars from biomass

Inventors: Stephen P Long (Champaign, IL); Vijay Singh (Savoy, IL); Haibo Huang (Urbana, IL)
Assignee: The Board of Trustees of the University of Illinois
C11B1/10B02C23/08C07H1/08C07H3/04C11B1/04C11B1/06C11B3/006C11B3/008C11B3/16
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Quick Facts
Patent No.
US 9,394,503
App. No.
14/514,206
Granted
Jul 19, 2016
Kind
B2
Abstract

Process for recovery and separation of sugars and oil from plants where the stems and leaves of such plants have substantial levels of both sugars and oils.

Claims (45)

1. A method of recovering oil and sugars from a modified plant comprising stems and leaves, wherein the stems and leaves each contain oil selected from lipids, in an amount from 0.1 to 25 wt % on a dry matter basis and sugars selected from sucrose, glucose, fructose, other mono, di, or tri saccharides, or mixtures thereof in an amount from 0.1 to 55 wt % on a dry matter basis,

the method comprising:

mechanically treating the plant to release liquid comprising the oil and sugars from the stems and leaves, thereby forming a mechanically treated mixture comprising the liquid and solid components, the mechanical treatment being selected from at least one of shredding, crushing and pressing;

separating the oil from the liquid, thereby forming an oil-rich stream, the oil separation step being selected from centrifugation, membrane filtration, or solvent extraction; and

separating the sugars from the liquid, thereby forming a sugar-rich solution, the sugar separation step being selected from centrifugation or membrane filtration.

2. The method of claim 1 , further comprising purifying the oil-rich stream, the oil purification step being selected from physical, chemical or biological processes.

3. The method of claim 1 , further comprising purifying the sugar-rich solution, the sugar-solution purification step being selected from physical, chemical or biological processes.

4. The method of claim 1 , further comprising treating the solid component in a solid component processing step selected from physical, chemical or biological processes.

5. The method of claim 1 wherein the plant is a grass.

6. The method of claim 5 wherein the grass is a saccharinae.

7. The method of claim 6 wherein the saccharinae is sugarcane or sweet sorghum.

8. The method of claim 1 wherein the mechanical treatment comprises crushing in a roller mill.

9. The method of claim 8 wherein during crushing, the mechanically treated mixture is immersed in hot water or solvents.

10. The method of claim 1 wherein the lipids are selected from fats, waxes, sterols, monoglycerides, diglycerides, triglycerides, phospholipids or mixtures thereof.

11. The method of claim 1 wherein the mechanical treatment step comprises at least two of shredding, crushing and pressing.

12. The method of claim 1 wherein the mechanical treatment step comprises shredding, crushing and pressing.

13. The method of claim 1 wherein the sugars are selected from sucrose, other di, or tri saccharides, or mixtures thereof.

14. The method of claim 1 wherein the lipids are present in an amount from 0.5 to 25 wt %.

15. The method of claim 1 wherein the sugars are present in an amount from 1.0 to 55 wt %.

16. The method of claim 1 wherein the lipids are present in an amount from 0.5 to 25 wt % and the sugars are present in an amount from 1.0 to 55 wt %.

17. A method of recovering oil and sugars from a modified plant comprising stems and leaves, wherein the stems and leaves each contain oil selected from lipids in an amount from 0.1 to 25 wt % on a dry matter basis and sugars selected from sucrose, glucose, fructose, other mono, di, or tri saccharides, or mixtures thereof in an amount from 0.1 to 55 wt % on a dry matter basis,

the method comprising:

mechanically treating the plant to release liquid comprising oil and sugars from the stems and leaves, thereby forming a mechanically treated mixture comprising the liquid and solid components, the mechanical treatment being selected from at least one of shredding and crushing;

separating the liquid from the solid component in a liquid-solid separation step selected from centrifugation or filtration, thereby forming a separated liquid stream and a separated solid component stream;

separating the oils from the sugars in the separated liquid stream in a solvent extraction step, thereby forming a raw sugar solution stream and a miscella stream comprising oil and solvent;

removing solvent from the miscella stream in an evaporation step, thereby forming an oil-rich stream and a solvent recycle stream; and

returning the solvent stream to the solvent extraction step.

18. A method of recovering oil and sugars from a modified plant comprising stems and leaves, wherein the stems and leaves each contain oil selected from lipids in an amount from 0.1 to 25 wt % on a dry matter basis and sugars selected from sucrose, glucose, fructose, other mono, di, or tri saccharides, or mixtures thereof in an amount from 0.1 to 55 wt % on a dry matter basis,

the method comprising:

mechanically treating the plant to release liquid comprising oil and sugars from the stems and leaves, thereby forming a mechanically treated mixture comprising the liquid and solid components, the mechanical treatment being selected from at least one of shredding and crushing;

separating the liquid from the solid component in a liquid-solid separation step selected from centrifugation or filtration, thereby forming a separated liquid stream and a separated solid component stream;

separating the oil from the sugars in the separated liquid stream in a membrane filtration step, thereby forming a raw sugar solution stream and an oil-rich stream comprising oil; and

concentrating the oil in the oil-rich stream in an evaporation step, thereby forming a concentrated oil stream.

19. A method of recovering oil and sugars from a modified plant comprising stems and leaves, wherein the stems and leaves each contain oil selected from lipids in an amount from 0.1 to 25 wt % on a dry matter basis and sugars selected from sucrose, glucose, fructose, other mono, di, or tri saccharides, or mixtures thereof in an amount from 0.1 to 55 wt% on a dry matter basis,

the method comprising:

mechanically treating the plant to release liquid comprising oil and sugars from the stems and leaves, thereby forming a mechanically treated mixture comprising the liquid and solid components, the mechanical treatment being selected from at least one of shredding and crushing;

extracting the mechanically treated mixture in a solvent extraction step, thereby forming a de-oiled material stream comprising sugars and a solid component, and a miscella stream comprising oil and solvent;

removing solvent from the miscella stream in an evaporation step, thereby forming an oil-rich stream and a solvent recycle stream; and

separating the sugars from the solid component in the de-oiled material stream in a membrane filtration step, thereby forming a raw sugar solution and a solid component stream.

20. A method of recovering oil and sugars from a modified plant comprising stems and leaves, wherein the stems and leaves each contain oil selected from lipids in an amount from 0.1 to 25 wt % on a dry basis and sugars selected from sucrose, glucose, fructose, other mono, di, or tri saccharides, or mixtures thereof in an amount from 0.1 to 55 wt % on a dry matter basis,

the method comprising:

mechanically treating the plant to release liquid from the stems and leaves, thereby forming a mechanically treated mixture comprising a juice stream comprising the oil and sugars, the mechanical treatment being selected from at least one of shredding and crushing;

fermenting the juice stream in a fermentation step to convert the sugars to ethanol, thereby forming a fermented mixture;

evaporating the ethanol from the fermented mixture in an evaporation step, thereby forming a raw oil stream; and

extracting the raw oil stream in a solvent extraction step to separate oil from the raw oil stream, thereby forming an oil enriched stream.

Assignments (2)
CONFIRMATORY LICENSE Recorded Jul 22, 2018
From: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 046602/0321 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2018
From: LONG, STEPHEN P.; SINGH, VIJAY; HUANG, HAIBO
To: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
Reel/Frame 046384/0781 →
Continuity (2)
Provisional Application 61891211 · Oct 15, 2013
Related Publication 20150105546A1 · Apr 16, 2015