Solvent-free processing, system and methods
Disclosed is a process for purifying one or more chemical constituents from plant matter using extraction with a fluid that is not a solvent, for example, with a vegetable oil. The extracted chemical constituents may then optionally be further processed by heating in order to induce desired chemical transformations. The extracted chemical constituents are also processed by concentrating at reduced pressure, for example, by distillation.
1. A method for purifying a cannabinoid from plant matter, the method comprisirg:
contacting the plant matter with a non-solvent comprising canola oil, tributylmethylammonium methyl sulfate, or 1-butyl -3-methylimidazolium chloride;
extracting a cannabinoid into the non-solvent to produce a mixture comprising;
a non-solvent enriched in the cannabinoid; and plant matter residue;
separating the enriched non-solvent from the Plant matter residue; and
volatilizing the cannabinoid out of enriched non-solvent to produce a purified cannabinoid.
2. A method for purifying a cannabinoid from plant matter, the method comprising:
contacting the plant matter with a non-solvent comprising canola oil, tributylmethylammonium methyl sulfate, or 1-butyl-3-methylimidazolium chloride;
extracting a cannabinoid into the non-solvent to produce a mixture comprising: a non-solvent enriched in the cannabinoid; and plant matter residue;
separating the enriched non-solvent from the plant matter residue; and
volatilizing the cannabinoid out of the enriched non-solvent to produce a purified cannabinoid;
further comprising decarboxylating the cannabinoid to produce a decarboxylated cannabinoid.
3. The method of claim 2 , wherein the decarboxylation step occurs in conjunction with the volatilizing step.
4. The method of claim 2 , wherein he decarboxylation step occurs separately from the volatilizing step.
5. A method for purifying a cannabinoid from plant matter;
the method comprisin:
contacting the plant matter with a non-solvent comprising canola oil, tributylmethylammonium methyl sulfate, or 1-butyl-3-methylimidazolium chloride;
extracting a cannabinoid into the non-solvent to produce a mixture comprising; a non-solvent enriched in the cannabiniod; and plant matter residue;
separating the enriched non-solvent from the plant matter residue; and
volatilizing the cannabinoid out of the enriched non-solvent to produce a purified cannabinoid; wherein the cannabinoid is a cannabinoid acid and the purified cannabinoid is a decarboxylated cannabinoid.
6. The method of claim 5 , wherein decarboxylation comprises heating.
7. The method of claim 6 , wherein heating comprises elevating the temperature of the cannabinoid above 100 degrees C.
8. The method of claim 6 , wherein heating comprises drawing hot gas through the enriched non-solvent.
9. The method of claim 6 , wherein heating comprises, contacting the enriched non-solvent with at least a hot surface.
10. The method of claim 9 , wherein the at least a hot surface is more than 70 degrees C. hotter than the enriched non-solvent prior to heating.
11. The method of claim 2 , therein the plant matter comprises cannabaceae.
12. The method claim 1 , wherein the method is performed at an operating pressure greater than one (1) atmosphere.