Machinable zirconia comprising titania nanopowder
Provided is a machinable zirconia having high translucency as a sintered body which is formed to include a tetragonal zirconia composite powder containing 79.8 to 92 mol % ZrO 2 , 4.5 to 10.2 mol % Y 2 O 3 , 3.5 to 7.5 mol % Nb 2 O 5 or 5.5 to 10.0 mol % Ta 2 O 5 , and a TiO 2 nano powder which is added with a weight ratio of more than 0 wt % and up to 2.5 wt % to the composite powder, wherein a density of the sintered body is 99% or more, an average grain size of the sintered body is 2 μm or larger, hardness of the sintered body is in a range of 4 to 10 GPa, fracture toughness of the sintered body is in a range of 9 to 14 MPa·m 1/2 , a strength of the sintered body is in a range of 400 to 1000 MPa.
1. A machinable zirconia as a sintered body which is formed to include a tetragonal zirconia composite powder containing 79.8 to 92 mol % ZrO 2 , 4.5 to 10.2 mol % Y 2 O 3 , 3.5 to 7.5 mol % Nb 2 O 5 or 5.5 to 10.0 mol % Ta 2 O s , and a TiO 2 nano powder which is added with a weight ratio of between 0.05 wt % and 2.5 wt % of the composite powder,
wherein a density of the sintered body is 99% or more, an average particle diameter of particles of the sintered body is 2 μm or more, hardness of the sintered body is in a range of 4 to 10 GPa, fracture toughness of the sintered body is in a range of 9 to 14 MPa·m 1/2 , and a strength of the sintered body is in a range of 400 to 1000 MPa.
2. The machinable zirconia according to claim 1 , wherein the sintered body further contains CeO 2 in a range of 0.5 to 3 wt %.
3. The machinable zirconia according to claim 1 , wherein the sintered body further contains SiO 2 in a range of 0.2 to 0.8 wt %.
4. The machinable zirconia according to claim 1 , wherein the sintered body further contains F 2 O 3 , Er 2 O 3 , Tb 4 O 7 , Pr 2 O 3 , or combination thereof in a range of 0.005 to 5 wt %.
5. A method of manufacturing a machinable zirconia, comprising:
preparing a raw material including a tetragonal zirconia composite powder containing 79.8 to 92 mol % ZrO 2 , 4.5 to 10.2 mol % Y 2 O 3 , 3.5 to 7.5 mol % Nb 2 O 5 or 5.5 to 10.0 mol % Ta 2 O 5 , and a TiO 2 nano powder which is added with a weight ratio of between 0.05 wt % and 2.5 wt % of the composite powder;
forming composite granules by spraying and drying slurry containing the raw material; and
performing sintering after molding the granules,
wherein the sintering is performed in a temperature range of 1500 to 1700° C. for 2 to 40 hours.
6. The method according to claim 5 , wherein the sintering includes:
increasing a temperature up to a temperature of 1400 to 1600° C.;
retaining the temperature for a predetermined time; and
increasing the temperature up to a temperature of 1500 to 1700° C.
7. The method according to claim 6 , wherein the retaining the temperature is performed in a temperature range of 1300 to 1500° C. for 20 to 30 hours.
8. The method according to claim 6 , wherein after the sintering, hot isotropic pressing is additionally performed in a temperature range of 1300 to 1700° C. with a pressure of 10000 to 50000 psi so as to improve translucency.