IP Library Granted Patent US 10,371,681
Granted Patent B2
US 10,371,681 · App. 14/557,350 · Granted Aug 6, 2019

Systems and methods for generation of hydrogen peroxide vapor

Inventors: Adam H. Love (Berkeley, CA); Joel Del Eckels (Livermore, CA); Alex K. Vu (Dublin, CA); Armando Alcaraz (Livermore, CA); John G. Reynolds (San Ramon, CA)
Assignee: Lawrence Livermore National Security, LLC
G01N33/007C01B15/01C01B15/013F17D1/005G01N2033/0072Y10T137/0318
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Quick Facts
Patent No.
US 10,371,681
App. No.
14/557,350
Granted
Aug 6, 2019
Kind
B2
Abstract

A method according one embodiment includes at least one of bubbling dried air through a hydrogen peroxide solution in a container for producing a first hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above the hydrogen peroxide solution in a container for producing a second hydrogen peroxide vapor. Additional systems and methods are also presented.

Claims (12)

1. A method, comprising:

bubbling dried air from a moisture trap through a hydrogen peroxide solution in a first container for producing a first hydrogen peroxide vapor, wherein the hydrogen peroxide solution comprises water, aqueous hydrogen peroxide, a solute and a mixing agent;

passing dried air from the moisture trap into a headspace above a hydrogen peroxide solution in a second container for producing a second hydrogen peroxide vapor;

alternately directing, using a switching valve, the dried air through the hydrogen peroxide solution to generate the first hydrogen peroxide vapor and through the headspace above the hydrogen peroxide solution to generate the second hydrogen peroxide vapor;

creating a pressure differential between the moisture trap and the container for causing the dried air to pass from the moisture trap to the container; and

wherein the dried air is an artificial mix of gases, and has a volumetric flow rate of greater than 0.5 liters per minute and less than one liter per minute;

wherein the hydrogen peroxide solution in the container is not exposed to atmospheric gases;

wherein the hydrogen peroxide vapor exiting the container has a hydrogen peroxide concentration from 100 ppm to 1000 ppm;

wherein the moisture trap comprises a condenser;

wherein the container, the moisture trap, and all other surfaces and/or equipment to which the hydrogen peroxide solution and the hydrogen peroxide vapor are exposed comprise one or more nonreactive materials selected from the group consisting of: polytetrafluoroethylene (PTFE), acrylonitrile butadiene (ABS) plastic, ethylene propylene diene terpolymer (EPDM), polyvinyl chloride (PVC), nylon, polyethylene (PE), silicone, and carbon steel;

wherein the first hydrogen peroxide vapor is characterized by a higher concentration of hydrogen peroxide than the second hydrogen peroxide vapor; and

wherein an absolute humidity of the dried air passed from the moisture trap is less than 1 gram of water per cubic meter of the air.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2019
From: LOVE, ADAM H.; ECKELS, JOEL DEL; VU, ALEXANDER K.; ALCARAZ, ARMANDO; REYNOLDS, JOHN G.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 049581/0171 →
CONFIRMATORY LICENSE Recorded Jan 6, 2015
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 034640/0059 →
Continuity (3)
Division 12271163 · Nov 14, 2008
Provisional Application 60988371 · Nov 15, 2007
Related Publication 20150075249A1 · Mar 19, 2015