Forward osmosis membrane for seawater desalination and method for preparing the same
A forward osmosis membrane for seawater desalination and a method for preparing the same. The forward osmosis membrane has a composite membrane structure including a nonwoven fabric layer; a hydrophilic polymer layer; and a polyamide layer. The hydrophilic polymer layer formed on the nonwoven fabric layer facilitates an inflow of water from the feed water to the draw solution to enhance flux and realize high water permeability in the direction of osmosis. The polyamide layer not only secures contamination resistance and chemical resistance but also minimizes the back diffusion of salts of the draw solution in the direction of reverse osmosis. Hence, the forward osmosis membrane of the present invention is greatly useful for desalination of high-concentration seawater.
1. A forward osmosis membrane for seawater desalination having a composite membrane structure of sequentially laminated layers comprising:
a woven fabric layer;
a hydrophilic polymer layer; and
a polyamide layer, wherein the forward osmosis membrane has a back diffusion of salts from a draw solution of not more than 0.375 (μS/c)/min·cm 2 , and satisfies a flux of 3-30 gfd as measured using feed water and a 2M NaCl draw solution under an osmotic pressure condition,
wherein the hydrophilic polymer layer comprises any one selected from the group consisting of hydrophilic polyacrylonitrile, hydrophilic polyacrylate, hydrophilic polymethylmethacrylate, hydrophilic polyethylene imide, hydrophilic cellulose acetate, hydrophilic cellulose triacetate, hydrophilic polyvinyl alcohol, hydrophilic polyvinylpyrrolidone, hydrophilic polyethyleneglycol, hydrophilic sulfonated polysulfone-based polymer, hydrophilic polyethylene oxide and hydrophilic polyvinyl acetate and a mixture thereof; and
wherein the fabric layer is made of woven fabric that satisifies the following two conditions: (1) number of intersections (mesh count) between weft and warp yarns in an area of 2.54 cm×2.54 cm=150-500; and (2) fineness=5-25 denier.
2. The forward osmosis membrane as claimed in claim 1 , wherein the woven fabric is made of weft and warp yarns that comprises one or more fibers selected from the group consisting of polyester, polypropylene, nylon, polyethylene, acryl, rayon, acetate and cellulose fibers.
3. The forward osmosis membrane as claimed in claim 1 , wherein the fabric layer has a thickness of 40-100 μm.
4. The forward osmosis membrane for seawater desalination as claimed in claim 1 , wherein the hydrophilic polymer layer has finger-like pores.
5. The forward osmosis membrane for seawater desalination as claimed in claim 1 , wherein the mixture contains any one selected from polyvinylpyrrolidone, polyvinyl alcohol, polyethyleneglycol or cellulose acetate in an amount of 0.1 to 5 wt % in combination with polyacrylonitrile.
6. The forward osmosis membrane for seawater desalination as claimed in claim 1 , wherein the sulfonated polysulfone-based polymer contains 0.1 to 10 wt % of a sulfonated polysulfone-based polymer represented by formula 1 in combination with the polysulfone-based polymer:
wherein A is any one functional group selected from:
B is any one functional group selected from:
m/(n+m) is 0.2 to 0.7; and is 50 to 2,300.
7. The forward osmosis membrane for seawater desalination as claimed in claim 6 , wherein the polysulfone-based polymer is any one selected from the group consisting of polysulfone, polyethersulfone, or polyarylethersulfone, either alone or as any mixture thereof.
8. The forward osmosis membrane for seawater desalination as claimed in claim 6 , wherein the sulfonated polysulfone-based polymer is a compound represented by formula 2:
wherein m/(n+m) is 0.2 to 0.7; and x is 50 to 2,300.
9. The forward osmosis membrane for seawater desalination as claimed in claim 1 , wherein the hydrophilic polymer layer has a thickness of 30 to 250 μm.
10. The forward osmosis membrane for seawater desalination as claimed in claim 1 , wherein the polyamide layer is formed by an interfacial polymerization of an aqueous solution being prepared by further adding 0.01 to 2 wt % of the polyamine salt compound to an aqueous solution containing polyfunctional amine or alkylated aliphatic amine and an organic solution containing a polyfunctional acyl halide compound.
11. The forward osmosis membrane for seawater desalination as claimed in claim 10 , wherein the polyamine salt compound is prepared from a tertiary polyamine and a strong acid at a molar ratio of 0.5˜2:1.
12. The forward osmosis membrane for seawater desalination as claimed in claim 11 , wherein the tertiary polyamine is any one selected from the group consisting of 1,4-diazabicyclo[2,2,2]octane (DABCO), 1,8-diazabicyclo[5,4,0]undec-7-ene (DBU), 1,5-diazabicyclo[4,3,0]none-5-ene (DBN), 1,4-dimethylpiperazine, 4-[2-(dimethylamino)ethyl]morpholine, N,N,N′,N′-tetramethylethylenediamine, N,N,N′,N′-tetramethyl-1,3-butanediamine, N,N,N′,N′-tetramethyl-1,4-butanediamine (TMBD), N,N,N′,N′-tetramethyl-1,3-propanediamine, N,N,N′,N′-tetramethyl-1,6-hexanediamine (TMHD), 1,1,3,3-tetramethylguanidine (TMGU) and N,N,N′,N′,N″-pentamethyldiethylenetriamine.