Process for the manufacture of self-binding pigmentary particles, dry or in aqueous suspension or dispersion, containing inorganic matter and binders
The present invention is directed to a process for the preparation of an aqueous suspension of self-binding pigmentary particles comprising the following stages: (a) forming one or more aqueous suspensions of at least one inorganic matter comprising calcium carbonate; (b) forming or obtaining one or more aqueous solutions or suspensions or emulsions of at least one binder; and (c) co-grinding the aqueous suspension or suspensions obtained in stage a) with the aqueous solutions or suspensions or emulsions obtained in stage b) in a mill so as to obtain an aqueous suspension of self-binding pigmentary particles.
1. Self-binding pigmentary particles comprising at least one inorganic matter and at least one binder, said pigmentary particles obtained by a process comprising the following stages:
a) forming one or more aqueous suspensions of at least one inorganic matter comprising calcium carbonate;
b) forming or obtaining one or more aqueous solutions or suspensions or emulsions of at least one binder selected from the group consisting of (i) semi-crystalline latexes or solutions of soluble binders, (ii) latexes in emulsion or solutions of soluble binders comprising polyvinylic alcohol, polyvinyl acetate, starch, casein, proteins, carboxymethyl cellulose (CMC), ethyl hydroxyethyl cellulose (EHEC), or their mixtures, and (iii) emulsions of polyethylene waxes or copolymers in their neutralized form of polyethylene with other monomer units or other monomers or their mixtures; and
c) co-grinding the aqueous suspension or suspensions obtained in stage a) with the aqueous solutions or suspensions or emulsions obtained in stage b) in a mill so as to obtain an aqueous suspension of self-binding pigmentary particles comprising the inorganic matter and the binder adsorbed on the surface of the inorganic matter, wherein the self-binding pigmentary particles comprises at least 5% by weight of the at least one binder, and wherein the average particle diameter of the self-binding pigmentary particles so obtained is less than the average particle diameter of the inorganic matter from stage a);
d) optionally drying or increasing the concentration of the aqueous suspension obtained in stage c).
2. The particles according to claim 1 , wherein the aqueous suspension obtained in stage c) is subjected to drying.
3. The particles according to claim 1 , wherein the aqueous suspension or suspensions of inorganic matter formed in stage a) contain from 1% to 80% by dry weight of inorganic matter.
4. The particles according to claim 1 , wherein the aqueous suspension or suspensions of inorganic matter formed in stage a) contain from 15% to 60% by dry weight of inorganic matter.
5. The particles according to claim 1 , wherein the inorganic matter in stage a) comprises calcium carbonate in admixture with one or more of metallic oxides, hydroxides, sulphites, silicates, dolomites, kaolin, talc, gypsum, titanium dioxide, satin white, and aluminium trihydroxide.
6. The particles according to claim 1 , wherein the inorganic matter consists essentially of calcium carbonate.
7. The particles according to claim 1 , wherein the inorganic matter is calcium carbonate in the natural form or in the precipitated form or their mixtures.
8. The particles according to claim 7 , wherein the inorganic matter is a natural calcium carbonate comprising chalk, marble, calcite, or their mixtures.
9. The particles according to claim 1 , wherein the aqueous solutions or suspensions or emulsions of at least one binder formed in stage b) contain from 5% to 50% by weight of at least one binder.
10. The particles according to claim 1 , wherein the aqueous solutions or suspensions or emulsions of at least one binder formed in stage b) contain from 5% to 20% by weight of at least one binder.
11. The particles according to claim 1 , wherein the binder or binders of stage b) comprise semi-crystalline latexes, or solutions of soluble binders.
12. The particles according to claim 1 , wherein the binder or binders of stage b) comprise latexes in emulsion or solutions of soluble binders comprising polyvinylic alcohol, polyvinyl acetate, starch, casein, proteins, carboxymethyl cellulose (CMC), ethyl hydroxyethyl cellulose (EHEC), or their mixtures.
13. The particles according to claim 11 , wherein the semi-crystalline latexes comprise emulsions of polyethylene waxes or copolymers in their neutralized form of polyethylene with other monomer units or other monomers or their mixtures.
14. The particles according to claim 13 , wherein the monomer units are acrylic acid.
15. The particles according to claim 1 , wherein the ratio of inorganic matter and binders is between 70 and 30 expressed as weight proportions.
16. The particles according to claim 1 , wherein the self-binding pigmentary particles obtained in step c) have an average particle diameter of between 0.1 μm and 10 μm.
17. The particles according to claim 1 , wherein the self-binding pigmentary particles obtained in step c) have an average particle diameter of between 0.1 μm and 2 μm.
18. The particles according to claim 1 , wherein the aqueous suspension obtained in stage c) is concentrated by thermal or mechanical concentration.
19. The particles according to claim 1 , wherein the aqueous suspension obtained in step c) is dispersed with at least one dispersing agent and/or wetting agent.
20. The particles according to claim 19 , wherein the dispersing agent is selected from the group consisting of polymers and/or acrylic or vinylic or allylic copolymers, homopolymers or copolymers in their totally acidic or partially or totally neutralised forms by neutralising agents containing monovalent or polyvalent cations or amines or their mixtures, from at least one of the monomers including acrylic and/or methacrylic, itaconic, crotonic, fumaric acids, maleic anhydride or isocrotonic, aconitic, mesaconic, sinapic, undecylenic acid, angelic acid and/or their respective esters including acrylates or methacrylates of alkyl, aryl, alkylaryl, arylalkyl, ethyl acrylate, butyl acrylate, methyl methacrylate, sulfonic acrylamido methyl propane acid, acrylamide and/or methacrylamide, carylate phosphate of glycol ethylene, methacrylate phosphate of glycol ethylene, acrylate phosphate of glycol propylene, methacrylate phosphate of glycol propylene, chlorine or ammonium trimethyl propyl methacrylamide sulphate, their acrylate and acrylamide equivalents, quaternised or not, and/or dimethyldiallyl chlorate, vinylpyrrolidone, vinylcaprolactame, diisobutylene, vinyl acetate, styrene, alpha-methyl-styrene, styrene sodium sulfonate, vinylmethylether, allylamine or at least one of the monomers or their mixtures, polymerised in the presence of at least one mineral material.
21. The particles according to claim 19 , wherein from 0.01% to 2% by weight of at least one dispersing agent is added.
22. The particles according to claim 19 , wherein from 0.01% to 5% by weight of the at least one wetting agent is added.
23. The particles according to claim 2 , wherein the self-binding pigmentary particles after drying contain from 70% to 95% by weight of the at least one inorganic matter and from 5% to 30% by weight of the at least one binder.
24. The particles according to claim 2 , wherein the self-binding pigmentary particles after drying contain from 85% to 95% by weight of at least one inorganic matter and from 5% to 15% by weight of at least one binder.
25. The particles according to claim 2 , wherein the average diameter of the self-binding pigmentary particles after drying is between 5 μm and 100 μm.
26. The particles according to claim 2 , wherein the average diameter of the self-binding pigmentary particles after drying is between 10 μm and 30 μm.