Catalyst and process for the production of diesel fuel from natural gas, natural gas liquids, or other gaseous feedstock
A unique process and catalyst is described that operates efficiently for the direct production of a high cetane diesel type fuel or diesel type blending stock from stoichiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 10,000 barrels of product per day, by eliminating traditional wax upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as gas to liquids production and other applications that require optimized economics based on supporting distributed feedstock resources.
1. A process for the production of a hydrocarbon mixture comprising the steps of:
a) reducing a catalyst in-situ in a fixed bed reactor, wherein the catalyst has a support, and wherein the support is selected from a group consisting of alumina, silica, carbon nanotubes, carbon nanofibers, zeolites and combinations thereof, and wherein the catalyst comprises a metal catalyst and a promoter, and wherein the metal catalyst comprises cobalt, iron, nickel or combinations thereof, and wherein the promoter comprises cerium, ruthenium, lanthanum, platinum, rhenium, gold, nickel or rhodium;
b) reacting a feed gas that contains hydrogen and carbon monoxide with the catalyst to produce a hydrocarbon product stream, wherein the hydrocarbon product stream comprises light gases, a diesel fuel and a wax
wherein the diesel fuel fraction is produced without requiring the hydroprocessing of wax.
2. A process for the production of a hydrocarbon mixture comprising:
a) reducing a catalyst in-situ in a fixed bed reactor, wherein the catalyst has a support, and wherein the support is selected from a group consisting of alumina, silica, carbon nanotubes, carbon nanofibers, zeolites and combinations thereof, and wherein the catalyst comprises a metal catalyst and a promoter, and wherein the metal catalyst comprises cobalt, iron, nickel or combinations thereof, and wherein the promoter comprises cerium, ruthenium, lanthanum, platinum, rhenium, gold, nickel or rhodium;
b) reacting a feed gas that contains hydrogen and carbon monoxide with the catalyst
thereby producing a hydrocarbon product stream comprising light gases, diesel fuel and a wax, wherein the majority of hydrocarbons in the diesel fuel are C 8 -C 24 hydrocarbons.
3. The process of claim 1 , wherein the catalyst is reduced with hydrogen at temperatures below 650 F.
4. The process of claim 1 , wherein the diesel fuel fraction produced is about ⅔ of the non-gas product produced.
5. The process of claim 1 , wherein the catalyst support is a lobed support with more than four lobes and an effective pellet radius of less than 600 microns.
6. The process of claim 5 , where all of the lobes are not equal lengths.
7. The process of claim 1 , wherein the light wax fraction produced from the catalyst consists of hydrocarbons contained in the wax consist of no greater than 0.5 wt. % of each carbon number greater than C35.
8. The process of claim 1 , further comprising blending a cold flow improver to the diesel fuel.
9. The process of claim 1 , further comprising reacting the diesel fuel with a platinum-promoted catalyst to isomerize the diesel fuel.
10. The process of claim 1 , further comprising reacting the diesel fuel with a hydrogenation catalyst.
11. The process of claim 1 , wherein the catalyst is reduced with syngas at temperatures below 650 F.