Solid-state imaging device, manufacturing method thereof, and electronic apparatus

1. An imaging device, comprising:

a plurality of photoelectric conversion portions disposed in a semiconductor substrate; and

a trench portion surrounding at least one of the plurality of photoelectric conversion portions in a plan view, wherein a portion of the trench portion disposed between adjacent photoelectric conversion portions of the plurality of photoelectric conversion portions, includes:

a first portion including a pinning layer, and a second portion including the pinning layer and an insulating layer,

wherein the trench portion has a lattice shape in the plan view and the first portion is in contact with a p-type region, and wherein a width of the first portion is smaller than a width of the second portion in a cross-section view.

2. The imaging device according to claim 1 ,

wherein the pinning layer is formed so as to bury the entire inner portion of the first portion.

3. The imaging device according to claim 2 , wherein the insulating layer is formed so as to cover the inside surface of the second portion via the pinning layer.

4. The imaging device according to claim 1 , wherein the insulating layer is formed so as to cover the inner surface of the second portion via the pinning layer,

wherein the pinning layer is formed so as to cover the inside surface of the first portion, and

the insulating layer is formed so as to bury the inner portion of the first portion via the pinning layer.

5. The imaging device according to claim 1 ,

wherein the pinning layer is formed of a material which includes a negative fixed charge.

6. The imaging device according to claim 1 ,

wherein the pinning layer is formed by using hafnium oxide, tantalum pentoxide, or aluminum oxide.

7. The imaging device according to claim 1 ,

wherein the pinning layer is formed with hafnium oxide.

8. The imaging device according to claim 1 , further comprising:

a pixel transistor that is provided on a surface of a side opposite to a light incident surface in the semiconductor substrate and outputs a signal charge generated by one photoelectric conversion portion of the plurality of photoelectric conversion portions as an electric signal, and

a wiring layer that is provided so as to cover the pixel transistor in the surface of the side opposite to the light incident surface in the semiconductor substrate.

9. The imaging device according to claim 1 , further comprising:

multiple trench portions that comprise the trench portion, and

a color filter that transmits incident light to a light sensing surface,

wherein a plurality of kinds of filter layers having a high transmissivity with respect to light of wavelength ranges different from one another are disposed so as to be adjacent to one another corresponding to each of a plurality of pixels in the color filer, each photoelectric conversion portion in the plurality of photoelectric conversion portions corresponding to each pixel in the plurality of pixels, and

wherein the trench portion is in a periphery of a pixel of the plurality of pixels, and the pixel has a filter layer having higher transmissivity with respect to the light of the wavelength range of the longest wavelength in the plurality of kinds of filter layers, and the trench portion in the pixel is formed so as to be deeper than trenches in other photoelectric conversion portions.

10. A method of manufacturing a solid-state imaging device comprising:

providing a plurality of photoelectric conversion portions disposed in a semiconductor substrate; and

forming a trench portion surrounding at least one of the plurality of photoelectric conversion portions in a plan view, wherein a portion of the trench portion disposed between adjacent photoelectric conversion portions of the plurality of photoelectric conversion portions, includes:

a first portion including a pinning layer, and a second portion including the pinning layer and an insulating layer,

wherein the trench portion has a lattice shape in the plan view, wherein the first portion is in contact with a p-type region and wherein a diameter of the first portion is smaller than a diameter of the second portion.

11. An imaging device, comprising:

a plurality of photoelectric conversion portions disposed in a semiconductor substrate;

a trench portion surrounding at least one of the plurality of photoelectric conversion portions in a plan view, wherein a portion of the trench portion disposed between adjacent photoelectric conversion portions of the plurality of photoelectric conversion portions, includes:

a first portion including a pinning layer and an insulating layer, and a second portion including the insulating layer,

wherein the trench portion has a lattice shape in the plan view and the first portion is in contact with a p-type region, and wherein a width of the first portion is smaller than a width of the second portion in a cross-section view.

12. An electronic apparatus comprising the imaging device according to claim 11 .

13. The imaging device according to claim 1 ,

wherein the trench portion comprises an upper portion and a lower portion, wherein the upper portion is closer to a light-receiving surface of the semiconductor surface than the lower portion, and wherein the lower portion is in contact with the p-type region.

14. The imaging device according to claim 1 ,

wherein the first portion is a lower portion of the trench portion that is furthest from a light-receiving surface of the semiconductor substrate.