IP Library Granted Patent US 9,695,317
Granted Patent B2
US 9,695,317 · App. 14/515,202 · Granted Jul 4, 2017

Fuel-resistant liquid asphalt binders and methods of making the same

Inventor: Ronald Corun (Ocean City, MD)
Assignee: Associated Asphalt Marketing, LLC
C08L95/00C08J3/203C08J3/24C08K5/17C08J2395/00C08J2409/06
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Quick Facts
Patent No.
US 9,695,317
App. No.
14/515,202
Granted
Jul 4, 2017
Kind
B2
Abstract

A fuel-resistant liquid asphalt binder including a composition of fatty amine derivatives for improving the flowability and workability of a bituminous asphalt mix. The fuel-resistant liquid asphalt binder may include 0.4 wt % to 0.7 wt % of a composition of fatty amine derivatives, 2 wt % to 5 wt % styrene-butadiene-styrene, and 2 wt % to 5 wt % high acetate content ethyl vinyl acetate. The fuel-resistant liquid asphalt binder may be mixed with an aggregate to form a bituminous asphalt mix at temperatures ranging from 330° F. to 280° F.

Claims (35)

1. A fuel-resistant liquid asphalt binder comprising:

a liquid asphalt binder base having a concentration in the range of 89.3 wt % to 95.6 wt %;

styrene-butadiene-styrene having a concentration in the range of 2 wt % to 5 wt %;

high acetate content ethylene vinyl acetate having a concentration in the range of 2 wt % to 5 wt %; and

a composition of fatty amine derivatives having a concentration in the range of 0.4 wt % to 0.7 wt %.

2. The fuel-resistant liquid asphalt binder of claim 1 , wherein the styrene-butadiene-styrene has a concentration in the range of 3 wt % to 4 wt %.

3. The fuel-resistant liquid asphalt binder of claim 1 , wherein the high acetate content ethylene vinyl acetate has a concentration in the range of 3 wt % to 4 wt %.

4. The fuel-resistant liquid asphalt binder of claim 1 , wherein the composition of fatty amine derivatives has a concentration in the range of 0.45 wt % to 0.55 wt %.

5. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder has an ASTMD7173 maximum temperature difference of less than or equal to 40° F. when using a ASTM D36 Ring and Ball apparatus.

6. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder has a minimum performance grade of PG 82-22.

7. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder has an ASTM D6084 elastic recovery at 25° C. of greater than or equal to 85%.

8. A bituminous asphalt mix comprising:

a fuel-resistant liquid asphalt binder comprising:

a liquid asphalt binder base having a concentration in the range of 89.3 wt % to 95.6 wt %;

styrene-butadiene-styrene having a concentration in the range of 2 wt % to 5 wt %;

high acetate content ethylene vinyl acetate having a concentration in the range of 2 wt % to 5 wt %; and

a composition of fatty amine derivatives having a concentration in the range of 0.4 wt % to 0.7 wt %,

air voids; and

an aggregate.

9. The bituminous asphalt mix of claim 8 , wherein the fuel-resistant liquid asphalt binder has a concentration in the range of 4 wt % to 9 wt %.

10. The bituminous asphalt mix of claim 8 , wherein the air voids have a concentration in the range of 2 vol % to 3 vol %.

11. The bituminous asphalt mix of claim 8 , wherein the mix has a weight loss by fuel immersion of less than 2.5% when measured according to FAA P-601 test specifications.

12. A method of making a fuel-resistant liquid asphalt binder, the method comprising:

mixing a liquid asphalt binder base and styrene-butadiene-styrene in a high shear mixer, thereby forming a first mixture;

adding at least one cross-linking agent to the first mixture;

curing the first mixture;

mixing the first mixture with high acetate content ethylene vinyl acetate in a high shear mixer; thereby forming a second mixture; and

mixing a composition of fatty amine derivatives with the second mixture, thereby forming the fuel-resistant liquid asphalt binder;

wherein the liquid asphalt binder base has a concentration in the range of 89.3 wt % to 95.6 wt % in the fuel-resistant liquid asphalt binder; the styrene-butadiene-styrene has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder; the high acetate content ethylene vinyl acetate has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder; and the composition of fatty amine derivatives has a concentration in the range of 0.4 wt % to 0.7 wt % in the fuel-resistant liquid asphalt binder.

13. The method of claim 12 , wherein the styrene-butadiene-styrene has a concentration in the range of 3 wt % to 4 wt % in the fuel-resistant liquid asphalt binder.

14. The method of claim 12 , wherein the high acetate content ethylene vinyl acetate has a concentration in the range of 3 wt % to 4 wt % in the fuel-resistant liquid asphalt binder.

15. The method of claim 12 , wherein the composition of fatty amine derivatives has a concentration in the range of 0.45 wt % to 0.55 wt % in the fuel-resistant liquid asphalt binder.

16. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder has an ASTMD7173 maximum temperature difference of less than or equal to 40° F. when using a ASTM D36 Ring and Ball apparatus,

wherein the fuel-resistant liquid asphalt binder has a minimum performance grade of PG 82-22, and

wherein the fuel-resistant liquid asphalt binder has an ASTM D6084 elastic recovery at 25° C. of greater than or equal to 85%.

