IP Library Granted Patent US 9,362,571
Granted Patent B2
US 9,362,571 · App. 14/603,750 · Granted Jun 7, 2016

Degradable implantable battery

Inventors: Gerald Hodgkinson (Guilford, CT); William O. Powers (Cheshire, CT); Ahmad Robert Hadba (Fort Worth, TX)
Assignee: Covidien LP
H01M6/34A61B5/6846A61N1/378A61N1/3787H01M4/131H01M4/134H01M4/137H01M4/38H01M4/42H01M4/466H01M4/485H01M4/602H01M4/622H01M6/02H01M6/04Y02E60/122
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Quick Facts
Patent No.
US 9,362,571
App. No.
14/603,750
Granted
Jun 7, 2016
Kind
B2
Abstract

A biodegradable battery is provided. The battery includes an anode comprising a material including an inner surface and an outer surface, wherein electrochemical oxidation of the anode material results in the formation of a reaction product that is substantially non-toxic and a cathode comprising a material including an inner surface and an outer surface, the inner surface of the cathode being in direct physical contact with the inner surface of the anode, wherein electrochemical reduction of the cathode material results in the formation of a reaction product that is substantially non-toxic, and wherein the cathode material presents a larger standard reduction potential than the anode material.

Claims (18)

1. A biodegradable battery comprising:

an anode comprising a material including an inner surface and an outer surface, wherein electrochemical oxidation of the anode material results in the formation of a reaction product that is substantially non-toxic; and

a cathode comprising a material including an inner surface and an outer surface, the inner surface of the cathode being separate from the inner surface of the anode,

wherein electrochemical reduction of the cathode material results in the formation of a reaction product that is substantially non-toxic, and wherein the cathode material presents a larger standard reduction potential than the anode material, and wherein the biodegradable battery has a substantially frustoconical shape.

2. The biodegradable battery of claim 1 , wherein the anode material is selected from the group consisting of magnesium, iron, zinc, electrochemically oxidizable degradable polymers, alloys, and combinations thereof.

3. The biodegradable battery of claim 1 , wherein the cathode material is selected from the group of materials consisting of metal oxides, metal hydroxides, metal oxyhydroxides, polyoxymetallates, metal salts, electrochemically reducible degradable polymers, and combinations thereof.

4. The biodegradable battery of claim 1 , further comprising a biodegradable coating disposed over the outer surface of the cathode and a portion of the outer surface of the anode.

5. The biodegradable battery of claim 4 , wherein the biodegradable coating comprises a polymer selected from the group consisting of aliphatic polyesters, polyamides, polyamines, polyalkylene oxalates, poly(anhydrides), polyamidoesters, copoly(ether-esters), poly(carbonates), poly(hydroxyalkanoates), poly(hydroxyvaleric acid), poly(hydroxybutyrate), polyimide carbonates, poly(imino carbonates), polyorthoesters, polyoxaesters, polyphosphazenes, poly (propylene fumarates), polyurethanes, polymer drugs, and combinations thereof.

6. The biodegradable battery of claim 1 , further comprising a hydrogel layer disposed over the outer surface of the anode, the hydrogel layer comprising at least one precursor material.

7. A biodegradable battery comprising:

an anode comprising a material including an inner surface and an outer surface, wherein electrochemical oxidation of the anode material results in the formation of a reaction product that is substantially non-toxic;

a cathode comprising a material including an inner surface and an outer surface, the inner surface of the cathode being separate from the inner surface of the anode; and

a biodegradable coating disposed over the outer surface of the cathode and a portion of the outer surface of the anode,

wherein electrochemical reduction of the cathode material results in the formation of a reaction product that is substantially non-toxic, and wherein the cathode material having a larger standard reduction potential than the anode material, and wherein the biodegradable battery has a substantially frustoconical shape.

8. The biodegradable battery of claim 7 , wherein the anode material comprises a material selected from the group consisting of magnesium, iron, zinc, electrochemically oxidizable degradable polymers, alloys and combinations thereof.

9. The biodegradable battery of claim 7 , wherein the cathode material comprises a material selected from the group of materials consisting of metal oxides, metal hydroxides, metal oxyhydroxides, polyoxymetallates, metal salts, electrochemically reducible degradable polymers, and combinations thereof.

10. The biodegradable battery of claim 7 , wherein the biodegradable coating comprises a polymer selected from the group consisting of aliphatic polyesters, polyamides, polyamines, polyalkylene oxalates, poly(anhydrides), polyamidoesters, copoly(ether-esters), poly(carbonates), poly(hydroxyalkanoates), poly(hydroxyvaleric acid), poly(hydroxybutyrate), polyimide carbonates, poly(imino carbonates), polyorthoesters, polyoxaesters, polyphosphazenes, poly (propylene fumarates), polyurethanes, polymer drugs, and combinations thereof.

11. The biodegradable battery of claim 7 , further comprising a hydrogel layer disposed over the outer surface of the anode, the hydrogel layer comprising at least one precursor material.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 23, 2015
From: HODGKINSON, GERALD; POWERS, WILLIAM O.; HADBA, AHMAD ROBERT
To: TYCO HEALTHCARE GROUP LP
Reel/Frame 034799/0725 →
CHANGE OF NAME Recorded Jan 23, 2015
From: TYCO HEALTHCARE GROUP LP
To: COVIDIEN LP
Reel/Frame 034807/0267 →
Continuity (3)
Continuation 14077397 · Nov 12, 2013
Continuation In Part 13183708 · Jul 15, 2011
Related Publication 20150140387A1 · May 21, 2015