Assignments (14)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2024
From: ASSOCIATED ASPHALT PARTNERS, LLC
To: ERGON ASPHALT & EMULSIONS, INC.
Reel/Frame 068329/0161 →
RELEASE OF SECURITY INTEREST Recorded Dec 15, 2023
From: PNC BANK, NATIONAL ASSOCIATION
To: ASSOCIATED ASPHALT PARTNERS, LLC
Reel/Frame 065888/0549 →
RELEASE OF SECURITY INTEREST Recorded Dec 15, 2023
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS SUCCESSOR COLLATERAL AGENT TO CREDIT SUISSE AG
To: ASSOCIATED ASPHALT PARTNERS, LLC
Reel/Frame 065888/0503 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY AT REEL/FRAME NO. 41980/0750 Recorded Jul 1, 2021
From: KEYBANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: ASSOCIATED ASPHALT MARKETING, LLC
Reel/Frame 056752/0069 →
SECURITY INTEREST Recorded Jun 30, 2021
From: ASSOCIATED ASPHALT PARTNERS, LLC; ASSOCIATED ASPHALT, INC.; ASSOCIATED ASPHALT TAMPA, LLC
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 056719/0238 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 20, 2021
From: ASSOCIATED ASPHALT MARKETING, LLC
To: ASSOCIATED ASPHALT PARTNERS, LLC
Reel/Frame 055660/0418 →
ASSIGNMENT AND ASSUMPTION OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Nov 6, 2020
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS RESIGNING COLLATERAL AGENT
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 054341/0223 →
CHANGE OF ADDRESS Recorded Dec 10, 2018
From: ASSOCIATED ASPHALT MARKETING, LLC
To: ASSOCIATED ASPHALT MARKETING, LLC
Reel/Frame 047762/0030 →
CHANGE OF NAME Recorded Apr 17, 2017
From: AXEON MARKETING LLC
To: ASSOCIATED ASPHALT MARKETING, LLC
Reel/Frame 042269/0246 →
SECURITY INTEREST Recorded Apr 5, 2017
From: BLUE RIDGE ASPHALT II, LLC; ROAD HOLDINGS III, L.L.C.; ASSOCIATED ASPHALT PARTNERS, LLC; BLUE RIDGE ASPHALT II, INC.; ROAD HOLDINGS, INC.; ASSOCIATED ASPHALT FINANCE CORP.; TC ASPHALT CORPORATION; ASSOCIATED ASPHALT, INC.; ASSOCIATED ASPHALT DISTRIBUTION, LLC; ASSOCIATED ASPHALT EQUIPMENT, LLC; ASSOCIATED ASPHALT TRANSPORT, LLC; ASSOCIATED ASPHALT ROANOKE, LLC; ASSOCIATED ASPHALT INMAN, LLC; ASSOCIATED ASPHALT SALISBURY, LLC; ASSOCIATED ASPHALT GREENSBORO, LLC; ASSOCIATED ASPHALT MARTINSBURG, LLC; ASSOCIATED ASPHALT TAMPA, LLC; BITUMINOUS TECHNOLOGIES, LLC; ASSOCIATED ASPHALT BRISTOL, LLC; ASSOCIATED ASPHALT GAINESVILLE, LLC; ASSOCIATED ASPHALT CHARLOTTE, LLC; AA PROPERTIES-ROANOKE, LLC; AA PROPERTIES-INMAN, LLC; AA PROPERTIES-SALISBURY, LLC; AA PROPERTIES-GREENSBORO, LLC; AA PROPERTIES-MARTINSBURG, LLC; AA PROPERTIES-TAMPA, LLC; AA PROPERTIES-PORT OF TAMPA, LLC; AA PROPERTIES-BRISTOL, LLC; AA PROPERTIES-PINEVILLE, LLC; AA PROPERTIES-GAINESVILLE, LLC; ASSOCIATED ASPHALT COLUMBIA, LLC; ASSOCIATED ASPHALT CONLEY, LLC; AA PROPERTIES-RICHLAND COUNTY, LLC; AA PROPERTIES-CONLEY, LLC; AA PROPERTIES-EDISTO, LLC; AA PROPERTIES-COMMERCE TULLER, LLC; AA PROPERTIES-CHURCH AVENUE, LLC; ASSOCIATED ASPHALT LAKE CITY, LLC; ASSOCIATED ASPHALT HOPEWELL, LLC; ASSOCIATED ASPHALT SAVANNAH, LLC; AA DISTRIBUTION-COLUMBIA, LLC; ASSOCIATED ASPHALT WINSTON-SALEM, LLC; AA PROPERTIES-HOPEWELL, LLC; ASSOCIATED ASPHALT MARKETING, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 041866/0648 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY ADDRESS PREVIOUSLY RECORDED AT REEL: 041184 FRAME: 0376. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 24, 2017
From: AXEON SPECIALTY PRODUCTS LLC
To: AXEON MARKETING LLC
Reel/Frame 042086/0455 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT SUPPLEMENT Recorded Mar 13, 2017
From: ASSOCIATED ASPHALT MARKETING, LLC
To: KEYBANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 041980/0750 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 6, 2017
From: AXEON SPECIALTY PRODUCTS LLC
To: AXEON MARKETING LLC
Reel/Frame 041184/0373 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2014
From: CORUN, RONALD
To: AXEON SPECIALTY PRODUCTS LLC
Reel/Frame 034123/0728 →
Continuity (1)
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